Strong Homotopy Lie Algebras, Generalized Nahm Equations and Multiple M2-branes

We review various generalizations of the notion of Lie algebras, in particular those appearing in the recently proposed Bagger-Lambert-Gustavsson model, and study their interrelations. We find that Filippov's n-Lie algebras are a special case of strong homotopy Lie algebras. Furthermore, we define a class of homotopy Maurer-Cartan equations, which contains both the Nahm and the Basu-Harvey equations as special cases. Finally, we show how the super Yang-Mills equations describing a Dp-brane and the Bagger-Lambert-Gustavsson equations supposedly describing M2-branes can be rewritten as homotopy Maurer-Cartan equations, as well.Comment: 1+28 page

Affine invariant conditions for the topological distinction of quadratic systems with a critical point of the 4th multiplicity

The affine invariant partition of the set of quadratic systems with one finite singular point of the 4th multiplicity with respect to different topological classes is accomplished. The conditions corresponding to this partition are semi-algebraic, i.e. they are expressed as equalities or inequalities between polynomials

Dissolution and phosphate-induced transformation of ZnO nanoparticles in synthetic saliva probed by AGNES without previous solid-liquid separation. Comparison with UF-ICP-MS

The variation over time of free Zn2+ ion concentration in stirred dispersions of ZnO nanoparticles (ZnO NPs) prepared in synthetic saliva at pH 6.80 and 37 degrees C was followed in situ (without solid liquid separation step) with the electroanalytical technique AGNES (Absence of Gradients and Nernstian Equilibrium Stripping). Under these conditions, ZnO NPs are chemically unstable due to their reaction with phosphates. The initial stage of transformation (around 5-10 h) involves the formation of a metastable solid (presumably ZnHPO4), which later evolves into the more stable hopeite phase. The overall decay rate of ZnO NPs is significantly reduced in comparison with phosphate-free background solutions of the same ionic strength and pH. The effective equilibrium solubilities of ZnO (0.29-0.47 mg.L-1), as well as conditional excess-ligand stability constants and fractional distributions of soluble Zn species, were determined in the absence and presence of organic components. The results were compared with the conventional ultrafiltration and inductively coupled plasma-mass spectrometry (UF-ICP-MS) methodology. AGNES proves to be advantageous in terms of speed, reproducibility, and access to speciation information. KeywordsThis work was supported by the Spanish Ministry MINECOunder Grant No. CTM2016-78798 and European UnionSeventh Framework Programme FP7-NMP.2012.1.3-3 underGrant No. 310584 (NANoREG). FQ gratefully acknowledgesa grant from AGAUR

Dynamics of trace metal sorption by an ion-exchange chelating resin described by a mixed intraparticle/film diffusion transport model. The Cd/Chelex case

The time-evolution of Cd2+ ion sorption by Chelex 100 resin was studied in batch experiments as a function of time, pH, ionic strength, stirring rate, mass of resin and initial metal ion concentration. In the experimental conditions, the amount of resin sites are in excess with respect to the amount of metal ion, leading to extensive depletion of metal in bulk solution when equilibrium is reached. The data were described using a mixed control mass transport model in finite volume conditions (MCM) that includes explicitly both intraparticle and film diffusion steps. Exact numerical computations and a new approximate analytical expression of this model are reported here. MCM successfully predicts the influence of pH and ionic strength on the experimental Cd(II)/Chelex kinetic profiles (which cannot be justified by a pure film diffusion controlled mechanism) with a minimum number of fitting parameters. The overall diffusion coefficient inside the resin was modelled in terms of the Donnan factor and the resin/cation binding stability constant. The values of the latter coefficient as a function of pH and ionic strength were estimated from the Gibbs-Donnan model. Even though MCM is numerically more involved than models exclusively restricted to film or intraparticle diffusion control, it proves to be accurate in a wider range of values of the mass transfer Biot number and solution/resin metal ratios.The authors gratefully acknowledge support for this research from the Spanish Ministry MINECO (Projects CTM2013-48967 and CTM2016-78798) and by the “Comissionat d'Universitats i Recerca de la Generalitat de Catalunya” (2014SGR1132). FQ acknowledges a grant from AGAUR

Exact N=2 Supergravity Solutions With Polarized Branes

We construct several classes of exact supersymmetric supergravity solutions describing D4 branes polarized into NS5 branes and F-strings polarized into D2 branes. These setups belong to the same universality class as the perturbative solutions used by Polchinski and Strassler to describe the string dual of N=1* theories. The D4-NS5 setup can be interpreted as a string dual to a confining 4+1 dimensional theory with 8 supercharges, whose properties we discuss. By T-duality, our solutions give Type IIB supersymmetric backgrounds with polarized branes.Comment: 22 pages. v2 - references added, details clarifie

Lagrangian Variational Framework for Boundary Value Problems

A boundary value problem is commonly associated with constraints imposed on a system at its boundary. We advance here an alternative point of view treating the system as interacting "boundary" and "interior" subsystems. This view is implemented through a Lagrangian framework that allows to account for (i) a variety of forces including dissipative acting at the boundary; (ii) a multitude of features of interactions between the boundary and the interior fields when the boundary fields may differ from the boundary limit of the interior fields; (iii) detailed pictures of the energy distribution and its flow; (iv) linear and nonlinear effects. We provide a number of elucidating examples of the structured boundary and its interactions with the system interior. We also show that the proposed approach covers the well known boundary value problems.Comment: 41 pages, 3 figure

A semi-grand canonical Monte Carlo simulation model for ion binding to ionizable surfaces: proton binding of carboxylated latex particles as a case study

In this paper, we present a computer simulation study of the ion binding process at an ionizable surface using a semi-grand canonical Monte Carlo method that models the surface as a discrete distribution of charged and neutral functional groups in equilibrium with explicit ions modelled in the context of the primitive model. The parameters of the simulation model were tuned and checked by comparison with experimental titrations of carboxylated latex particles in the presence of different ionic strengths of monovalent ions. The titration of these particles was analysed by calculating the degree of dissociation of the latex functional groups vs. pH curves at different background salt concentrations. As the charge of the titrated surface changes during the simulation, a procedure to keep the electroneutrality of the system is required. Here, two approaches are used with the choice depending on the ion selected to maintain electroneutrality: counterion or coion procedures. We compare and discuss the difference between the procedures. The simulations also provided a microscopic description of the electrostatic double layer (EDL) structure as a function of p H and ionic strength. The results allow us to quantify the effect of the size of the background salt ions and of the surface functional groups on the degree of dissociation. The non-homogeneous structure of the EDL was revealed by plotting the counterion density profiles around charged and neutral surface functional groups

Holomorphic matrix models

This is a study of holomorphic matrix models, the matrix models which underlie the conjecture of Dijkgraaf and Vafa. I first give a systematic description of the holomorphic one-matrix model. After discussing its convergence sectors, I show that certain puzzles related to its perturbative expansion admit a simple resolution in the holomorphic set-up. Constructing a `complex' microcanonical ensemble, I check that the basic requirements of the conjecture (in particular, the special geometry relations involving chemical potentials) hold in the absence of the hermicity constraint. I also show that planar solutions of the holomorphic model probe the entire moduli space of the associated algebraic curve. Finally, I give a brief discussion of holomorphic $ADE$ models, focusing on the example of the $A_2$ quiver, for which I extract explicitly the relevant Riemann surface. In this case, use of the holomorphic model is crucial, since the Hermitian approach and its attending regularization would lead to a singular algebraic curve, thus contradicting the requirements of the conjecture. In particular, I show how an appropriate regularization of the holomorphic $A_2$ model produces the desired smooth Riemann surface in the limit when the regulator is removed, and that this limit can be described as a statistical ensemble of `reduced' holomorphic models.Comment: 45 pages, reference adde

(Anti)symmetric matter and superpotentials from IIB orientifolds

We study the IIB engineering of N=1 gauge theories with unitary gauge group and matter in the adjoint and (anti)symmetric representations. We show that such theories can be obtained as Z2 orientifolds of Calabi-Yau A2 fibrations, and discuss the explicit T-duality transformation to an orientifolded Hanany-Witten construction. The low energy dynamics is described by a geometric transition of the orientifolded background. Unlike previously studied cases, we show that the orientifold 5-`plane' survives the transition, thus bringing a nontrivial contribution to the effective superpotential. We extract this contribution by using matrix model results and compare with geometric data. A Higgs branch of our models recovers the engineering of SO/Sp theories with adjoint matter through an O5-`plane' T-dual to an O6-plane. We show that the superpotential agrees with that produced by engineering through an O5-`plane' dual to an O4-plane, even though the orientifold of this second construction is replaced by fluxes after the transition.Comment: 40 page