Light intensity influence on strontium Titanate based photo-electrochemical cells

The influence of light intensity on photo-electrochemical cells (PECs) consisting of an n-type strontium titanate (SrTiO₃) photoanode and nickel cathode in potassium hydroxide electrolyte is studied. The band levels of an electrolyte metalsemiconductor-electrolyte system are presented and the effect of different light intensities on the energy levels is investigated. Photocurrent density, quantum efficiency, and open circuit potential measurements are performed on the processed PECs under different light intensities (375 nm). It is demonstrated that a threshold value of the light intensity has to be reached in order to obtain positive photo activity and that beyond this value the performance remains nearly constant

Intense pCO2 and [O2] Oscillations in a Mussel-Seagrass Habitat: Implications for Calcification

Numerous studies have been conducted on the effect of ocean acidification on calcifiers inhabiting nearshore benthic habitats, such as the blue mussel Mytilus edulis. The majority of these experiments was performed under stable CO2 partial pressure (pCO2), carbonate chemistry and oxygen (O2) levels, reflecting present or expected future open ocean conditions. Consequently, levels and variations occurring in coastal habitats, due to biotic and abiotic processes, were mostly neglected, even though these variations largely override global long-term trends. To highlight this hiatus and guide future research, state-of-the-art technologies were deployed to obtain high-resolution time series of pCO2 and [O2] on a mussel patch within a Zostera marina seagrass bed, in Kiel Bay (western Baltic Sea) in August and September 2013. Combining the in situ data with results of discrete sample measurements, a full seawater carbonate chemistry was derived using statistical models. An average pCO2 more than 50 % (~ 640 µatm) higher than current atmospheric levels was found right above the mussel patch. Diel amplitudes of pCO2 were large: 765 ± 310 (mean ± SD). Corrosive conditions for calcium carbonates (Ωarag and Ωcalc < 1) centered on sunrise were found, but the investigated habitat never experienced hypoxia throughout the study period. It is estimated that mussels experience conditions limiting calcification for 12–15 h per day, based on a regional calcium carbonate concentration physiological threshold. Our findings call for more extensive experiments on the impact of fluctuating corrosive conditions on mussels. We also stress the complexity of the interpretation of carbonate chemistry time series data in such dynamic coastal environments

Single-Mode Polymer Ridge Waveguide Integration of Organic Thin-Film Laser

Organic thin-film lasers (OLAS) are promising optical sources when it comes to flexibility and small-scale manufacturing. These properties are required especially for integrating organic thin-film lasers into single-mode waveguides. Optical sensors based on single-mode ridge waveguide systems, especially for Lab-on-a-chip (LoC) applications, usually need external laser sources, free-space optics, and coupling structures, which suffer from coupling losses and mechanical stabilization problems. In this paper, we report on the first successful integration of organic thin-film lasers directly into polymeric single-mode ridge waveguides forming a monolithic laser device for LoC applications. The integrated waveguide laser is achieved by three production steps: nanoimprint of Bragg gratings onto the waveguide cladding material EpoClad, UV-Lithography of the waveguide core material EpoCore, and thermal evaporation of the OLAS material Alq3:DCM2 on top of the single-mode waveguides and the Bragg grating area. Here, the laser light is analyzed out of the waveguide facet with optical spectroscopy presenting single-mode characteristics even with high pump energy densities. This kind of integrated waveguide laser is very suitable for photonic LoC applications based on intensity and interferometric sensors where single-mode operation is required

Field-level land-use data reveal heterogeneous crop sequences with distinct regional differences in Germany

Crop cultivation intensifies globally, which can jeopardize biodiversity and the resilience of cropping systems. We investigate changes in crop rotations as one intensification metric for half of the croplands in Germany with annual field-level land-use data from 2005 to 2018. We proxy crop rotations with crop sequences and compare how these sequences changed among three seven-year periods. The results reveal an overall high diversity of crop sequences in Germany. Half of the cropland has crop sequences with four or more crops within a seven-year period, while continuous cultivation of the same crop is present on only 2% of the cropland. Larger farms tend to have more diverse crop sequences and organic farms have lower shares of cereal crops. In three federal states, crop rotations became less structurally diverse over time, i.e. the number of crops and the number of changes between crops decreased. In one state, structural diversity increased and the proportion of monocropping decreased. The functional diversity of the crop sequences, which measures the share of winter and spring crops as well as the share of leaf and cereal crops per sequence, remained largely stable. Trends towards cereal- or leaf-crop dominated sequences varied between the states, and no clear overall dynamic could be observed. However, the share of winter crops per sequence decreased in all four federal states. Quantifying the dynamics of crop sequences at the field level is an important metric of land-use intensity and can reveal the patterns of land-use intensification

Macroalgae may mitigate ocean acidification effects on mussel calcification by increasing pH and its fluctuations

Ocean acidification (OA) is generally assumed to negatively impact calcification rates of marine organisms. At a local scale however, biological activity of macrophytes may generate pH fluctuations with rates of change that are orders of magnitude larger than the long-term trend predicted for the open ocean. These fluctuations may in turn impact benthic calcifiers in the vicinity. Combining laboratory, mesocosm and field studies, such interactions between OA, the brown alga Fucus vesiculosus, the sea grass Zostera marina and the blue mussel Mytilus edulis were investigated at spatial scales from decimetres to 100s of meters in the western Baltic. Macrophytes increased the overall mean pH of the habitat by up to 0.3 units relative to macrophyte-free, but otherwise similar, habitats and imposed diurnal pH fluctuations with amplitudes ranging from 0.3 to more than 1 pH unit. These amplitudes and their impact on mussel calcification tended to increase with increasing macrophyte biomass to bulk water ratio. At the laboratory and mesocosm scales, biogenic pH fluctuations allowed mussels to maintain calcification even under acidified conditions by shifting most of their calcification activity into the daytime when biogenic fluctuations caused by macrophyte activity offered temporal refuge from OA stress. In natural habitats with a low biomass to water body ratio, the impact of biogenic pH fluctuations on mean calcification rates of M. edulis was less pronounced. Thus, in dense algae or seagrass habitats, macrophytes may mitigate OA impact on mussel calcification by raising mean pH and providing temporal refuge from acidification stress

Manufacturing of embedded multimode waveguides by reactive lamination of cyclic olefin polymer and polymethylmethacrylate

We demonstrate the manufacturing of embedded multimode optical waveguides through linking of polymethylmethacrylate (PMMA) foils and cyclic olefin polymer (COP) filaments based on a lamination process. Since the two polymeric materials cannot be fused together through interdiffusion of polymer chains, we utilize a reactive lamination agent based on PMMA copolymers containing photoreactive 2-acryloyloxyanthraquinone units, which allows the creation of monolithic PMMA-COP substrates through C-H insertion reactions across the interface between the two materials. We elucidate the lamination process and evaluate the chemical link between filament and foils by carrying out extraction tests with a custom-built tensile testing machine. We also show attenuation measurements of the manufactured waveguides for different manufacturing parameters. The lamination process is in particular suited for large-scale and low-cost fabrication of board-level devices with optical waveguides or other micro-optical structures, e.g., optofluidic devices. © 2016 Society of Photo-Optical Instrumentation Engineers (SPIE).DFG/SFB/TRR 12

The Great Slump : Mrk 926 reveals discrete and varying Balmer line satellite components during a drastic phase of decline

This work has been supported by the DFG grants KO857/35-1 and CH71/34-3. K. H. acknowledges support from STFC grant ST/M001296/1. D. C. acknowledges support from ISF grant 2398/19.Aims. Mrk 926 is known to be a highly variable active galactic nucleus. Furthermore, it is known to show very broad line profiles. We intended to study the continuum and line profile variations of this object with high temporal resolution in order to determine its broad-line region structure and to derive its black hole mass. Methods. We carried out a high-cadence spectroscopic variability campaign of Mrk 926 with the 10m HET telescope, aided by photometric V-band data taken with the C18 telescope at the Wise Observatory, over a period of about five months. We extracted spectroscopic continuum and line light curves, and computed cross-correlation functions (CCFs) as well as velocity-resolved CCFs with respect to the combined spectroscopic and photometric V-band light curve. Results. The continuum luminosity of Mrk 926 showed a drastic decrease during our campaign. The luminosity dropped to less than 50% of its original luminosity within only 2.5 months. Furthermore, the spectra of Mrk 926 show complex and very broad Balmer line profiles, including outer Balmer satellites ranging from ±5000 to ±13 000 km s−1. The integrated Hα, Hβ, and He Iλ5876 line light curves are delayed relative to the continuum light curve. The Hα and Hβ lines show two velocity-delay structures in the central part of their line profile (within ±5000 km s−1), at ∼10 and ∼57 light-days and at ∼5 and ∼48 light-days, respectively. These structures might be interpreted as the upper and lower halves of an ellipse in the velocity-delay plane, which might be the signature of a line-emitting ring, inclined by ∼50° to the line of sight and orbiting the black hole at radii, R, of 33.5 and 26.5 light-days. We determined continuum luminosities, log(λ Lλ/erg s−1), of 43.68–44.13, which are in good agreement with the established RBLR − LAGN relation. Adopting delays of 33.5 and 26.5 days for Hα and Hβ, respectively, we derive a black hole mass of (1.1 ± 0.2)×108 M⊙; this indicates a low Eddington ratio, which decreased from 8 to 3 percent during our campaign. The Balmer satellite components show a higher correlation coefficient with respect to the continuum than the central line profile, and their response to the continuum variations is on the order of only 3 − 5 days. We attribute this to the central line segment and the Balmer satellites having different, spatially distinct regions of origin.Publisher PDFPeer reviewe

DLR HySU—A Benchmark Dataset for Spectral Unmixing

Spectral unmixing represents both an application per se and a pre-processing step for several applications involving data acquired by imaging spectrometers. However, there is still a lack of publicly available reference data sets suitable for the validation and comparison of different spectral unmixing methods. In this paper, we introduce the DLR HyperSpectral Unmixing (DLR HySU) benchmark dataset, acquired over German Aerospace Center (DLR) premises in Oberpfaffenhofen. The dataset includes airborne hyperspectral and RGB imagery of targets of different materials and sizes, complemented by simultaneous ground-based reflectance measurements. The DLR HySU benchmark allows a separate assessment of all spectral unmixing main steps: dimensionality estimation, endmember extraction (with and without pure pixel assumption), and abundance estimation. Results obtained with traditional algorithms for each of these steps are reported. To the best of our knowledge, this is the first time that real imaging spectrometer data with accurately measured targets are made available for hyperspectral unmixing experiments. The DLR HySU benchmark dataset is openly available online and the community is welcome to use it for spectral unmixing and other applications