9 research outputs found
Colloidal BaZrS3 chalcogenide perovskite nanocrystals for thin film device fabrication
The theoretical optoelectronic properties of chalcogenide perovskites (e.g., BaZrS3) are as good as those of halide perovskites (e.g., CH3NH3PbI3). But the fabrication of optoelectronic devices is rarely reported, mainly because researchers still do not know how to prepare good quality thin films of chalcogenide perovskites. Here, we report colloidal BaZrS3 nanocrystals (NCs, 40-60 nm) and their solution processed thin film transistors. BaZrS3 NCs are first prepared using a solid-state synthesis route, and the subsequent surface modifications lead to a colloidal dispersion of NCs in both polar N-methyl-2-pyrrolidinone and non-polar chloroform solvents. The NCs exhibit good thermal (15-673 K) and aqueous stability. Colloidal BaZrS3 NCs in chloroform are then used to make field effect transistors showing ambipolar properties with a hole mobility of 0.059 cm(2) V-1 s(-1) and an electron mobility of 0.017 cm(2) V-1 s(-1). This report of solution processed chalcogenide perovskite thin films with reasonable carrier mobility and optical absorption and emission is expected to pave the way for future optoelectronic devices of chalcogenide perovskites.11Nsciescopu
Curcumin-Based Pyrazoline Analogues As Selective Inhibitors Of Human Monoamine Oxidase A
A series of 2-methoxy-4-(5-phenyl-4,5-dihydro-1H-pyrazol-3-yl)phenol (pyrazoline) derivatives (2-6) have been synthesized and tested for human monoamine oxidase (hMAO) inhibitory activity. The most active derivative (2) behaved as a competitive hMAO-A inhibitor, with an inhibition constant value of 0.08 M and a strong hMAO-A selectivity (K-i(hMAO-B)/K-i(hMAO-A) > 1751). In addition, 2 exhibited little to no cytotoxic effects up to a 25 M concentration and provided the best blood-brain barrier permeability among the derivatives synthesized. Molecular dynamics simulations revealed that a chlorine substituent at the para-position of the phenyl ring in 2 enabled a - stacking interaction with Tyr407 and Tyr444 that resulted in the formation of an aromatic sandwich structure. Consequently, this tight-binding aromatic cage culminated in a dramatically reduced active site volume that is believed to be the origin of the observed selectivity between the hMAO-A and hMAO-B isozymes. Removal of the chlorine from 2 disrupted the favorable intermolecular interactions and resulted in a selectivity change towards hMAO-B
Unlocking the Potential of Single Atoms Loaded Geobacter Hybrid Catalyst as Bifunctional Electrocatalyst for Water Splitting
Single-atom metal (SA-M) catalysts with high dispersion of active metal sites allow maximum atomic utilization. However, conventional synthesis of SA-M catalysts involves high-temperature treatments, leading to a low yield with random distribution of atoms. Herein, a facile method to synthesize SA-M catalysts (M = Fe, Ir, Pt, Ru, Cu, or Pd) in a single step at ambient temperature, using the extracellular electron transfer capability of Geobacter sulfurreducens (GS), is presented. Interestingly, the SA-M is coordinated to three nitrogen (N) atoms adopting an MN3 on the surface of GS. Dry samples of SA-Ir@GS without further heat treatments show exceptionally high activity for OER when compared to benchmark IrO2 catalyst and comparable HER activity to commercial 10 wt.% Pt/C. The SA-Ir@GS electrocatalyst exhibits the best water‐splitting performance compared to other SA-M@GS, showing a low applied potential of 1.65 V to achieve 10 mA cm−2 in 1.0 M KOH solution with cycling over 5 h. The density functional calculations reveal that the large adsorption energy of H2O and moderate adsorption energies of reactants and reaction intermediates for SA-Ir@GS favorably improve its activity. This nature-based facile synthesis method of SA-M at room temperature provides a versatile platform for the preparation of other transition metal SA-M catalysts for various energy-related applications by merely altering the metal precursors. <br /
A Convenient Route for Au@Ti–SiO<sub>2</sub> Nanocatalyst Synthesis and Its Application for Room Temperature CO Oxidation
Small
gold nanoparticles of size less than 5 nm encapsulated inside
titanium modified silica shell have been reported. Here, a modified
sol–gel method, which is a one-step process, produces Au@Ti–SiO<sub>2</sub> nanocatalyst with a good control of titanium loading. With
a titanium loading of 0.9 and 2.2 wt % in silica, unprecedented low
temperature activity (full conversion) is observed for this catalyst
for CO oxidation reaction compared to Au@SiO<sub>2</sub> catalyst.
A combination of optimum sized gold nanoparticles with a large amount
of oxygen vacancies created due to Ti incorporation in silica matrix
is considered to be the reason for this enhanced catalytic activity.
The size of gold nanoparticles is maintained even after high temperature
pretreatments, which show the benefit of encapsulation. The effect
of the various pretreatments on the catalytic activity has also been
reported
Anisotropic phenanthroline-based ruthenium polymers grafted on a titanium metal-organic framework for efficient photocatalytic hydrogen evolution
Combining conjugated polymers with transition-metal-based metal-organic frameworks offers an opportunity to produce efficient photocatalytic materials. Here, exposed active sites and efficient charge transfer lead to hydrogen evolution rates of up to 2438 µmol g−1 h−1 for composites of anisotropic phenanthroline-based ruthenium polymers grafted on titanium-based MOFs
Size-Induced Structural Phase Transition at ∼6.0 nm from Mixed fcc–hcp to Purely fcc Structure in Monodispersed Nickel Nanoparticles
We
have investigated the core issue of atomic lattices in monodispersed
Ni nanoparticles (NPs) of sizes 3.8–10.1 nm using detailed
analysis of X-ray diffraction, synchrotron radiation X-ray absorption
spectroscopy, and magnetization data. This has revealed the very remarkable
coexistence of atomic face-centered cubic (fcc) and hexagonal closed-packed
(hcp) lattices in samples with particle size ≤ 6.0 nm with
the prevalence of only fcc phase beyond this. They are also associated
with reduced coordination number, modified electronic structure, and
surface atom coordination with ligands. Magnetization data furthermore
reveal the coexistence of ferromagnetism and superparamagnetism at
300 K. Considered to be due to dominant roles of ligands, they are
likely to open up far-reaching implications to their future applications
Nitrogen Doping in Oxygen-Deficient Ca<sub>2</sub>Fe<sub>2</sub>O<sub>5</sub>: A Strategy for Efficient Oxygen Reduction Oxide Catalysts
Oxygen
reduction reaction (ORR) is increasingly being studied in oxide systems
due to advantages ranging from cost effectiveness to desirable kinetics.
Oxygen-deficient oxides like brownmillerites are known to enhance
ORR activity by providing oxygen adsorption sites. In parallel, nitrogen
and iron doping in carbon materials, and consequent presence of catalytically
active complex species like C–Fe–N, is also suggested
to be good strategies for designing ORR-active catalysts. A combination
of these features in N-doped Fe containing brownmillerite can be envisaged
to present synergistic effects to improve the activity. This is conceptualized
in this report through enhanced activity of N-doped Ca<sub>2</sub>Fe<sub>2</sub>O<sub>5</sub> brownmillerite when compared to its oxide
parents. N doping is demonstrated by neutron diffraction, UV–vis
spectroscopy, X-ray photoelectron spectroscopy, and X-ray absorption
spectroscopy. Electrical conductivity is also found to be enhanced
by N doping, which influences the activity. Electrochemical characterization
by cyclic voltammetry, rotating disc electrode, and rotating ring
disk electrode (RRDE) indicates an improved oxygen reduction activity
in N-doped brownmillerite, with a 10 mV positive shift in the onset
potential. RRDE measurements show that the compound exhibits 4-electron
reduction pathways with lower H<sub>2</sub>O<sub>2</sub> production
in the N-doped system; also, the N-doped sample exhibited better stability.
The observations will enable better design of ORR catalysts that are
stable and cost-effective