66 research outputs found
Mesoscopic non-equilibrium thermodynamics approach to the dynamics of polymers
We present a general formalism able to derive the kinetic equations of
polymer dynamics. It is based on the application of nonequilibrium
thermodynamics to analyze the irreversible processes taking place in the
conformational space of the macromolecules. The Smoluchowski equation results
from the analysis of the underlying diffusion process in that space within the
scheme of nonequilibrium thermodynamics. We apply the method to different
situations, concerning flexible, semiflexible and rod-like polymers and to the
case of more concentrated solutions in which interactions become important.Comment: 13 pages (RevTex). To be published in Physica
ItÀ-Suomen ammattikorkeakoulut : YhteistyössÀ hyvinvoinnin osaamista edistÀmÀssÀ
Pohjois-Karjalan ammattikorkeakoulu ja Savonia-ammattikorkeakoulu ovat osana ISAT-toimintaa tehneet yhteistyötÀ vÀljÀsti asutun alueen hyvinvointipalvelujen kehittÀmiseksi. Yhteistyö on toteutunut kaikilla korkeakoulujen tehtÀvÀalueilla: koulutus, tutkimus-, kehittÀmis- ja innovaatiotoiminta sekÀ aluekehittÀminen ja kansainvÀlinen yhteistyö.
TÀssÀ julkaisussa kuvataan edellÀ mainittua ISAT-yhteistyötÀ useista eri nÀkökulmista, useiden eri asiantuntijoiden kertomana. Tavoitteena on, ettÀ lukijalle syntyy mielikuva ISAT-yhteistyön monipuolisuudesta, koskien vÀljÀsti asutun alueen hyvinvointipalveluita
Evaluation of social competencies in chemical engineering: application and results of the pilot test (academic year 2012-2013)
The Escola TĂšcnica Superior dâEnginyeria QuĂmica has a long tradition in the deployment of social competencies in engineering curricula through Integrated Projects (IP) carried out in structured teams. Social competencies are taught and practiced during the development of the IPs. We conceptually introduce a methodology for a 360o assessment of the studentsâ social competencies, as a tool to foster the improvement of their competency levels. In this article we analyze the results of the pilot test where the aforementioned methodology has been implemented in the Bachelor studies of Chemical Engineering. The results indicate that it is possible to objectively obtain the studentâs competency level discriminating among different social competencies, as well as among different students in the same team. The application of this tool fosters the development of specific educative actions to help the students with low competency profile, to reach acceptable levels for a successful insertion in the labor marketPeer Reviewe
Kinetics of Particles Adsorption Processes Driven by Diffusion
The kinetics of the deposition of colloidal particles onto a solid surface is
analytically studied. We take into account both the diffusion of particles from
the bulk as well as the geometrical aspects of the layer of adsorbed particles.
We derive the first kinetic equation for the coverage of the surface (a
generalized Langmuir equation) whose predictions are in agreement with recent
simulation results where diffusion of particles from the bulk is explicitly
considered.Comment: 4 page
Histogram Reweighting Method for Dynamic Properties
The histogram reweighting technique, widely used to analyze Monte Carlo data,
is shown to be applicable to dynamic properties obtained from Molecular
Dynamics simulations. The theory presented here is based on the fact that the
correlation functions in systems in thermodynamic equilibrium are averages over
initial conditions of functions of the trajectory of the system in phase-space,
the latter depending on the volume, the total number of particles and the
classical Hamiltonian. Thus, the well-known histogram reweighting method can
almost straightforwardly be applied to reconstruct the probability distribution
of initial states at different thermodynamic conditions, without extra
computational effort. Correlation functions and transport coefficients are
obtained with this method from few simulation data sets.Comment: 4 pages, 3 figure
Phenomenological approach to non-linear Langevin equations
In this paper we address the problem of consistently construct Langevin
equations to describe fluctuations in non-linear systems. Detailed balance
severely restricts the choice of the random force, but we prove that this
property together with the macroscopic knowledge of the system is not enough to
determine all the properties of the random force. If the cause of the
fluctuations is weakly coupled to the fluctuating variable, then the
statistical properties of the random force can be completely specified. For
variables odd under time-reversal, microscopic reversibility and weak coupling
impose symmetry relations on the variable-dependent Onsager coefficients. We
then analyze the fluctuations in two cases: Brownian motion in position space
and an asymmetric diode, for which the analysis based in the master equation
approach is known. We find that, to the order of validity of the Langevin
equation proposed here, the phenomenological theory is in agreement with the
results predicted by more microscopic models.Comment: LaTex file, 2 figures available upon request, to appear in Phys.Rev.
Dissipative Particle Dynamics with Energy Conservation
The stochastic differential equations for a model of dissipative particle
dynamics with both total energy and total momentum conservation in the
particle-particle interactions are presented. The corresponding Fokker-Planck
equation for the evolution of the probability distribution for the system is
deduced together with the corresponding fluctuation-dissipation theorems
ensuring that the ab initio chosen equilibrium probability distribution for the
relevant variables is a stationary solution. When energy conservation is
included, the system can sustain temperature gradients and heat flow can be
modeled.Comment: 7 pages, submitted to Europhys. Let
Particle-Based Mesoscale Hydrodynamic Techniques
Dissipative particle dynamics (DPD) and multi-particle collision (MPC)
dynamics are powerful tools to study mesoscale hydrodynamic phenomena
accompanied by thermal fluctuations. To understand the advantages of these
types of mesoscale simulation techniques in more detail, we propose new two
methods, which are intermediate between DPD and MPC -- DPD with a multibody
thermostat (DPD-MT), and MPC-Langevin dynamics (MPC-LD). The key features are
applying a Langevin thermostat to the relative velocities of pairs of particles
or multi-particle collisions, and whether or not to employ collision cells. The
viscosity of MPC-LD is derived analytically, in very good agreement with the
results of numerical simulations.Comment: 7 pages, 2 figures, 1 tabl
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