3,175 research outputs found
Thermodynamic analysis of turbulent combustion in a spark ignition engine. Experimental evidence
A method independent of physical modeling assumptions is presented to analyze high speed flame photography and cylinder pressure measurements from a transparent piston spark ignition research engine. The method involves defining characteristic quantities of the phenomena of flame propagation and combustion, and estimating their values from the experimental information. Using only the pressure information, the mass fraction curves are examined. An empirical burning law is presented which simulates such curves. Statistical data for the characteristics delay and burning angles which show that cycle to cycle fractional variations are of the same order of magnitude for both angles are discussed. The enflamed and burnt mass fractions are compared as are the rates of entrainment and burning
Turbulent flame propagation and combustion in spark ignition engines
Pressure measurements synchronized with high-speed motion picture records of flame propagation have been made in a transparent piston engine. The data show that the initial expansion speed of the flame front is close to that of a laminar flame. As the flame expands, its speed rapidly accelerates to a quasi-steady value comparable with that of the turbulent velocity fluctuations in the unburned gas. During the quasi-steady propagation phase, a significant fraction of the gas behind the visible front is unburned. Final burnout of the charge may be approximated by an exponential decay in time. The data have been analyzed in a model independent way to obtain a set of empirical equations for calculating mass burning rates in spark ignition engines. The burning equations contain three parameters: the laminar burning speed s l, a characteristic speed u T, and a characteristic length l T. The laminar burning speed is known from laboratory measurements. Tentative correlations relating u T and l T to engine geometry and operating variables have been derived from the engine data. © 1983
Stochastic Transition States: Reaction Geometry amidst Noise
Classical transition state theory (TST) is the cornerstone of reaction rate
theory. It postulates a partition of phase space into reactant and product
regions, which are separated by a dividing surface that reactive trajectories
must cross. In order not to overestimate the reaction rate, the dynamics must
be free of recrossings of the dividing surface. This no-recrossing rule is
difficult (and sometimes impossible) to enforce, however, when a chemical
reaction takes place in a fluctuating environment such as a liquid.
High-accuracy approximations to the rate are well known when the solvent forces
are treated using stochastic representations, though again, exact no-recrossing
surfaces have not been available. To generalize the exact limit of TST to
reactive systems driven by noise, we introduce a time-dependent dividing
surface that is stochastically moving in phase space such that it is crossed
once and only once by each transition path
Biorthogonal quantum mechanics
The Hermiticity condition in quantum mechanics required for the characterization of (a) physical observables and (b) generators of unitary motions can be relaxed into a wider class of operators whose eigenvalues are real and whose eigenstates are complete. In this case, the orthogonality of eigenstates is replaced by the notion of biorthogonality that defines the relation between the Hilbert space of states and its dual space. The resulting quantum theory, which might appropriately be called 'biorthogonal quantum mechanics', is developed here in some detail in the case for which the Hilbert-space dimensionality is finite. Specifically, characterizations of probability assignment rules, observable properties, pure and mixed states, spin particles, measurements, combined systems and entanglements, perturbations, and dynamical aspects of the theory are developed. The paper concludes with a brief discussion on infinite-dimensional systems. © 2014 IOP Publishing Ltd
Accountability, Strategy, and International Non-Governmental Organizations
Increased prominence and greater influence expose international non-governmental development and environmental organizations (INGOs) to increased demands for accountability from a wide variety of stakeholdersdonors, beneficiaries, staffs, and partners among others. This paper focuses on developing the concept of INGO accountability, first as an abstract concept and then as a strategic idea with very different implications for different INGO strategies. We examine those implications for INGOs that emphasize service delivery, capacity-building, and policy influence. We propose that INGOs committed to service delivery may owe more accountability to donors and service regulators; capacity-building INGOs may be particularly obligated to clients whose capacities are being enhanced; and policy influence INGOs may be especially accountable to political constituencies and to influence targets. INGOs that are expanding their activities to include new initiatives may need to reorganize their accountability systems to implement their strategies effectively. This publication is Hauser Center Working Paper No. 7. The Hauser Center Working Paper Series was launched during the summer of 2000. The Series enables the Hauser Center to share with a broad audience important works-in-progress written by Hauser Center scholars and researchers
Brain connectivity analysis: a short survey
This short survey the reviews recent literature on brain connectivity studies. It encompasses all forms of static and dynamic
connectivity whether anatomical, functional, or effective. The last decade has seen an ever increasing number of studies devoted
to deduce functional or effective connectivity, mostly from functional neuroimaging experiments. Resting state conditions have
become a dominant experimental paradigm, and a number of resting state networks, among them the prominent default mode
network, have been identified. Graphical models represent a convenient vehicle to formalize experimental findings and to closely
and quantitatively characterize the various networks identified. Underlying these abstract concepts are anatomical networks, the
so-called connectome, which can be investigated by functional imaging techniques as well. Future studies have to bridge the gap between anatomical neuronal connections and related functional or effective connectivities
Stanniocalcin2, but Not Stanniocalcin1, Responds to Hypoxia in a HIF1-Dependent Manner in the Retina
The quest for neuroprotective factors that can prevent or slow down the progression of retinal degeneration is still ongoing. Acute hypoxic stress has been shown to provide transient protection against subsequent damage in the retina. Stanniocalcins – STC1 and STC2 – are secreted glycoproteins that are hypoxia-regulated and were shown to be cytoprotective in various in vitro studies. Hence, we investigated the expression of stanniocalcins in the normal, degenerating and hypoxic retina. We show that the expression of Stc1 and Stc2 in the retina was detectable as early as postnatal day 10 and persisted during aging. Retinal expression of Stc2, but not Stc1, was induced in mice in an in vivo model of acute hypoxia and a genetic model of chronic hypoxia. Furthermore, we show that HIF1, not HIF2, is responsible for regulating Stc2 in cells with the molecular response to hypoxia activated due to the absence of von Hippel Lindau protein. Surprisingly, Stc2 was not normally expressed in photoreceptors but in the inner retina, as shown by laser capture microdissection and immunofluorescence data. The expression of both Stc1 and Stc2 remained unchanged in the degenerative retina with an almost complete loss of photoreceptors, confirming their expression in the inner retina. However, the absence of either Stc1 or Stc2 had no effect on retinal architecture, as was evident from retinal morphology of the respective knockout mice. Taken together our data provides evidence for the differential regulation of STC1 and STC2 in the retina and the prospect of investigating STC2 as a retinal neuroprotective factor
A Design Kit for Mobile Device-Based Interaction Techniques
Beside designing the graphical interface of mobile applications, mobile phones and their built-in sensors enable various possibilities to engage with digital content in a physical, device-based manner that move beyond the screen content. So-called mobile device-based interactions are characterized by device movements and positions as well as user actions in real space. So far, there is only little guidance available for novice designers and developers to ideate and design new solutions for specic individual or collaborative use cases. Hence, the potential for designing mobile-based interactions is seldom fully exploited. To address this issue, we propose a design kit for mobile device-based interaction techniques following a morphological approach. Overall, the kit comprises seven dimensions with several elements that can be easily combined with each other to form an interaction technique by selecting at least one entry of each dimension. The design kit can be used to support designers in exploring novel mobile interaction techniques to specic interaction problems in the ideation phase of the design process but also in the analysis of existing device-based interaction solutions
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