Utility of heavy minerals distribution and granulometric analyses in the study of coastal dynamics: Application to the littoral between Sanlúcar de Barrameda and Rota (Cadiz, southwest Iberian Peninsula)

The present paper deals with grain size and heavy minerals distribution in the sandy coastal sediments of the littoral between the cities of Sanlúcar de Barrameda and Rota. We have related these distributions to the predominant southward littoral drift and the possible source contributions, mostly represented by the Guadalquivir and Guadalete Rivers. The littoral studied is composed of fine sand in the northern sector and medium sand in its central and southern sectors. Heavy minerals were identified using X-ray analysis: the most abundant in the study area are epidote and garnet. We found that their concentrations and sizes decrease from north to south according to the coastal drift, whereas the grain morphology and the mineralogical component generally remain constant.Este trabajo trata de las distribuciones granulométrica y de minerales pesados de los sedimentos arenosos del tramo de litoral comprendido entre las ciudades de Sanlúcar de Barrameda y Rota (suroeste de la península Ibérica). Se han relacionado dichas distribuciones con la deriva litoral predominante hacia el Sur y con las fuentes de aporte de sedimentos constituidas por los ríos Guadalquivir y Guadalete. El litoral estudiado se caracteriza por arena fina en su parte norte y arena media en su parte central y meridional. Los minerales pesados se han identificado mediante rayos X: los más abundantes en el área estudiada son epidota y granate. Se ha deducido cómo sus concentraciones y tamaños disminuyen de norte a sur de acuerdo con la deriva litoral, manteniéndose el conjunto mineralógico y la morfología de los granos constante.Instituto Español de Oceanografí

Diferencias en las propiedades reológicas de suspensiones de cal calcítica y dolomítica: influencia de las características de las partículas e implicaciones prácticas en la fabricación de morteros de cal

The study of the rheological properties of lime suspensions is a useful means to evaluate the workability of lime mortars. In this work, we studied the flow behaviour of two industrial hydrated limes, one of calcitic and the other of dolomitic composition, by means of two types of rheometer with different geometry and setup mode. The obtained results were interpreted taking into account the differences in microstructure and surface properties of the suspended particles. Calcitic lime dry particles are formed by angular and polydisperse clusters and, once dispersed in water, they behave like thixotropic materials. On the other hand, the dolomitic lime is formed by nanoparticles and small round cluster and it shows a pronounced plastic behaviour in suspension. This fundamental difference between the two materials explains the traditional preference for dolomitic lime mortars for plastering and rendering applications.El estudio de las propiedades reológicas de suspensiones de cal es una herramienta muy útil para evaluar la trabajabilidad de morteros de cal. En este trabajo se ha estudiado el comportamiento en suspensión de dos cales hidratadas, de composición calcítica y dolomítica, mediante dos tipos de reómetros con geometría y modalidades distintas de medida. Los resultados obtenidos se han interpretado teniendo en cuenta las diferencias en la microestructura y las propiedades de superficie de las partículas en suspensión. Las partículas de cal calcítica están formadas por aglomerados angulares y polidispersos y, una vez dispersadas en agua, presentan un comportamiento tixotrópico. Por su parte, la cal dolomítica está formada por nanopartículas y pequeños agregados redondeados y muestra en suspensión un pronunciado comportamiento plástico. Esta importante diferencia entre las dos cales explica la preferencia tradicional de morteros de cal dolomítica para aplicaciones en revocos

Estudio mineralógico, textural y físico-mecánico de morteros de cal hidráulica curados en distintas condiciones de humedad relativa

This work focuses on the chemical-mineralogical, textural and physical-mechanical properties of hydraulic lime mortars made with siliceous and calcareous aggregate. Mortars were cured at 60% and 90% of relative humidity, so as to assess the variability of mortar petrophysical properties in the hardened state due to the moisture conditions. The final aim was to determine the most adequate moisture conditions to be maintained during application and hardening of hydraulic mortars intended for repair interventions. We found out that using a calcareous aggregate and curing mortar at 90% of relative humidity give place to better textural and mechanical properties. However, these characteristics mostly depend on the maximum size of the aggregate grains, which should be smaller than 6 mm, in order to avoid the occurrence of mechanical discontinuities in the mortar.En este trabajo se han estudiado las propiedades químico-mineralógicas, texturales y físico-mecánicas de morteros de cal hidráulica elaborados con áridos silíceo y calcítico. Estos morteros se han curado al 60% y 90% de humedad relativa, con el fin de evaluar las eventuales diferencias en las propiedades petrofísicas de los morteros una vez endurecidos y así establecer cuál de los dos ambientes es recomendable durante la aplicación y fraguado de morteros de cal hidráulica destinados a obras de restauración. Se ha encontrado que el uso de un árido de composición calcítica y el curado al 90% de humedad relativa dan lugar a morteros hidráulicos con mejores características texturales y propiedades mecánicas. De todas formas, estas características dependen principalmente del tamaño máximo del árido empleado, que debería ser inferior a 6 mm para evitar discontinuidades mecánicas en el mortero

Influence of Surface Finishes and a Calcium Phosphate-Based Consolidant on the Decay of Sedimentary Building Stones Due to Acid Attack

Natural stone has long been used as a building material because of its physical-mechanical resistance and its esthetic appeal. However, over the last century increasing industrial activity has produced more acidic environments, such as polluted urban areas, that can cause serious damage to many buildings and historic monuments, and in particular those made with carbonate rocks, which are most prone to decay. In order to mitigate the physicochemical processes that degrade these buildings, a number of phosphate-based consolidants have been developed, which are highly compatible with the carbonated substrate. Research about the role of the surface and its different possible finishes in the transmission of the agents that damage or protect the stone would therefore be very useful, both when choosing the most suitable stone for new constructions and when restoring historic buildings. The main objective of this research was to determine whether the roughness of three types of surface finish (saw-cut, honed and bush-hammered) influences the durability of four types of natural stone (two calcarenites, one travertine and one sandstone) widely used in Andalusia (Spain). The efficacy of a calcium phosphate-based consolidant as a mitigator of deterioration in polluted urban environments was also studied and to this end the physical properties of untreated and treated samples were measured and compared. The samples were exposed to artificial atmospheres with SO2 pollution in order to assess the damage caused to each surface finish. The results indicate that all the surface finishes were vulnerable to the decay caused by acidic atmospheres, although the saw-cut finish was less affected, perhaps because it did not require additional industrial processing. The mineral composition and texture of the rocks were critical factors in terms of the amount and type of decay they suffered, and the travertine and sandstone were more resistant to deterioration than the calcarenites. Similarly, the pore system of each rock was decisive in the penetration of the consolidant. Application of the consolidant improved the behavior of the treated samples by making them more resistant to acid attack without significantly altering the water vapor permeability, the color or the roughness of the surface

Estudio mineralógico, textural y físico-mecánico de morteros de cal hidráulica curados en distintas condiciones de humedad relativa

This work focuses on the chemical-mineralogical, textural and physical-mechanical properties of hydraulic lime mortars made with siliceous and calcareous aggregate. Mortars were cured at 60% and 90% of relative humidity, so as to assess the variability of mortar petrophysical properties in the hardened state due to the moisture conditions. The final aim was to determine the most adequate moisture conditions to be maintained during application and hardening of hydraulic mortars intended for repair interventions. We found out that using a calcareous aggregate and curing mortar at 90% of relative humidity give place to better textural and mechanical properties. However, these characteristics mostly depend on the maximum size of the aggregate grains, which should be smaller than 6 mm, in order to avoid the occurrence of mechanical discontinuities in the mortar.En este trabajo se han estudiado las propiedades químico-mineralógicas, texturales y físico-mecánicas de morteros de cal hidráulica elaborados con áridos silíceo y calcítico. Estos morteros se han curado al 60% y 90% de humedad relativa, con el fin de evaluar las eventuales diferencias en las propiedades petrofísicas de los morteros una vez endurecidos y así establecer cuál de los dos ambientes es recomendable durante la aplicación y fraguado de morteros de cal hidráulica destinados a obras de restauración. Se ha encontrado que el uso de un árido de composición calcítica y el curado al 90% de humedad relativa dan lugar a morteros hidráulicos con mejores características texturales y propiedades mecánicas. De todas formas, estas características dependen principalmente del tamaño máximo del árido empleado, que debería ser inferior a 6 mm para evitar discontinuidades mecánicas en el mortero.This study was financially supported by the Spanish research group RNM179 of the Junta de Andalucía, by the research project MAT-2012-34473 and by the Institute of Conservation and Restoration of Cultural Heritage of the CICOP foundation (ICON-CICOP)

Consolidation with ethyl silicate: how the amount of product alters the physical properties of the bricks and affects their durability

We evaluated the consolidating capacity of ethyl silicate in three types of bricks fired at 800, 950 and 1100 °C. We chose two concentrations of product, at 25% and 50%, diluting the product in white spirit to estimate whether greater dilution enables the product to penetrate deeper into the bricks, or whether a higher concentration leads to better consolidation of bricks. The application of ethyl silicate caused bricks porosity to decline and their compactness to increase. These changes were more accentuated as the concentration of the product increased. The pore size distribution not changed substantially except that there were fewer of the smallest pores. The color and the lightness of the pieces changed after application of the consolidant, albeit slightly. The durability of bricks improved as manifested by the results of the salt crystallization test. In general, the longest-lasting pieces were those treated with 25% ethyl silicate.Se ha evaluado la capacidad consolidante del silicato de etilo en tres tipos de ladrillos cocidos a 800, 950 y 1100 °C. Se eligieron dos concentraciones de producto, al 25% y 50%, diluyéndolo en white spirit para estimar si más dilución favorece una penetración más en profundidad del producto o si una mayor concentración produce una mejor consolidación de los ladrillos. El silicato de etilo ha causado una disminución de la porosidad y un aumento de la compacidad de los ladrillos, acentuándose estas modificaciones con mayor concentración de producto. La distribución porométrica no ha cambiado de forma sustancial, disminuyendo los poros más pequeños. Color y luminosidad de las piezas han modificado ligeramente tras la aplicación del consolidante. Los ladrillos consolidados han mejorado su durabilidad frente al envejecimiento acelerado producido por las sales. En general, las piezas más duraderas han resultado ser las tratadas con el 25% de silicato de etilo.This study was financially supported by Research Group RNM179 of the Junta de Andalucía and by Research Project MAT2016-75889-R

Estudio arqueométrico y evaluación del deterioro de los materiales cerámicos de la fachada de la iglesia de Santa Maria del Carmine (Pavía, Italia)

We performed an archaeometric study of the ceramic materials from the façade of the church of Santa Maria del Carmine in Pavia (Italy). We obtained useful information about the firing temperatures, the provenance of raw materials and the type of oven used. The ceramics used in the façade are mineralogically rich in quartz, feldspar and phyllosilicates, and newly formed calcium silicate phases were detected in some samples. Microtextural observations revealed the presence of incipient reaction rims, phyllosilicate sintering and partial vitrification of the matrix. Ceramics show high porosity (32 to 45%) and pore sizes of between 0.4 and 1.3 µm. Our study of the different types of decay collected on the façade of the church (green and black patinas and efflorescences) revealed the presence of gypsum, whewellite, thenardite and moolooite