200 research outputs found
Spin-polarized x-ray emission of 3d transition-metal ions: A comparison via K a and K ß detection
This paper demonstrates that spin-polarized x-ray-excitation spectra can be obtained using K a emission as
well as K ß lines. A spin-polarized analysis of K a x-ray emission and the excitation spectra by K a detection
on a Ni compound is reported. A systematic analysis of the first-row transition-metal ions using the ligand-field
multiplet calculation is presented for K a and K ß emission spectra
High Resolution K Capture X-ray Fluorescence Spectroscopy: A New Tool for Chemical Characterization
The ability to probe specific chemical sites in complex systems would make X-ray spectroscopy a far more versatile spectroscopic tool. In vibrational and magnetic resonance spectroscopies, isotopic substitution is commonly employed to allow characterization of particular species. Except in a few special cases, such as gas-phase spectra of light elements, isotope effects are too small to be observed in X-ray absorption spectra. An alternative approach is to examine the X-ray emission that results after electron capture by a radioactive isotope.^1,2 Controlled introduction of electron-capture isotopes could result in specific labeling of chemically distinct sites. In this paper, we show that highresolution electron capture fluorescence spectra can be obtained on a reasonable time scale. Chemical shifts in these spectra can be used to identify elemental spin states, oxidation states, and even the types of neighboring atoms. In the electron-capture process an inner shell electron reacts with a nuclear proton to yield a neutron and a neutrino
Influence of the core hole on Kß emission following photoionization or orbital electron capture: a comparison using MnO and 55Fe2O3
The Mn K ß fluorescence emission in MnO after photoionization and in "Fe 2 O 3 after radioactive electron
capture decay from the K shell have been measured using a crystal array spectrometer with an instrumental
energy bandwidth of 0.7 eV (full width at half maximum). Both compounds have a 3d 5 valence electron
configuration in the ionic approximation. It is found that the spectral features after K capture in 55 Fe 2 O 3 are
shifted in emission energy and are sharper, compared to the spectra following photoionization in MnO, i.e., the
spectra exhibit a dependence on the mode of excitation. Crystal-field multiplet calculations including ligand-to-
metal charge transfer have been carried out for the 1s intermediate states as well as for the 3p to 1s (K ß)
radiative transition. The populated 1s intermediate states after photoionization are found to be spread over
several eV. In comparison, only the lowest-lying 1s intermediate states split by the weak (1s,3d) exchange
interaction are populated after K capture. It is proposed that the differences in population of the 1s intermediate
states together with a term-dependent final-state lifetime broadening can account for the changes in the spectral
shapes due to the different modes of excitation
Low frequency dynamics of the nitrogenase MoFe protein via femtosecond pump probe spectroscopy - Observation of a candidate promoting vibration
We have used femtosecond pump-probe spectroscopy (FPPS) to study the FeMo-cofactor within the nitrogenase (N2ase) MoFe protein from Azotobacter vinelandii. A sub-20-fs visible laser pulse was used to pump the sample to an excited electronic state, and a second sub-10-fs pulse was used to probe changes in transmission as a function of probe wavelength and delay time. The excited protein relaxes to the ground state with a ~1.2ps time constant. With the short laser pulse we coherently excited the vibrational modes associated with the FeMo-cofactor active site, which are then observed in the time domain. Superimposed on the relaxation dynamics, we distinguished a variety of oscillation frequencies with the strongest band peaks at ~84, 116, 189, and 226cm(-1). Comparison with data from nuclear resonance vibrational spectroscopy (NRVS) shows that the latter pair of signals comes predominantly from the FeMo-cofactor. The frequencies obtained from the FPPS experiment were interpreted with normal mode calculations using both an empirical force field (EFF) and density functional theory (DFT). The FPPS data were also compared with the first reported resonance Raman (RR) spectrum of the N2ase MoFe protein. This approach allows us to outline and assign vibrational modes having relevance to the catalytic activity of N2ase. In particular, the 226cm(-1) band is assigned as a potential 'promoting vibration' in the H-atom transfer (or proton-coupled electron transfer) processes that are an essential feature of N2ase catalysis. The results demonstrate that high-quality room-temperature solution data can be obtained on the MoFe protein by the FPPS technique and that these data provide added insight to the motions and possible operation of this protein and its catalytic prosthetic group
Entanglement Interpretation of Black Hole Entropy in String Theory
We show that the entropy resulting from the counting of microstates of non
extremal black holes using field theory duals of string theories can be
interpreted as arising from entanglement. The conditions for making such an
interpretation consistent are discussed. First, we interpret the entropy (and
thermodynamics) of spacetimes with non degenerate, bifurcating Killing horizons
as arising from entanglement. We use a path integral method to define the
Hartle-Hawking vacuum state in such spacetimes and discuss explicitly its
entangled nature and its relation to the geometry. If string theory on such
spacetimes has a field theory dual, then, in the low-energy, weak coupling
limit, the field theory state that is dual to the Hartle-Hawking state is a
thermofield double state. This allows the comparison of the entanglement
entropy with the entropy of the field theory dual, and thus, with the
Bekenstein-Hawking entropy of the black hole. As an example, we discuss in
detail the case of the five dimensional anti-de Sitter, black hole spacetime
Algorithmic Tamper-Proof (ATP) Security: Theoretical Foundations for Security against Hardware Tampering
Abstract. Traditionally, secure cryptographic algorithms provide security against an adversary who has only black-box access to the secret information of honest parties. However, such models are not always adequate. In particular, the security of these algorithms may completely break under (feasible) attacks that tamper with the secret key. In this paper we propose a theoretical framework to investigate the algorithmic aspects related to tamper-proof security. In particular, we define a model of security against an adversary who is allowed to apply arbitrary feasible functions f to the secret key sk, and obtain the result of the cryptographic algorithms using the new secret key f(sk). We prove that in the most general setting it is impossible to achieve this strong notion of security. We then show minimal additions to the model, which are needed in order to obtain provable security. We prove that these additions are necessary and also sufficient for most common cryptographic primitives, such as encryption and signature schemes. We discuss the applications to portable devices protected by PINs and show how to integrate PIN security into the generic security design. Finally we investigate restrictions of the model in which the tampering powers of the adversary are limited. These restrictions model realistic attacks (like differential fault analysis) that have been demonstrated in practice. In these settings we show security solutions that work even without the additions mentioned above
Demonstration of the temporal matter-wave Talbot effect for trapped matter waves
We demonstrate the temporal Talbot effect for trapped matter waves using
ultracold atoms in an optical lattice. We investigate the phase evolution of an
array of essentially non-interacting matter waves and observe matter-wave
collapse and revival in the form of a Talbot interference pattern. By using
long expansion times, we image momentum space with sub-recoil resolution,
allowing us to observe fractional Talbot fringes up to 10th order.Comment: 17 pages, 7 figure
Kaon Production and Kaon to Pion Ratio in Au+Au Collisions at \snn=130 GeV
Mid-rapidity transverse mass spectra and multiplicity densities of charged
and neutral kaons are reported for Au+Au collisions at \snn=130 GeV at RHIC.
The spectra are exponential in transverse mass, with an inverse slope of about
280 MeV in central collisions. The multiplicity densities for these particles
scale with the negative hadron pseudo-rapidity density. The charged kaon to
pion ratios are and
for the most central collisions. The ratio is lower than the same
ratio observed at the SPS while the is higher than the SPS result.
Both ratios are enhanced by about 50% relative to p+p and +p
collision data at similar energies.Comment: 6 pages, 3 figures, 1 tabl
Phi meson production in Au+Au and p+p collisions at sqrt (s)=200 GeV
We report the STAR measurement of Phi meson production in Au+Au and p+p
collisions at sqrt (s)=200 GeV. Using the event mixing technique, the Phi
spectra and yields are obtained at mid-rapidity for five centrality bins in
Au+Au collisions and for non-singly-diffractive p+p collisions. It is found
that the Phi transverse momentum distributions from Au+Au collisions are better
fitted with a single-exponential while the p+p spectrum is better described by
a double-exponential distribution. The measured nuclear modification factors
indicate that Phi production in central Au+Au collisions is suppressed relative
to peripheral collisions when scaled by the number of binary collisions. The
systematics of versus centrality and the constant Phi/K- ratio versus beam
species, centrality, and collision energy rule out kaon coalescence as the
dominant mechanism for Phi production.Comment: 6 pages, 3 figures, submitted to Phys. Rev. Let
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