Electronic structure of C60 / graphite

We report temperature-dependent photoelectron spectra for a monolayer of C_60 adsorbed on HOPG, as well as C 1s x-ray absorption. This extends a previous report which showed the close similarity between the spectrum of the HOMO for the two-dimensional overlayer and that of C_60 in the gas phase. The present work shows that intermolecular and molecule-substrate vibrations contribute strongly to the spectral lineshape at room temperature. Thus, vibrational effects are shown to be crucial for the proper understanding of photoelectron spectra, and thus the charge transport properties, for C_60 in contact with graphite and graphite-like materials.Comment: Proc. of the XV. Int. Winterschool on Electronic Properties of Novel Materials, Kirchberg/Tirol, Austria, 200

Spatial and temporal resolution of carbon flux estimates for 1983?2002

International audienceWe discuss the spatial and temporal resolution of monthly carbon flux estimates for the period 1983?2002 using a fixed-lag Kalman Smoother technique with a global chemical transport model, and the GLOBALVIEW data product. The observational network has expanded substantially over this period, and we the improvement in the constraints provided flux estimates by observations for the 1990's in comparison to the 1980's. The estimated uncertainties also decrease as observational coverage expands. In this study, we use the Globalview data product for a network that changes every 5 y, rather than using a small number of continually-operating sites (fewer observational constraints) or a large number of sites, some of which may consist almost entirely of extrapolated data. We show that the discontinuities resulting from network changes reflect uncertainty due to a sparse and variable network. This uncertainty effectively limits the resolution of trends in carbon fluxes. The ability of the inversion to distinguish, or resolve, carbon fluxes at various spatial scales is examined using a diagnostic known as the resolution kernel. We find that the global partition between land and ocean fluxes is well-resolved even for the very sparse network of the 1980's, although prior information makes a significant contribution to the resolution. The ability to distinguish zonal average fluxes has improved significantly since the 1980's, especially for the tropics, where the zonal ocean and land biosphere fluxes can be distinguished. Care must be taken when interpreting zonal average fluxes, however, since the lack of air samples for some regions in a zone may result in a large influence from prior flux estimates for these regions. We show that many of the TransCom 3 source regions are distinguishable throughout the period over which estimates are produced. Examples are Boreal and Temperate North America. The resolution of fluxes from Europe and Australia has greatly improved since the 1990's. Other regions, notably Tropical South America and the Equatorial Atlantic remain practically unresolved. Comparisons of the average seasonal cycle of the estimated carbon fluxes with the seasonal cycle of the prior flux estimates reveals a large adjustment of the summertime uptake of carbon for Boreal Eurasia, and an earlier onset of springtime uptake for Temperate North America. In addition, significantly larger seasonal cycles are obtained for some ocean regions, such as the Northern Ocean, North Pacific, North Atlantic and Western Equatorial Pacific, regions that appear to be well-resolved by the inversion

Computationally efficient methods for modelling laser wakefield acceleration in the blowout regime

Electron self-injection and acceleration until dephasing in the blowout regime is studied for a set of initial conditions typical of recent experiments with 100 terawatt-class lasers. Two different approaches to computationally efficient, fully explicit, three-dimensional particle-in-cell modelling are examined. First, the Cartesian code VORPAL using a perfect-dispersion electromagnetic solver precisely describes the laser pulse and bubble dynamics, taking advantage of coarser resolution in the propagation direction, with a proportionally larger time step. Using third-order splines for macroparticles helps suppress the sampling noise while keeping the usage of computational resources modest. The second way to reduce the simulation load is using reduced-geometry codes. In our case, the quasi-cylindrical code CALDER-CIRC uses decomposition of fields and currents into a set of poloidal modes, while the macroparticles move in the Cartesian 3D space. Cylindrical symmetry of the interaction allows using just two modes, reducing the computational load to roughly that of a planar Cartesian simulation while preserving the 3D nature of the interaction. This significant economy of resources allows using fine resolution in the direction of propagation and a small time step, making numerical dispersion vanishingly small, together with a large number of particles per cell, enabling good particle statistics. Quantitative agreement of the two simulations indicates that they are free of numerical artefacts. Both approaches thus retrieve physically correct evolution of the plasma bubble, recovering the intrinsic connection of electron self-injection to the nonlinear optical evolution of the driver

An atmospheric perspective on North American carbon dioxide exchange: CarbonTracker

We present an estimate of net CO2 exchange between the terrestrial biosphere and the atmosphere across North America for every week in the period 2000 through 2005. This estimate is derived from a set of 28,000 CO2 mole fraction observations in the global atmosphere that are fed into a state-of-the-art data assimilation system for CO2 called CarbonTracker. By design, the surface fluxes produced in CarbonTracker are consistent with the recent history of CO2 in the atmosphere and provide constraints on the net carbon flux independent from national inventories derived from accounting efforts. We find the North American terrestrial biosphere to have absorbed –0.65 PgC/yr (1 petagram = 10^15 g; negative signs are used for carbon sinks) averaged over the period studied, partly offsetting the estimated 1.85 PgC/yr release by fossil fuel burning and cement manufacturing. Uncertainty on this estimate is derived from a set of sensitivity experiments and places the sink within a range of –0.4 to –1.0 PgC/yr. The estimated sink is located mainly in the deciduous forests along the East Coast (32%) and the boreal coniferous forests (22%). Terrestrial uptake fell to –0.32 PgC/yr during the large-scale drought of 2002, suggesting sensitivity of the contemporary carbon sinks to climate extremes. CarbonTracker results are in excellent agreement with a wide collection of carbon inventories that form the basis of the first North American State of the Carbon Cycle Report (SOCCR), to be released in 2007. All CarbonTracker results are freely available at http://carbontracker.noaa.gov

Single-stage plasma-based correlated energy spread compensation for ultrahigh 6D brightness electron beams

Plasma photocathode wakefield acceleration combines energy gains of tens of GeV m−1 with generation of ultralow emittance electron bunches, and opens a path towards 5D-brightness orders of magnitude larger than state-of-the-art. This holds great promise for compact accelerator building blocks and advanced light sources. However, an intrinsic by-product of the enormous electric field gradients inherent to plasma accelerators is substantial correlated energy spread—an obstacle for key applications such as free-electron-lasers. Here we show that by releasing an additional tailored escort electron beam at a later phase of the acceleration, when the witness bunch is relativistically stable, the plasma wave can be locally overloaded without compromising the witness bunch normalized emittance. This reverses the effective accelerating gradient, and counter-rotates the accumulated negative longitudinal phase space chirp of the witness bunch. Thereby, the energy spread is reduced by an order of magnitude, thus enabling the production of ultrahigh 6D-brightness beams

Upper critical field and de Haas-van Alphen oscillations in KOs2_2O6_6 measured in a hybrid magnet

Magnetic torque measurements have been performed on a KOs$_2$O$_6$ single crystal in magnetic fields up to 35.3 T and at temperatures down to 0.6 K. The upper critical field is determined to be $\sim$30 T. De Haas-van Alphen oscillations are observed. A large mass enhancement of (1+$\lambda$) = $m^* / m_{band}$ = 7.6 is found. It is suggested that, for the large upper critical field to be reconciled with Pauli paramagnetic limiting, the observed mass enhancement must be of electron-phonon origin for the most part.Comment: 4 pages, 4 figures, published versio

Particle interactions with single or multiple 3D solar reconnecting current sheets

The acceleration of charged particles (electrons and protons) in flaring solar active regions is analyzed by numerical experiments. The acceleration is modelled as a stochastic process taking place by the interaction of the particles with local magnetic reconnection sites via multiple steps. Two types of local reconnecting topologies are studied: the Harris-type and the X-point. A formula for the maximum kinetic energy gain in a Harris-type current sheet, found in a previous work of ours, fits well the numerical data for a single step of the process. A generalization is then given approximating the kinetic energy gain through an X-point. In the case of the multiple step process, in both topologies the particles' kinetic energy distribution is found to acquire a practically invariant form after a small number of steps. This tendency is interpreted theoretically. Other characteristics of the acceleration process are given, such as the mean acceleration time and the pitch angle distributions of the particles.Comment: 18 pages, 9 figures, Solar Physics, in pres

Upward revision of global fossil fuel methane emissions based on isotope database

Methane has the second-largest global radiative forcing impact of anthropogenic greenhouse gases after carbon dioxide, but our understanding of the global atmospheric methane budget is incomplete. The global fossil fuel industry (production and usage of natural gas, oil and coal) is thought to contribute 15 to 22 per cent of methane emissions to the total atmospheric methane budget. However, questions remain regarding methane emission trends as a result of fossil fuel industrial activity and the contribution to total methane emissions of sources from the fossil fuel industry and from natural geological seepage, which are often co-located. Here we re-evaluate the global methane budget and the contribution of the fossil fuel industry to methane emissions based on long-term global methane and methane carbon isotope records. We compile the largest isotopic methane source signature database so far, including fossil fuel, microbial and biomass-burning methane emission sources. We find that total fossil fuel methane emissions (fossil fuel industry plus natural geological seepage) are not increasing over time, but are 60 to 110 per cent greater than current estimates owing to large revisions in isotope source signatures. We show that this is consistent with the observed global latitudinal methane gradient. After accounting for natural geological methane seepage, we find that methane emissions from natural gas, oil and coal production and their usage are 20 to 60 per cent greater than inventories. Our findings imply a greater potential for the fossil fuel industry to mitigate anthropogenic climate forcing, but we also find that methane emissions from natural gas as a fraction of production have declined from approximately 8 per cent to approximately 2 per cent over the past three decades.Published88-916A. Geochimica per l'ambienteJCR Journa

Impact of CO2 measurement bias on CarbonTracker surface flux estimates

For over 20 years, atmospheric measurements of CO2 dry air mole fractions have been used to derive estimates of CO2 surface fluxes. Historically, only a few research laboratories made these measurements. Today, many laboratories are making CO2 observations using a variety of analysis techniques and, in some instances, using different calibration scales. As a result, the risk of biases in individual CO2 mole fraction records, or even in complete monitoring networks, has increased over the last decades. Ongoing experiments comparing independent, well-calibrated measurements of atmospheric CO2 show that biases can and do exist between measurement records. Biases in measurements create artificial spatial and temporal CO2 gradients, which are then interpreted by an inversion system, leading to erroneous flux estimates. Here we evaluate the impact of a constant bias introduced into the National Oceanic and Atmospheric Administration (NOAA) quasi-continuous measurement record at the Park Falls, Wisconsin (LEF), tall tower site on CarbonTracker flux estimates. We derive a linear relationship between the magnitude of the introduced bias at LEF and the CarbonTracker surface flux responses. Temperate North American net flux estimates are most sensitive to a bias at LEF in our CarbonTracker inversion, and its linear response rate is 68 Tg C yr-1 (~10% of the estimated North American annual terrestrial uptake) for every 1 ppm of bias in the LEF record. This sensitivity increases when (1) measurement biases approached assumed model errors and (2) fewer other measurement records are available to anchor the flux estimates despite the presence of bias in one record. Flux estimate errors are also calculated beyond North America. For example, biospheric uptake in Europe and boreal Eurasia combined increases by 25 Tg C yr-1 per ppm CO2 to partially compensate for changes in the North American flux totals. These results illustrate the importance of well-calibrated, high-precision CO2 dry air mole fraction measurements, as well as the value of an effective strategy for detecting bias in measurements. This study stresses the need for a monitoring network with the necessary density to anchor regional, continental, and hemispheric fluxes more tightly and to lessen the impact of potentially undetected biases in observational networks operated by different national and international research programs

All-optical density downramp injection in electron-driven plasma wakefield accelerators

Injection of well-defined, high-quality electron populations into plasma waves is a key challenge of plasma wakefield accelerators. Here, we report on the first experimental demonstration of plasma density downramp injection in an electron-driven plasma wakefield accelerator, which can be controlled and tuned in all-optical fashion by mJ-level laser pulses. The laser pulse is directed across the path of the plasma wave before its arrival, where it generates a local plasma density spike in addition to the background plasma by tunnelling ionization of a high ionization threshold gas component. This density spike distorts the plasma wave during the density downramp, causing plasma electrons to be injected into the plasma wave. By tuning the laser pulse energy and shape, highly flexible plasma density spike profiles can be designed, enabling dark current free, versatile production of high-quality electron beams. This in turn permits creation of unique injected beam configurations such as counter-oscillating twin beamlets