12,693 research outputs found
Automatic learning of gait signatures for people identification
This work targets people identification in video based on the way they walk
(i.e. gait). While classical methods typically derive gait signatures from
sequences of binary silhouettes, in this work we explore the use of
convolutional neural networks (CNN) for learning high-level descriptors from
low-level motion features (i.e. optical flow components). We carry out a
thorough experimental evaluation of the proposed CNN architecture on the
challenging TUM-GAID dataset. The experimental results indicate that using
spatio-temporal cuboids of optical flow as input data for CNN allows to obtain
state-of-the-art results on the gait task with an image resolution eight times
lower than the previously reported results (i.e. 80x60 pixels).Comment: Proof of concept paper. Technical report on the use of ConvNets (CNN)
for gait recognition. Data and code:
http://www.uco.es/~in1majim/research/cnngaitof.htm
Effects of introgressed 4Nv Aegilops ventricosa chromosome on yield and yield components in bread wheat.
Effects of introgressed 4Nv Aegilops ventricosa chromosome on yield and yield components in bread whea
Theoretical and experimental SERS study of thiocarbonyl compounds adsorbed on metal nanoparticles
Thiocarbonyl compounds have been reported to exhibit interesting biological and pharmacological properties but they are many often characterized by their toxicological effects. However the chemistry of thiobenzoic acid (TBA) and thiobenzamide (TB) has not been fully studied yet. Some of the biological studies of TBA are related to the tautomerism of thiocarboxylic acids and the important role that the -C(=O)-S and -C(=S)-O functional groups play in the catalytic activities of enzymes such as cysteine or serine proteases.1
From a chemical point of view, thiocarboxylates are an interesting type of molecules having two different donor atoms, a soft sulfur donor atom and a hard oxygen donor one. The presence of these unlike groups can lead to the bonding with metal surfaces. Likewise the interaction of thiobenzamide and their derivatives with metals is of great interest because both the sulfur and nitrogen atoms are also able to coordinate with the surface. Therefore the high affinity of these molecules for metal surfaces makes them suitable SERS target adsorbates. Taking advantage of the fact that SERS spectroscopy is both surface selective and highly sensitive we have attempted to determine the molecular structure of TBA and TB once they are adsorbed on the metal. The main objective of this work is focussed on discussing the observed vibrational wavenumber shifts of TBA and TB upon adsorption on silver nanoparticles. In this work the SERS substrates have been prepared by using different colloidal silver solutions according to the method described by Creighton et al.2 and Leopold and Lendl.3
The analysis of the vibrational wavenumbers shifts of the Raman and SERS spectra allow us to know the adsorption process (Figure 1). In the case of TBA, the wavenumber of the SERS band assigned to (C=O) vibrational mode shows an important blue shift up to 40 cm-1 with respect to the Raman whereas the (C-S) band undergoes a red shift up to 40 cm-1. These results suggest a unidentate coordination of TBA to the silver surface through the sulfur atom.
On the other hand, the SERS band assigned in the case of TB to Amide III (mainly (CN)) exhibits a significant blueshift up to 41 cm-1, and the SERS band assigned to Amide I (mainly (CS)) shows a red shift up to 11 cm-1. These wavenumber shifts indicate that TB interacts to the silver surface through the sulfur atom. Interestingly, in previous SERS studies of pyridinecarboxamides and benzamide we have observed that some SERS bands assigned to 1;ring, Amide I (mainly (C=O)) and Amide III (mainly C-N)) show wavenumber shifts of +50, -50 and +10 cm-1, respectively, which were attributed to the deprotonation of carboxamide group.4,5
Finally, in order to verify experimental results DFT calculations have been carried out for different silver complexes of TBA and TB concluding that the unidentate coordination is the most likely interaction of both of them.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech
Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene
Indexación: ScieloThis work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000300014&lng=es&nrm=is
Modulation of Cytokine and Cytokine Receptor/Antagonist by Treatment with Doxycycline and Tetracycline in Patients with Dengue Fever
Dengue virus infection can lead to dengue fever (DF) or dengue hemorrhagic fever (DHF). Disease severity has been linked to an increase in various cytokine levels. In this study, we evaluated the effectiveness of doxycycline and tetracycline to modulate serum levels of IL-6, IL-1B, and TNF and cytokine receptor/receptor antagonist TNF-R1 and IL-1RA in patients with DF or DHF. Hospitalized patients were randomized to receive standard supportive care or supportive care combined with doxycycline or tetracycline therapy. Serum cytokine and cytokine receptor/antagonist levels were determined at the onset of therapy and after 3 and 7 days. Cytokine and cytokine receptor/antagonist levels were substantially elevated at day 0. IL-6, IL-1β, and TNF remained at or above day 0 levels throughout the study period in untreated patients. Treatment with tetracycline or doxycycline resulted in a significant decline in cytokine levels. Similarly, IL-1RA and TNF-R1 serum concentrations were elevated at baseline and showed a moderate increase among untreated patients. Both drugs resulted in a significant rise in IL-1Ra levels by day 3 in patients. In contrast, treatment did not affect a similar result for TNF-R1. When compared to the control group, however, a significant rise post-treatment was seen upon intragroup analysis. Further analysis demonstrated that doxycycline was significantly more effective at modulating cytokine and cytokine receptor/antagonist levels than tetracycline
Thermodynamics of Higher Spin Black Holes in AdS
We discuss the thermodynamics of recently constructed three-dimensional
higher spin black holes in SL(N,R)\times SL(N,R) Chern-Simons theory with
generalized asymptotically-anti-de Sitter boundary conditions. From a
holographic perspective, these bulk theories are dual to two-dimensional CFTs
with W_N symmetry algebras, and the black hole solutions are dual to thermal
states with higher spin chemical potentials and charges turned on. Because the
notion of horizon area is not gauge-invariant in the higher spin theory, the
traditional approaches to the computation of black hole entropy must be
reconsidered. One possibility, explored in the recent literature, involves
demanding the existence of a partition function in the CFT, and consistency
with the first law of thermodynamics. This approach is not free from
ambiguities, however, and in particular different definitions of energy result
in different expressions for the entropy. In the present work we show that
there are natural definitions of the thermodynamically conjugate variables that
follow from careful examination of the variational principle, and moreover
agree with those obtained via canonical methods. Building on this intuition, we
derive general expressions for the higher spin black hole entropy and free
energy which are written entirely in terms of the Chern-Simons connections, and
are valid for both static and rotating solutions. We compare our results to
other proposals in the literature, and provide a new and efficient way to
determine the generalization of the Cardy formula to a situation with higher
spin charges.Comment: 30 pages, PDFLaTeX; v2: typos corrected, explicit expressions for the
free energy adde
Characterization of a putative grapevine Zn transporter, VvZIP3, suggests its involvement in early reproductive development in Vitis vinifera L
Gonzalez, E (reprint author), Univ Talca, Inst Biol Vegetal & Biotecnol, Talca, Chile.Background: Zinc (Zn) deficiency is one of the most widespread mineral nutritional problems that affect normal development in plants. Because Zn cannot passively diffuse across cell membranes, it must be transported into intracellular compartments for all biological processes where Zn is required. Several members of the Zinc-regulated transporters, Iron-regulated transporter-like Protein (ZIP) gene family have been characterized in plants, and have shown to be involved in metal uptake and transport. This study describes the first putative Zn transporter in grapevine. Unravelling its function may explain an important symptom of Zn deficiency in grapevines, which is the production of clusters with fewer and usually smaller berries than normal.
Results: We identified and characterized a putative Zn transporter from berries of Vitis vinifera L., named VvZIP3. Compared to other members of the ZIP family identified in the Vitis vinifera L. genome, VvZIP3 is mainly expressed in reproductive tissue - specifically in developing flowers - which correlates with the high Zn accumulation in these organs. Contrary to this, the low expression of VvZIP3 in parthenocarpic berries shows a relationship with the lower Zn accumulation in this tissue than in normal seeded berries where its expression is induced by Zn. The predicted protein sequence indicates strong similarity with several members of the ZIP family from Arabidopsis thaliana and other species. Moreover, VvZIP3 complemented the growth defect of a yeast Zn-uptake mutant, ZHY3, and is localized in the plasma membrane of plant cells, suggesting that VvZIP3 has the function of a Zn uptake transporter.
Conclusions: Our results suggest that VvZIP3 encodes a putative plasma membrane Zn transporter protein member of the ZIP gene family that might play a role in Zn uptake and distribution during the early reproductive development in Vitis vinifera L., indicating that the availability of this micronutrient may be relevant for reproductive development
Suplementación de raciones para cebo intensivo de terneros con aceites vegetales: rendimientos productivos, calidad de la canal, de la grasa y de la carne
Se han estudiado los efectos de la incorporación de aceites de origen vegetal sobre los rendimientos productivos,
calidad de la canal y de la grasa en el ganado vacuno. Se utilizaron 240 terneros agrupados en 24 lotes de 10 terneros
cada uno. Las raciones experimentales fueron: Tratamiento Control (4% de aceite de palma), Oliva (4,8% de jabón cálcico
de aceite de oliva), Soja (4% de aceite de soja). De cada lote se seleccionó al azar un ternero (8 terneros por tratamiento)
para diseccionar su 6ª costilla. No se han observado diferencias significativas entre tratamientos para ningún parámetro
productivo ni de calidad de la canal. Los animales que consumieron aceite de oliva presentaron un mayor contenido
(P=0,09) en C18:2 cis-9, trans-11 CLA en la grasa intramuscular que los que consumieron palma
Suplementación de raciones para cebo intensivo de terneros con aceites vegetales: calidad de carne
Se han estudiado los efectos de la incorporación de aceites de origen vegetal sobre la calidad de carne en el ganado vacuno. Se utilizaron 240 terneros agrupados en 24 lotes de 10 terneros cada uno. Las raciones experimentales fueron: Tratamiento Control (4% de aceite de palma), Oliva (4,8% de jabón cálcico de aceite de oliva), Soja (4% de aceite de soja). De cada lote se seleccionó al azar un ternero (8 terneros por tratamiento) para diseccionar su 6ª costilla. Se tomaron medidas de pH, color y textura del músculo Longissimus dorsi. Por último se realizó un análisis sensorial mediante un panel de catadores en el que se analizaron los parámetros de olor, textura y flavor de la carne. La carne de los animales alimentados con aceite de palma (Control) presentó el valor más alto (P0,05). En el análisis sensorial de la carne no se han observado diferencias significativas en los parámetros estudiados
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