ZnO nanobelt based conductometric H2 and NO2 gas sensors

Conductometric H2 and NO2 gas sensors based on single-crystalline ZnO nanobelt sensitive layers have been developed. These layers were deposited using a rf magnetron sputterer. TEM and SEM characterization methods were employed to study the morphology of the nanobelts. These sensors were exposed to H2 and NO2 gases at operating temperatures between 225degC and 420degC. Study showed that sensors responded with highest magnitude at above 300degC. The fastest response and recovery times, with greater repeatability occurred at 385degC and 350degC for H2 and NO2 gases, respectively. Sensor with ZnO nanobelts has a much lower optimum operational temperature than that of conductometric sensors with other forms of ZnO crystal layers

Production of Gas Phase Zinc Oxide Nanoclusters by Pulsed Laser Ablation

We present experimental results on the photoluminescence (PL) of gas-suspended zinc oxide nanoclusters prepared during ablation of sintered ZnO targets by a pulsed ArF laser in the presence of oxygen ambient gas. The PL spectra in the UV spectral region correspond to the exciton recombination in the nanoclusters which are crystallized and cooled down to the temperature of the ambient gas in the ablation chamber. The time evolution of the spectra as well as their dependence on the ambient gas pressure are discussed.Comment: EMRS-2004, Strasbourg, France. Paper N-I.

Single phase a-plane MgZnO epilayers for UV optoelectronics: substitutional behaviour of Mg at large contents

High quality 1 μm thick a-plane MgxZn1−xO layers were produced by molecular beam epitaxy with Mg contents higher than 50%. Resonant Rutherford backscattering spectrometry combined with ion channeling revealed a uniform growth in both composition and atomic order. The lattice-site location of Mg, Zn and O elements was determined independently, proving the substitutional behaviour of Mg in Zn-sites of the wurtzite lattice. X-Ray diffraction pole figure analysis also confirms the absence of phase separation. Optical properties at such high Mg contents were studied in Schottky photodiodes

THE POPULATION STRUCTURE OF VIBRIO CHOLERAE IN CHESAPEAKE BAY

The population structure of V. cholerae in Chesapeake Bay, United States, was analyzed and a simple procedure that employed only two biochemical tests in an abbreviated identification scheme, i.e., arginine dihydrolase and esculin hydrolysis, was developed. After enrichment in alkaline peptone water and selective plating on thiosulfate-citrate-bile salts-sucrose agar, all of the sucrose fermenting colonies identified by the two tests were confirmed as V. cholerae by the polymerase chain reaction. A non-redundant collection of 224 V. cholerae strains collected from 1998 through 2000 from Chesapeake Bay was analyzed for phenotype, genotype, and genomic fingerprint. A long-range enterobacterial repetitive intergenic consensus (ERIC) PCR method that was developed for this study provided fingerprint patterns that proved useful in assessing relatedness among the strains. Cluster analysis was done using three different methods and revealed three well separated, primary clusters: Cluster A, consisting of the majority of the isolates, including the toxigenic type strain for the species and luminescent strains of V. cholerae; a smaller Cluster B, with the noteworthy characteristic of low toxR gene homology; and Cluster M, consisting exclusively of V. mimicus. Another primary cluster, Cluster C, was also identified as a single clone of a sucrose-negative, luminescent, toxR-negative strain. Because V. mimicus formed a separate cluster with similar distance values as demonstrated by V. cholerae Cluster B, using both ERIC fingerprinting and DNA-DNA hybridization, and had phenotypic and genotypic traits and 16S rDNA sequences similar to V. cholerae, it is concluded that all of the primary clusters observed in this study, including V. mimicus, belong to a single species, V. cholerae. V. mimicus was judged to be the highest risk group of the non-toxigenic isolates, in terms of susceptibility to CTX-phi and possession of the heat-stable enterotoxin gene (stn). Approximately 11% of the V. cholerae strains that lacked the toxin-coregulated pili (TCP) and 50% of the V. mimicus strains were found to be susceptible to CTX-phi. In addition to the V. cholerae strains in the toxigenic subcluster, luminescent V. cholerae strains represented the next highest risk, since 14% of the luminescent strains were susceptible to CTX-phi and 33% were stn positive

Self-assembled MgxZn1−xO quantum dots (0 ≤ x ≤ 1) on different substrates using spray pyrolysis methodology

By using the spray pyrolysis methodology in its classical configuration we have grown self-assembled MgxZn1−xO quantum dots (size [similar]4–6 nm) in the overall range of compositions 0 ≤ x ≤ 1 on c-sapphire, Si (100) and quartz substrates. Composition of the quantum dots was determined by means of transmission electron microscopy-energy dispersive X-ray analysis (TEM-EDAX) and X-ray photoelectron spectroscopy. Selected area electron diffraction reveals the growth of single phase hexagonal MgxZn1−xO quantum dots with composition 0 ≤ x ≤ 0.32 by using a nominal concentration of Mg in the range 0 to 45%. Onset of Mg concentration about 50% (nominal) forces the hexagonal lattice to undergo a phase transition from hexagonal to a cubic structure which resulted in the growth of hexagonal and cubic phases of MgxZn1−xO in the intermediate range of Mg concentrations 50 to 85% (0.39 ≤ x ≤ 0.77), whereas higher nominal concentration of Mg ≥ 90% (0.81 ≤ x ≤ 1) leads to the growth of single phase cubic MgxZn1−xO quantum dots. High resolution transmission electron microscopy and fast Fourier transform confirm the results and show clearly distinguishable hexagonal and cubic crystal structures of the respective quantum dots. A difference of 0.24 eV was detected between the core levels (Zn 2p and Mg 1s) measured in quantum dots with hexagonal and cubic structures by X-ray photoemission. The shift of these core levels can be explained in the frame of the different coordination of cations in the hexagonal and cubic configurations. Finally, the optical absorption measurements performed on single phase hexagonal MgxZn1−xO QDs exhibited a clear shift in optical energy gap on increasing the Mg concentration from 0 to 40%, which is explained as an effect of substitution of Zn2+ by Mg2+ in the ZnO lattice

Superconducting cuprates and magnetoresistive manganites: similarities and contrasts

We report on three different experiments on high temperature superconducting (HTS) cuprates and colossal magnetoresistive (CMR) manganites, which clearly bring out some of the important similarities and differences between the two material systems. The experiments involve the measurement of temperature dependence of the mean squared displacement of Cu and Mn ions from their equilibrium site in the case of the cuprates and the manganites, respectively, and their correlation with the transport property. In both cases the key ions in the materials (Cu for HTS and Mn for CMR) exhibit vibration amplitudes larger than that of ions in simple Debye solids and clearly show discontinuities in the vibration amplitudes as a function of temperature close to the phase transition temperatures. These point to the unequivocal participation of phonons in the transport processes and possibly in the onset of the phase transitions (i.e. superconductivity and ferromagnetism). The second set of experiments, involves femtosecond optical excitation of micro-strip resistors made of cuprates or manganites, and the subsequent measurement of the changes in the impedance on a 20 ps time scale. In the case of the manganites one measures the time scales involved in the ionization and reformation of a Jahn-Teller polaron and also the decay times of magnon excitors. In the case of the cuprates one sees a highly efficient pair breaking process with a very sharp resonance, with a width of only 100 meV, which is indicative of the role of a large intermediate excitation in the mechanism of high temperature superconductivity. In the third experiment, spin-polarized electrons injected from a manganite electrode into a superconductor are observed to break pairs at a rate far larger than unpolarized electrons. This effect seems very orientation dependent for the case of YBCO, which may shed new light on the transport of quasi-particles at YBCO interfaces