43 research outputs found
First Principle Evaluation of Photocatalytic Suitability for TiO2-Based Nanotubes
Water splitting under the influence of solar light on semiconducting electrodes Immersed in aqueous electrolyte is a potentially clean and renewable source for hydrogen fuel production. Its efficiency depends on relative position of the band gap edges (the visible light interval between infrared and ultraviolet (UV) ranges of electromagnetic spectrum corresponds to gap widths 1.5–2.8 eV) accompanied by a proper band alignment relative to both reduction (H+/H2) and oxidation (O2/H2O) potentials (−4.44 eV and −5.67 eV on energy scale for vacuum, respectively) which must be positioned inside the band gap. Its width for TiO2 anatase-structured bulk is experimentally found to be 3.2 eV, which corresponds to photocatalytic activity under UV light possessing only ~1% efficiency of sunlight energy conversion. Noticeable growth of this efficiency can be achieved by by adjusting the band gap edges for titania bulk through nanoscale transformation of its morphology to anatase-type nanotubes (NTs) (formed by folding of (001) or (101) nanothin TiO2 sheets consisting of 9 or 6 atomic layers and possessing either (n,0) or (−n,n) chiralities, respectively) accompanied by partial substitution of pristine atoms by CO, FeTi, NO and SO single dopants as well as NO+SO codopants. In the latter case, the band gap can be reduced down to 2.2 eV while the efficiency is achieved up to ~15%. The energy differences between the edges of band gap (VB and CB), the highest occupied and lowest unoccupied impurity levels inside the band gap (HOIL and LUIL, respectively) induced in doped NTs, while preserving the proper disposition of these levels relatively to the redox potentials, so that εVB<εHOIL<εO2/H2O<εH+/H2<εLUIL<εCB, thus reducing the photon energy required for dissociation of H2O molecule. In this chapter, we analyze applicability of large-scale first principle calculations on the doped single-wall titania NTs of different morphologies with the aim of establishment of their suitability for photocatalytic water splitting
Providing stable friction properties of disc brakes for railway vehicles
A new approach is developed to ensure the stability of the coefficient of friction at different braking modes for the entire speed range of braking high-speed ground transport. The new approach is a combination of friction materials with individual effort effects on the brake disc. A brake pad design and its performance are confirmed experimentally
The greenhouse index of sustainable development for metallurgical processes of production in aspect of green power
The accounting of greenhouse gases (GHG) according to plans of the Russian Federation becomes obligatory since 2016 for the enterprises with issue of GHG not less than 150 thousand tons of CO2, since 2017 – from 50 thousand tons of CO2. Introduction of a carbon tax (15 dollars/t of CO2) is planned. Voluntary inventory of GHG of the enterprises and territories which in the long term apply is carried out to be called clever. According to University of Cambridge (USA) about 45% depreciation of joint-stock portfolios in the world markets, the expected climate change connected with are expected. Parameter for an assessment of the clever city with the developed metallurgy and need of decrease in greenhouse emissions in the atmosphere – the indicator of a sustainable development considering emission of carbon dioxide, prime cost of steel and its power consumption is offered. Its values for tandems blast furnace (BF) + oxygen converter (OC), BF, Corex, Romelt, Midrex, Hyl-3 everyone with arc furnace (AF) are defined
Experimental Study of Crystal Channelling at CERN-SPS for Beam-Halo Cleaning
An efficient and robust collimation system is mandatory for any superconducting hadron collider, in particular for the LHC, which will store a beam of unprecedented high intensity and energy. The usage of highly efficient and short primary bent-crystal collimators might be a possibility for reaching nominal and ultimate LHC intensity. Over the last years, groups in Italy (Ferrara) and Russia (St. Petersburg) have developed crystal production methods, that considerably improve the crystal quality. These developments led, in turn, to a surprising increase in the channeling efficiency and to the recent observation of the âワvolume reflectionâ mechanism. The aim of the proposed experiment is the setup of a beam test facility, directing primary protons from the SPS onto a bent silicon crystal, and the quantitative study of single-pass efficiency for all involved processes. Final goal will be the extrapolation of important information on the feasibility of a crystal collimator for halo cleaning in the LHC. The experiment will be performed in the H8 beamline at the CERN SPS where a beam with very small divergence can be provided thus representing a unique facility for tests and characterization of crystals to be used for particle channeling studies
Strong reduction of the off-momentum halo in crystal assisted collimation of the SPS beam
A study of crystal assisted collimation has been continued at the CERN SPS for different energies of stored beams using 120 GeV/. c and 270 GeV/. c protons and Pb ions with 270 GeV/. c per charge. A bent silicon crystal used as a primary collimator deflected halo particles using channeling and directing them into the tungsten absorber. A strong correlation of the beam losses in the crystal and off-momentum halo intensity measured in the first high dispersion (HD) area downstream was observed. In channeling conditions, the beam loss rate induced by inelastic interactions of particles with nuclei is significantly reduced in comparison with the non-oriented crystal. A maximal reduction of beam losses in the crystal larger than 20 was observed with 270 GeV/. c protons. The off-momentum halo intensity measured in the HD area was also strongly reduced in channeling conditions. The reduction coefficient was larger than 7 for the case of Pb ions. A strong loss reduction was also detected in regions of the SPS ring far from the collimation area. It was shown by simulations that the miscut angle between the crystal surface and its crystallographic planes doubled the beam losses in the aligned crystal.peer-reviewe
Erratum to: "Double volume reflection of a proton beam by a sequence of two bent crystals" [Phys. Lett. B 658 (2008) 109]
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Comparative results on collimation of the SPS beam of protons and Pb ions with bent crystals
New experiments on crystal assisted collimation have been carried out at the CERN SPS with stored beams of 120 GeV/. c protons and Pb ions. Bent silicon crystals of 2 mm long with about 170 μrad bend angle and a small residual torsion were used as primary collimators. In channeling conditions, the beam loss rate induced by inelastic interactions of particles with the crystal nuclei is minimal. The loss reduction was about 6 for protons and about 3 for Pb ions. Lower reduction value for Pb ions can be explained by their considerably larger ionization losses in the crystal. In one of the crystals, the measured fraction of the Pb ion beam halo deflected in channeling conditions was 74%, a value very close to that for protons. The intensity of the off-momentum halo leaking out from the collimation station was measured in the first high dispersion area downstream. The particle population in the shadow of the secondary collimator-absorber was considerably smaller in channeling conditions than for amorphous orientations of the crystal. The corresponding reduction was in the range of 2-5 for both protons and Pb ions.peer-reviewe
Observation of parametric X-rays produced by 400 GeV/c protons in bent crystals
Spectral maxima of parametric X-ray radiation (PXR) produced by 400 GeV/c protons in bent silicon crystals aligned with the beam have been observed in an experiment at the H8 external beam of the CERN SPS. The total yield of PXR photons was about 10-6 per proton. Agreement between calculations and the experimental data shows that the PXR kinematic theory is valid for bent crystals with sufficiently small curvature as used in the experiment. The intensity of PXR emitted from halo protons in a bent crystal used as a primary collimator in a circular accelerator may be considered as a possible tool to control its crystal structure, which is slowly damaged because of irradiation. The intensity distribution of PXR peaks depends on the crystal thickness intersected by the beam, which changes for different orientations of a crystal collimator. This dependence may be used to control crystal collimator alignment by analyzing PXR spectra produced by halo protons.peer-reviewe
The Influence of Political Connection and Institutions to the Performance and Bank Loans of Private Listed Companies
我国有着不同于西方发达国家的制度背景和政治制度,政府对市场的管制力度较大,上市公司的高管具有一定的政治背景,其中国有企业本身大股东的政府背景性质,其政治关联很可能是与生俱来的,而民营企业政治关联的形成则具有主动性。改革开放以来,民营经济不断发展壮大,己成为我国经济增长的主要推动力量,因此,研究政治关联对民营公司的影响这一问题在中国更具有现实启发意义。 本文以民营上市公司的高级管理人员是否是前任或现任的政府官员、人大代表或政协委员来衡量公司是否具有政治关联,选取2004年—2008年中国沪深两市所有A股民营上市公司为样本,实证研究了政治关联与制度环境对民营上市公司经营绩效和银行贷款的影响。研究...Chinese current institution and political system are different from the Western developed countries. Under this system, many executives of private listed companies are relevant to politics. Therefore the study of political influence of private companies related to this issue in China is more realistic instructive. This paper focuses on whether the company has the political connection, which measu...学位:管理学硕士院系专业:管理学院财务学系_财务学学号:1762007115174