66 research outputs found
Morphology of supported polymer electrolyte ultra-thin films: a numerical study
Morphology of polymer electrolytes membranes (PEM), e.g., Nafion, inside PEM
fuel cell catalyst layers has significant impact on the electrochemical
activity and transport phenomena that determine cell performance. In those
regions, Nafion can be found as an ultra-thin film, coating the catalyst and
the catalyst support surfaces. The impact of the hydrophilic/hydrophobic
character of these surfaces on the structural formation of the films has not
been sufficiently explored yet. Here, we report about Molecular Dynamics
simulation investigation of the substrate effects on the ionomer ultra-thin
film morphology at different hydration levels. We use a mean-field-like model
we introduced in previous publications for the interaction of the hydrated
Nafion ionomer with a substrate, characterized by a tunable degree of
hydrophilicity. We show that the affinity of the substrate with water plays a
crucial role in the molecular rearrangement of the ionomer film, resulting in
completely different morphologies. Detailed structural description in different
regions of the film shows evidences of strongly heterogeneous behavior. A
qualitative discussion of the implications of our observations on the PEMFC
catalyst layer performance is finally proposed
A polyaniline and Nafion® composite film as a rechargeable battery
10.1007/BF01024090Journal of Applied Electrochemistry226512-516JAEL
Equivalent electromechanical coefficient for IPMC actuator design based on equivalent bimorph beam theory
This paper addresses an “equivalent” electromechanical coupling coefficient that may be used in designing Ionic Polymer Metal Composite (IPMC) actuators. The coefficient is not a material constant and derived from equivalent bimorph beam model. The collective effect of the membrane thickness and operating voltage on the coefficient is demonstrated by using a design of experiment (DOE) of three and five levels of the two factors, respectively. Experiments and linear finite element analyses with MD.NASTRAN at DOE points are performed. The tip displacement and the coupling coefficient are reported and their response surface (RS) approximations as function of the thickness and voltage are constructed. Experiments and RS predictions indicate that actuator thickness and applied voltage are two interacting major factors for maximum tip displacement. The equivalent coupling coefficient is primarily driven by the thickness of actuator moreover voltage appears to contribute as the thickness increases. The initial curvature of the strips before electrical excitation is also shown to be a factor for “equivalent” coupling coefficient, it is not, however sufficient to explain the variation in the experimental data. A correction factor approach is proposed and applied to the straight beam tip displacement RS that filters out experimental variation. A corrected RS enables including the pre-imposed initial curvature as design parameter along with the actuator thickness and the operating peak voltage when predicting the tip displacement and the equivalent coupling coefficient
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