621 research outputs found
Materiales y tecnologías en la Arquitectura Modernista: casos de estudio de decoración de fachadas en Italia, Portugal y Polonia persiguiendo una restauración racional
The results of a diagnostic survey on the materials of representative Art Nouveau buildings in Italy, Portugal and Poland are here presented and compared, as a contribution to their understanding and, hence, to support compatible restoration. In particular, the facade decorations were investigated for the appraisal of their materials and technologies, often neglected in current maintenance/restoration works and so cancelled, leading to a severe loss in architectural image. The ongoing diagnostic campaign, in collaboration among different universities, is aimed to set up a database on materials and technologies of Art Nouveau facade decorations at a European scale, as a technical-scientific background for the highlighting of preservation guidelines
Hybrid Simulation Safety: Limbos and Zero Crossings
Physical systems can be naturally modeled by combining continuous and
discrete models. Such hybrid models may simplify the modeling task of complex
system, as well as increase simulation performance. Moreover, modern simulation
engines can often efficiently generate simulation traces, but how do we know
that the simulation results are correct? If we detect an error, is the error in
the model or in the simulation itself? This paper discusses the problem of
simulation safety, with the focus on hybrid modeling and simulation. In
particular, two key aspects are studied: safe zero-crossing detection and
deterministic hybrid event handling. The problems and solutions are discussed
and partially implemented in Modelica and Ptolemy II
Computing the Cassels–Tate pairing on the 3-Selmer group of an elliptic curve
We extend the method of Cassels for computing the Cassels-Tate pairing on the 2-Selmer group of an elliptic curve, to the case of 3-Selmer groups. This requires significant modifications to both the local and global parts of the calculation. Our method is practical in sufficiently small examples, and can be used to improve the upper bound for the rank of an elliptic curve obtained by 3-descent
Relationship between dynamics of Epstein-Barr virus and immune activation in HIV-1 infected subjects in the HAART era
Photoluminescence, photoabsorption and photoemission studies of hydrazone thin film used as hole transporting material in OLEDs
A fotoluminescência de filmes finos de 1-(3-metilfenil)-1,2,3,4-tetrahidroquinolina-6-carboxialdeído-1,1’-difenilhidrazona foi monitorada em função da irradiação com luz UV. A intensidade da emissão decresce exponencialmente com o tempo de exposição, sugerindo degradação das amostras. Com o objetivo de investigar os mecanismos de degradação e determinar a estrutura eletrônica desse material orgânico usado com sucesso como camada transportadora de buracos na fabricação de diodos orgânicos emissores de luz (OLEDs), foram empregadas as técnicas de fotoabsorção e de fotoemissão nas bordas 1s do carbono e do nitrogênio bem como na banda de valência. A influência da luz solar foi simulada usando radiação síncrotron não-monocromática. Após exposição, todos os espectros apresentam um decréscimo nos sinais de fotoabsorção e de fotoemissão, que é menos acentuado na borda do carbono, apresentando, entretanto, um decréscimo drástico na borda do nitrogênio e na região de valência. O estudo sugere que a perda de nitrogênio é a principal causa para a quebra do sistema π, levando, dessa forma, à falha do dispositivo fabricado com esse composto.Photoluminescence (PL) emission of 1-(3-methylphenyl)-1,2,3,4-tetrahydroquinoline-6-carboxyaldehyde-1,1’-diphenylhydrazone (MTCD) thin films was monitored as a function of UV irradiation, and it was found to decrease exponentially with the exposure time. In order to gain insight into the degradation mechanisms and evaluate the electronic structure of this organic material used with good results as hole transporting layer (HTL) in the fabrication of organic light emitting diodes (OLEDs), synchrotron radiation-based photoabsorption and photoemission techniques at the carbon and nitrogen 1s edges as well as at the valence band were employed. The influence of sunlight was simulated using non-monochromatized synchrotron radiation. After exposure all the spectra show a decrease of the photoabsorption and photoemission signals, however, while it is less accentuated at the carbon edge, at the nitrogen edge and at the valence region it decreases drastically. The loss of nitrogen is suggested to be the main step in the disruption of the π system, leading to the failure of the devices fabricated with this compound as hole transporting layer
Highly Luminescent Europium(III) Complexes in Solution and PMMA-Doped Films for Bright Red Electroluminescent Devices
This paper reports the synthesis, structure, photophysical, and optoelectronic properties of five eight-coordinate Europium(III) ternary complexes, namely, [Eu(hth)3(L)2], bearing 4,4,5,5,6,6,6-heptafluoro-1-(2-thienyl)-1,3-hexanedione (hth) as a sensitizer and L = H2O (1), dpso (diphenyl sulphoxide, 2), dpsoCH3 (4,4′-dimethyl diphenyl sulfoxide, 3), dpsoCl (bis(4-chlorophenyl)sulphoxide, 4), and tppo (triphenylphosphine oxide, 5) as co-ligands. The NMR and the crystal structure analysis confirmed the eight-coordinate structures of the complexes in solution and in a solid state. Upon UV-excitation on the absorption band of the β-diketonate ligand hth, all complexes showed the characteristic bright red luminescence of the Europium ion. The tppo derivative (5) displayed the highest quantum yield (up to 66%). As a result, an organic light-emitting device, OLED, was fabricated with a multi-layered structure—ITO/MoO3/mCP/SF3PO:[complex 5] (10%)/TPBi:[complex 5] (10%)/TmPyPB/LiF/Al—using complex 5 as the emitting component
Modular symbols in Iwasawa theory
This survey paper is focused on a connection between the geometry of
and the arithmetic of over global fields,
for integers . For over , there is an explicit
conjecture of the third author relating the geometry of modular curves and the
arithmetic of cyclotomic fields, and it is proven in many instances by the work
of the first two authors. The paper is divided into three parts: in the first,
we explain the conjecture of the third author and the main result of the first
two authors on it. In the second, we explain an analogous conjecture and result
for over . In the third, we pose questions for general
over the rationals, imaginary quadratic fields, and global function fields.Comment: 43 page
Computations in non-commutative Iwasawa theory
We study special values of L-functions of elliptic curves over Q twisted by
Artin representations that factor through a false Tate curve extension
. In this setting, we explain how to
compute L-functions and the corresponding Iwasawa-theoretic invariants of
non-abelian twists of elliptic curves. Our results provide both theoretical and
computational evidence for the main conjecture of non-commutative Iwasawa
theory.Comment: 60 pages; with appendix by John Coates and Ramdorai Sujath
Elliptic Curves over Real Quadratic Fields are Modular
We prove that all elliptic curves defined over real quadratic fields are
modular.Comment: 38 pages. Magma scripts available as ancillary files with this arXiv
versio
Systems analysis of protein signatures predicting cetuximab responses in KRAS, NRAS, BRAF and PIK3CA wild-type patient-derived xenograft models of metastatic colorectal cancer
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