Soy protein enzymatic hydrolysis and polysaccharides interactions: differential performance on kinetic adsorption at air-water interface

The objective of the work was to study the impact of soy protein hydrolysis on kinetic adsorption to the air-water interface and the effect of polysaccharides addition. Was used soy protein (SP) and theirs hydrolysates of 2% (H1) and 5.4% (H2) degree of hydrolysis. The polysaccharides (PS) used were a surface active one called E4M and a non-surface active one, lamda carrageenan (C). The dynamic surface pressure of interfacial films was evaluated with a drop tensiometer. In this contribution, we have determined the kinetic parameters of adsorption to the air-water interface which determined the penetration (Kp) and rearrangement (Kr) rates of SP, H1, H2 and PS, as well as their mixed systems. It was observed an increase of Kp and Kr when the protein were hydrolyzed (from SP to H1), however, when degree of hydrolysis progresses to H2 the parameters decreased again. In other hand, considerable differences were not found between these two PS studied concerning the Kp to air-water interface at these conditions. In spite of the different surface active nature of the PS, the proteins seem to control the behavior of the protein-PS interactions. However, when Kr of mixed systems was analyzed, the degree of hydrolysis and PS nature started to have a huge importance. Hence, it could be observed synergic or antagonic effects on Kr of biopolymers at liquid interface depending to the degree of hydrolysis of protein analyzed and the type of PS selected.CYTED through project 105PI0274CYCYT through grant AGL2007-60045Junta de Andalucía through grant PO6-AGR-01535Universidad de Buenos Aires, Agencia Nacional de Promoción Científica y Tecnológica (PICT 2008-1901) and Consejo Nacional de Investigaciones Científicas y Técnicas de la República Argentin

Ensayos de dinteles de fábrica de ladrillo atirantada sobre los nuevos Apoyos Pi, distanciados 6m entre sí

Comunicación presentada en las II Jornadas de Investigación en Construcción: "60 años de Informes de la Construcción", celebradas los pasados 22, 23 y 24 de mayo de 2008 en el Instituto "Eduardo Torroja" de Ciencias de la Construcción (IETCC-CSIC) de Madrid.Comparando la Arquitectura de Ladrillos del s.XIX con el empleo del ladrillo en la Arquitectura del s.XX, se puede observar que abunda mayor patología en las fábricas de ladrillo cara vista recientes que en las más antiguas. El primer paso para prevenir la abundante fisuración de la albañilería apreciada en España a finales del siglo pasado, se dio en 1992, con la realización del "Manual Murfor: La fábrica armada", estableciéndose en él los criterios posteriormente contemplados en el "Eurocódigo 6: Estructuras de Fábrica", de recomendar armar con el 0,03% de la sección del muro, y a distancias verticales no mayores de 600mm. Las primeras aplicaciones arquitectónicas de la fábrica armada en España, fueron realizadas por este Arquitecto en sus obras de la Plaza de la Remonta y de El Espinillo, divulgándose por su potencial arquitectónico, tanto en Europa como en América.En este artículo se retoman las posibilidades del incremento de prestaciones de la fábrica armada Murfor con "arcos atirantados ciegos de gran luz", establecidas por primera vez en el Manual español, lo que permite salvar 6m de luz con solamente 2 armaduras Murfor de 5mm de diámetro en la parte inferior de los dinteles.Los autores agradecen la inestimable colaboración de los Institutos de Investigación IBAC de Aachen (Alemania) y el I.E. Torroja de Madrid (España), por haber hecho posible esta interesante colaboración investigadora europea de valor internacional.Peer reviewe

Rift-related volcanism predating the birth of the Rheic Ocean

Two very different periods of magma emplacement in the crust of the Ossa-Morena zone (early and main events) in SW Iberia have been previously interpreted to record a Cambrian/Early Ordovician rifting event that is thought to have culminated in the opening of the Rheic Ocean during the Early Ordovician. New stratigraphic, petrographic, geochemical and Sm–Nd isotope data from Cambrian volcanic rocks included in six key low-grade sections in both Portugal and Spain considerably improve our understanding of these events. These data: (1) confirm the existence of two rift-related magmatic events in the Cambrian of the Ossa-Morena zone, (2) demonstrate that the early rift-related event was associated with migmatite and core-complex formation in the mid-upper crust and is represented by felsic peraluminous rocks, the parent magmas of which were derived mainly from crustal sources, and (3) show the main rift-related event to be represented by a bimodal association of felsic and mafic rocks with minor amounts of intermediate rocks. Some of the mafic rocks show N-MORB affinity, whereas others have OIB or E-MORB affinities, suggesting different heterogeneous mantle sources (depleted and enriched, asthenospheric and lithospheric, plume-like and non-plume-like). The acid and intermediate rocks appear to represent hybrid mixtures of crust and mantle-derived magmas. This new data supports the hypothesis that the onset of rifting was associated with a process of oblique ridgetrench collision. We interpret the significant differences between the early and main events as reflecting the evolution froma wide rift stagewith passive extensionmainly accommodated by lower-crust flowin a high heatflow setting, to a narrow rift stage with active extension characterized by extension rates that outpaced thermal diffusion rates

Monitoring of hazardous substances at Alcantarilha’s WTP, Portugal

A monitoring programme of hazardous substances was implemented in Alcantarilha’s water treatment plant (Algarve, Portugal) since 2002, in addition to the legally established monitoring of standard physical, chemical and microbiological parameters. The objective of this programme was to ensure the drinking water quality regarding the waterborne disease organisms Cryptosporidium, Giardia, Salmonella, Pseudomonas aeruginosa, enterovirus and cyanobacteria, and the potentially harmful chemicals aluminium, cyanotoxins, and disinfection by-products (THM) and their precursors (TOC, DOC, UV254nm, SUVA). Most of these parameters are new and still not regulated by the Portuguese and the European legislation. Data presented in this study refer to the period of August 2002 to October 2003. Results show that, despite the seasonal variations of the raw water quality, concentrations of the hazardous substances in the supplied drinking water were far below the legal standards and the WHO’s and EPA guideline values, demonstrating the high removal efficiencies of this treatment plant

Is eco-efficiency in greenhouse gas emissions converging among European Union countries?

Eco-efficiency refers to the ability to produce more goods and services with less impact on the environment and less consumption of natural resources. This issue has become a matter of concern that is receiving increasing attention from politicians, scientists and researchers. Furthermore, greenhouse gases emitted as a result of production processes have a marked impact on the environment and are also the foremost culprit of global warming and climate change. This paper assesses convergence in eco-efficiency in greenhouse gas emissions in the European Union. Eco-efficiency is assessed at both country and greenhouse-gas-specific levels using Data Envelopment Analysis techniques and directional distance functions, as recently proposed by Picazo-Tadeo et al. (Eur J Oper Res, 220:798–809, 2012). Convergence is then evaluated using the Phillips and Sul (Econometrica, 75:1771–1855, 2007) approach that allows testing for the existence of convergence groups. Although the results point to the existence of different convergence clubs depending on the specific pollutant considered, they signal the existence of at least four clear groups of countries. The first two groups are core European Union high-income countries (Benelux, Germany, Italy, Austria, the United Kingdom and Scandinavian countries). A third club is made up of peripheral countries (Spain, Ireland, Portugal and Greece) together with some Eastern countries (Latvia and Slovenia), while the remaining clubs consist of groups containing Eastern European countries

Health needs and masculinities: primary health care services for men

Estudam-se relações entre masculinidades e cuidado em saúde, abordando o reconhecimento de necessidades por homens usuários de atenção primária e respostas dos serviços. É parte de pesquisa realizada em quatro estados brasileiros, com oito serviços amostrados por conveniência. Triangulou-se observação etnográfica com entrevistas semi-estruturadas com 182 usuários de 15 a 65 anos e com 72 profissionais. A análise temática dos registros etnográficos e das entrevistas foi baseada nos referenciais de gênero e em estudos do trabalho em saúde. Os resultados apontam como a medicalização das necessidades de saúde marca usuários, profissionais e serviços, ocultando questões vinculadas à masculinidade. Permitem caracterizar a atenção primária como voltada para as mulheres, reproduzindo no funcionamento dos serviços e nos desempenhos profissionais as desigualdades de gênero, em que para as mulheres há a disciplina do cuidado e para os homens, impropriedades para assistir e cuidar.This study deals with the relations between masculinities and health care, approaching the recognition of health needs among male users of primary health care and the responses by the services. The study is part of a larger research project in four Brazilian States, with a convenience sample of eight health services. Ethnographic observation was compared with semi-structured interviews with 182 health care users from 15 to 65 years of age and 72 health professionals. Thematic analysis of the ethnographic records and interviews was based on gender references and studies on health work. The findings show how medicalization of health needs affects users, professionals, and services, disguising issues related to masculinity. Primary care focuses mainly on women, thereby reproducing gender inequalities in health services operations and professional performance, with women receiving disciplined care and men receiving insufficient attention and care

Initial test of "BabyRobot" behaviour on a teleoperated toy substitution: improving the motor skills of toddlers

This article introduces “Baby Robot”, a robot designed to improve infants’ and toddlers’ motor skills. This robot is a car-like toy that moves autonomously by using reinforcement learning and computer vision. Its behaviour consists of escaping from a target infant that has been previously recognized, or at least detected, without compromising the infant’s security by avoiding obstacles. Regarding other robots that share this purpose, there is a variety of commercial toys available on the market; however, no one is betting on an intelligent autonomous movement, since they use to repeat simple, yet repetitive movements. In order to examine how that autonomous movement may improve infants’ mobility, two crawling toys –one in representation of “Baby Robot”– were tested in a real environment. These real-life experiments were conducted with a safe and approved surrogate of our proposed robot in a kindergarten, where a group of infants interacted with the toys. Improvements in the efficiency of the play-session were detected.Peer ReviewedObjectius de Desenvolupament Sostenible::5 - Igualtat de GènereObjectius de Desenvolupament Sostenible::10 - Reducció de les DesigualtatsObjectius de Desenvolupament Sostenible::3 - Salut i BenestarObjectius de Desenvolupament Sostenible::4 - Educació de QualitatPostprint (published version

The electrode-electrolyte interface in CO2 reduction and H2 evolution: a multiscale approach

Electrocatalysis allows for storing electricity or converting it into chemical bonds, producing chemical building blocks and fuels using renewable resources. Therefore, it plays an important role in the transition towards a more sustainable future for our society through electrification. Still, to bring electrochemical technologies to industrial scale and make them competitive, optimization of various aspects of electrocatalytic reactions are needed. Many fundamental studies focus on understanding the catalyst surface, however, different components of the electrolyte, as pH and cations, have also shown to significantly affect the reaction activity and selectivity. In view of that, in this thesis, various aspects of the electrode-electrolyte interface are studied at different scales, using Scanning Electrochemical Microscopy (SECM), stationary and rotating-disc electrode voltammetry techniques, and bulk electrolysis.The work presented in this thesis was supported by the European Commission, as part of the Marie Skłodowska Curie Innovative Training Network ELCoREL-722614Catalysis and Surface Chemistr