382 research outputs found
Eccentricity signal in the nannofossil time-series across the Mid-Pleistocene Transition in the northwestern Pacific Ocean (ODP Site 1209)
The Mid-Pleistocene Transition (MPT; 1.25–0.6 million years ago, Ma) is one of the most important and still debated climate reorganizations during which the glacial/interglacial cycles switched from a 41-thousand years (kyr) cycle (i.e. obliquity) to a quasi-periodic 100-kyr cycle (associated with orbital eccentricity). Variations in the orbital geometry can affect the abundance and distribution of certain marine biota such as the coccolithophores, a group of unicellular calcifying phytoplankton, whose skeletal remains – called nannofossils – represent a valid tool within the geological archives to infer change in surface water conditions and/or coccolithophore productivity and how orbital variations may have impacted them. Here, we apply for the first time various time series analytical techniques to the nannofossil dataset from mid-latitudinal Ocean Drilling Program (ODP) Site 1209 in the northwest Pacific Ocean for the interval spanning the last 1.6 Myr. To better interpret the orbital signal recorded by different nannofossil species we used time series analyses (i.e. wavelet, autocorrelation and cross correlation) to identify the main periodicities by single nannofossil species during the MPT, and to investigate further their response timings to those orbital drivers. In addition, we investigated how the recorded periodicities can improve understanding of the paleoecological preferences of particular species. The combination of multiple time series analyses allowed identification of the 100-kyr periodicity as the main cyclicity recorded in most analyzed species at Site 1209, documenting the predominance of the eccentricity-related signal at mid-latitudes and a reduced or absent influence of the obliquity response. Thus, our data highlight how orbital influence varies by latitude impacting the nannofossil species. The lag between eccentricity and species abundance fluctuations was also investigated, identifying a fast response ranging between 20 and 40 kyr for the taxa Calcidiscus leptoporus subspecies leptoporus, Gephyrocapsa caribbeanica small, and Reticulofenestra spp. (>5 μm). This study corroborates the potential of nannofossils to deepen understanding of the dynamics and effects of variations in orbital geometry through time. It also underlines the need to extend the study of the responses of specific species through the use of different time series analysis techniques in order to return complementary information and detect clearer orbital signals
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Observation of off-Hugoniot shocked states with ultrafast time resolution
We apply ultrafast single shot interferometry to determine the pressure and density of argon shocked from up to 7.8 GPa static initial pressure in a diamond anvil cell. This method enables the observation of thermodynamic states distinct from those observed in either single shock or isothermal compression experiments, and the observation of ultrafast dynamics in shocked materials. We also present a straightforward method for interpreting ultrafast shock wave data which determines the index of refraction at the shock front, and the particle and shock velocities for shock waves in transparent materials. Based on these methods, we observe shocked thermodynamic states between the room temperature isotherm of argon and the shock adiabat of cryogenic argon at final shock pressures up to 28 GPa
Thermal equation of state of cubic boron nitride: Implications for a high-temperature pressure scale
The equation of state of cubic boron nitride (cBN) has been determined to a maximum temperature of 3300 K at a simultaneous static pressure of up to more than 70 GPa. Ab initio calculations to 80 GPa and 2000 K have also been performed. Our experimental data can be reconciled with theoretical results and with the known thermal expansion at 1 bar if we assume a small increase in pressure during heating relative to that measured at ambient temperature. The present data combined with the Raman measurements we presented earlier form the basis of a high-temperature pressure scale that is good to at least 3300 K
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Photoacoustically Measured Speeds of Sound and the Equation of State of HBO2: On Understanding Detonation with Boron Fuel
Elucidation of geodynamic, geochemical, and shock induced processes is limited by challenges to accurately determine molecular fluid equations of state (EOS). High pressure liquid state reactions of carbon species underlie physiochemical mechanisms such as differentiation of planetary interiors, deep carbon sequestration, propellant deflagration, and shock chemistry. In this proceedings paper we introduce a versatile photoacoustic technique developed to measure accurate and precise speeds of sound (SoS) of high pressure molecular fluids and fluid mixtures. SoS of an intermediate boron oxide, HBO{sub 2} are measured up to 0.5 GPa along the 277 C isotherm. A polarized exponential-6 interatomic potential form, parameterized using our SoS data, enables EOS determinations and corresponding semi-empirical evaluations of >2000 C thermodynamic states including energy release from bororganic formulations. Our thermochemical model propitiously predicts boronated hydrocarbon shock Hugoniot results
Synthesis of Alkaline Earth Diazenides MAEN2 (MAE = Ca, Sr, Ba) by Controlled Thermal Decomposition of Azides under High Pressure
The alkaline earth diazenides MAEN2 with MAE = Ca, Sr and Ba were synthesized by a novel synthetic approach, namely, a controlled decomposition of the corresponding azides in a multianvil press at highpressure/ high-temperature conditions. The crystal structure of hitherto unknown calcium diazenide (space group I4/mmm (no. 139), a = 3.5747(6) Å, c = 5.9844(9) Å, Z = 2, wRp = 0.078) was solved and refined on the basis of powder X-ray diffraction data as well as that of SrN2 and BaN2. Accordingly, CaN2 is isotypic with SrN2 (space group I4/mmm (no. 139), a = 3.8054(2) Å, c = 6.8961(4) Å, Z = 2, wRp = 0.057) and the corresponding alkaline earth acetylenides (MAEC2) crystallizing in a tetragonally distorted NaCl structure type. In accordance with literature data, BaN2 adopts a more distorted structure in space group C2/c (no. 15) with a = 7.1608(4) Å, b = 4.3776(3) Å, c = 7.2188(4) Å, β = 104.9679(33)°, Z = 4 and wRp = 0.049). The N−N bond lengths of 1.202(4) Å in CaN2 (SrN2 1.239(4) Å, BaN2 1.23(2) Å) correspond well with a double-bonded dinitrogen unit confirming a diazenide ion [N2]2−. Temperature-dependent in situ powder X-ray diffractometry of the three alkaline earth diazenides resulted in formation of the corresponding subnitrides MAE2N (MAE = Ca, Sr, Ba) at higher temperatures. FTIR spectroscopy revealed a band at about 1380 cm−1 assigned to the N−N stretching vibration of the diazenide unit. Electronic structure calculations support the metallic character of alkaline earth diazenides
A method for isolating and culturing placental cells from failed early equine pregnancies
Early pregnancy loss occurs in 6–10% of equine pregnancies making it the main cause of reproductive wastage. Despite this, reasons for the losses are known in only 16% of cases. Lack of viable conceptus material has inhibited investigations of many potential genetic and pathological causes. We present a method for isolating and culturing placental cells from failed early equine pregnancies. Trophoblast cells from 18/30 (60%) failed equine pregnancies of gestational ages 14–65 days were successfully cultured in three different media, with the greatest growth achieved for cells cultured in AmnioChrome™ Plus. Genomic DNA of a suitable quality for molecular assays was also isolated from 29/30 of these cases. This method will enable future investigations determining pathologies causing EPL
A reference time scale for Site U1385 (Shackleton Site) on the SW Iberian Margin
Weproduced a composite depth scale and chronology for Site U1385 on the SWIberianMargin. Using log(Ca/Ti)measured by core scanning XRF at 1-cm resolution in all holes, a composite section was constructed to166.5 meter composite depth (mcd) that corrects for stretching and squeezing in each core. Oxygen isotopesof benthic foraminifera were correlated to a stacked d18O reference signal (LR04) to produce an oxygen isotopestratigraphy and age model.Variations in sediment color contain very strong precession signals at Site U1385, and the amplitude modulationof these cycles provides a powerful tool for developing an orbitally-tuned agemodel.We tuned the U1385 recordby correlating peaks in L* to the local summer insolation maxima at 37°N. The benthic d18O record of Site U1385,when placed on the tuned agemodel, generally agrees with other time scaleswithin their respective chronologicuncertainties.The age model is transferred to down-core data to produce a continuous time series of log(Ca/Ti) that reflectrelative changes of biogenic carbonate and detrital sediment. Biogenic carbonate increases during interglacialand interstadial climate states and decreases during glacial and stadial periods. Much of the variance in thelog(Ca/Ti) is explained by a linear combination of orbital frequencies (precession, tilt and eccentricity), whereasthe residual signal reflects suborbital climate variability. The strong correlation between suborbital log(Ca/Ti)variability and Greenland temperature over the last glacial cycle at Site U1385 suggests that this signal can beused as a proxy for millennial-scale climate variability over the past 1.5 Ma.Millennial climate variability, as expressed by log(Ca/Ti) at Site U1385, was a persistent feature of glacial climatesover the past 1.5Ma, including glacial periods of the early Pleistocene (‘41-kyrworld’)when boundary conditionsdiffered significantly from those of the late Pleistocene (‘100-kyr world’). Suborbital variability was suppressedduring interglacial stages and enhanced during glacial periods, especially when benthic d18O surpassed ~3.3–3.5‰. Each glacial inception was marked by appearance of strong millennial variability and each deglaciatio
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Safety and security policies on psychiatric acute admission wards: results from a London-wide survey
Very little research evidence is available regarding current safety and security procedures on acute psychiatric wards. This includes controversial areas such as the temporary removal of personal property, the searching of patients and visitors, the use of alarms and modern technology, and locking of entrances to regulate those entering and leaving. This is also despite widening dismay over increasing violence within a variety of hospital settings, the comparatively high risk of physical assault faced by mental health professionals and an abundance of literature and training in regards to violence management and prevention. To gain an understanding of current safety and security measures, a London-wide survey of acute admission wards was undertaken revealing a wide variety of measures and policies in operation. Over 100 NHS and private wards were sent questionnaires; there was a response rate of 70%. Results show that a significant proportion of acute admission wards are now locked at all times and a small proportion of units have 24-hour security/reception staff on-site and a low level of modern technology usage such as CCTV and electronic access systems. There is wide variation in items banned, restrictions placed on inpatients, and the searching of patients and visitors. Two independently varying emphases of ward security policies were identifiable, the first aimed at preventing harm to patients using door security, banning of item and restrictions on inpatients. The other is aimed at reducing risks to staff via searching of patients, use of security guards and sophisticated alarm systems. There is some preliminary evidence that these security policies are differentially associated with levels of absconding and violent incidents. Further research to guide practice is urgently required
Enhanced climate instability in the North Atlantic and southern Europe during the Last Interglacial
Considerable ambiguity remains over the extent and nature of millennial/centennial-scale climate instability during the Last Interglacial (LIG). Here we analyse marine and terrestrial proxies from a deep-sea sediment sequence on the Portuguese Margin and combine results with an intensively dated Italian speleothem record and climate-model experiments. The strongest expression of climate variability occurred during the transitions into and out of the LIG. Our records also document a series of multi-centennial intra-interglacial arid events in southern Europe, coherent with cold water-mass expansions in the North Atlantic. The spatial and temporal fingerprints of these changes indicate a reorganization of ocean surface circulation, consistent with low-intensity disruptions of the Atlantic meridional overturning circulation (AMOC). The amplitude of this LIG variability is greater than that observed in Holocene records. Episodic Greenland ice melt and runoff as a result of excess warmth may have contributed to AMOC weakening and increased climate instability throughout the LIG
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