Self-synchronized duty-cycling for sensor networks with energy harvesting capabilities: Implementation in Wiselib

In this work we present a protocol for a self- synchronized duty-cycling mechanism in wireless sensor net- works with energy harvesting capabilities. The protocol is im- plemented in Wiselib, a library of generic algorithms for sensor networks. Simulations are conducted with the sensor network simulator Shawn. They are based on the specifications of real hardware known as iSense sensor nodes. The experimental results show that the proposed mechanism is able to adapt to changing energy availabilities. Moreover, it is shown that the system is very robust against packet loss.Postprint (published version

Synthesis of N-Heterocylic Carbene-Containing Metal Complexes from 2-(Pentafluorophenyl)imidazolidines

N-Heterocyclic carbene (NHC)-containing metal complexes are prepared through a simple, base-free method involving the decomposition of 2-(pentafluorophenyl)imidazolidines under mild thermolytic conditions. Ruthenium, iridium, and rhodium complexes containing NHC ligands with different electronic and steric parameters are reported

Reducing the manual length setting error of a passive Gough-Stewart platform for surgical template fabrication using a digital measurement system

As recently demonstrated, a passive Gough-Stewart platform (a.k.a. hexapod) can be used to create a personalized surgical template to achieve minimally invasive access to the cochlea. The legs of the hexapod are manually adjusted to the desired length, which must be read off an analog scale. Previous experiments have shown that manual length setting of the hexapod's legs is error-prone because of the imprecise readability of the analog scale. The objective of this study is to determine if integration of a linear encoder and digitally displaying the measured length help reduce the length setting error. Two experiments were conducted where users set the leg length manually. In both experiments, the users were asked to set the leg length to 20 nominal values using the whole setting range from 0 mm to 10 mm. In the first experiment, users had to rely only on the analog scale; in the second experiment, the electronic display additionally showed the user the actual leg length. Results show that the mean length setting error without using the digital display and only relying on the analog scale was (0.036 ± 0.020) mm (max: 0.107 mm) in contrast to (0.001 ± 0.000) mm (max: 0.002 mm) for the experiment with the integrated digital measurement system. The results support integration of digital length measurement systems as a promising tool to increase the accuracy of surgical template fabrication and thereby patients' safety. Future studies must be conducted to evaluate if integration of a linear encoder in each of the six legs is feasible

Self-assembly of gold nanoparticles at the oil-vapor interface: from mono- to multilayers

Alkylthiol-coated gold nanoparticles spontaneously segregate from dispersion in toluene to the toluene-vapor interface. We show that surface tension drops during segregation with a rate that depends on particle concentration. Mono- and multilayers of particles form depending on particle concentration, time, and temperature. X-ray reflectometry indicates fast monolayer formation and slow multilayer formation. A model that combines diffusion-limited segregation driven by surface energy and heterogeneous agglomeration driven by dispersive van der Waals particle interactions is proposed to describe film formation

ORD-Xplore: Bridging Open Research Data Collections through Modality Abstractions

We present ORD-Xplore, an approach to bridge gaps between digital editions, which represent valuable collections of multiple digitized research artifacts. However, digital editions often co-exist isolated, making it difficult for researchers to access, find, and re-use open research data from multiple digital editions. An ultimate goal is to unify library services across editions, even for editions with heterogeneity. In ORD-Xplore, we utilize abstraction methods from visualization research to help digital librarians identify unifying data modalities, as one important step towards standardization of heterogeneous digital editions

Isolable Diaminophosphide Boranes

Metalation of secondary diaminophosphine boranes by alkali metal amides provides a robust and selective access route to a range of metal diaminophosphide boranes M[(R2N)(2)P(BH3)] (M=Li, Na, K; R=alkyl, aryl) with acyclic or heterocyclic molecular backbones, whereas reduction of a chlorodiaminophosphine borane gave less satisfactory results. The metalated species were characterized in situ by NMR spectroscopy and in two cases isolated as crystalline solids. Single-crystal XRD studies revealed the presence of salt-like structures with strongly interacting ions. Synthetic applications of K[(R2N)(2)P(BH3)] were studied in reactions with a 1,2-dichlorodisilane and CS2, which afforded either mono- or difunctional phosphine boranes with a rare combination of electronegative amino and electropositive functional disilanyl groups on phosphorus, or a phosphinodithioformate. Spectroscopic studies gave a first hint that removal of the borane fragment may be feasible.Peer reviewe

Deletion of the Ca2+ Channel Subunit α2δ3 Differentially Affects Cav2.1 and Cav2.2 Currents in Cultured Spiral Ganglion Neurons Before and After the Onset of Hearing

Voltage-gated Ca2+ channels are composed of a pore-forming α1 subunit and auxiliary β and α2δ subunits, which modulate Ca2+ current properties and channel trafficking. So far, the partial redundancy and specificity of α1 for α2δ subunits in the CNS have remained largely elusive. Mature spiral ganglion (SG) neurons express α2δ subunit isoforms 1, 2, and 3 and multiple Ca2+ channel subtypes. Differentiation and in vivo functions of their endbulb of Held synapses, which rely on presynaptic P/Q channels (Lin et al., 2011), require the α2δ3 subunit (Pirone et al., 2014). This led us to hypothesize that P/Q channels may preferentially co-assemble with α2δ3. Using a dissociated primary culture, we analyzed the effects of α2δ3 deletion on somatic Ca2+ currents (ICa) of SG neurons isolated at postnatal day 20 (P20), when the cochlea is regarded to be mature. P/Q currents were the dominating steady-state Ca2+ currents (54% of total) followed by T-type, L-type, N-type, and R-type currents. Deletion of α2δ3 reduced P/Qand R-type currents by 60 and 38%, respectively, whereas L-type, N-type, and T-type currents were not altered. A subset of ICa types was also analyzed in SG neurons isolated at P5, i.e., before the onset of hearing (P12). Both L-type and N-type current amplitudes of wildtype SG neurons were larger at P5 compared with P20. Deletion of α2δ3 reduced L-type and N-type currents by 23 and 44%, respectively. In contrast, small P/Q currents, which were just being up-regulated at P5, were unaffected by the lack of α2δ3. In summary, α2δ3 regulates amplitudes of L- and N-type currents of immature cultured SG neurons, whereas it regulates P/Q- and R-type currents at P20. Our data indicate a developmental switch from dominating somatic N- to P/Q-type currents in cultured SG neurons. A switch from N- to P/Q-type channels, which has been observed at several central synapses, may also occur at developing endbulbs of Held. In this case, reduction of both neonatal N- (P5) and more mature P/Q-type currents (around/after hearing onset) may contribute to the impaired morphology and function of endbulb synapses in α2δ3-deficient mice

Simulating stress-dependent fluid flow in a fractured core sample using real-time X-ray CT data

Various geoscientific applications require a fast prediction of fracture permeability for an optimal workflow. Hence, the objective of the current study is to introduce and validate a practical method to characterize and approximate single flow in fractures under different stress conditions by using a core-flooding apparatus, in situ X-ray computed tomography (CT) scans and a finite-volume method solving the Navier–Stokes–Brinkman equations. The permeability of the fractured sandstone sample was measured stepwise during a loading–unloading cycle (0.7 to 22.1 MPa and back) to validate the numerical results. Simultaneously, the pressurized core sample was imaged with a medical X-ray CT scanner with a voxel dimension of 0.5  ×  0.5  ×  1.0 mm3. Fracture geometries were obtained by CT images based on a modification of the simplified missing attenuation (MSMA) approach. Simulation results revealed both qualitative plausibility and a quantitative approximation of the experimentally derived permeabilities. The qualitative results indicate flow channeling along several preferential flow paths with less pronounced tortuosity. Significant changes in permeability can be assigned to temporal and permanent changes within the fracture due to applied stresses. The deviations of the quantitative results appear to be mainly caused by both local underestimation of hydraulic properties due to compositional matrix heterogeneities and the low CT resolution affecting the accurate capturing of sub-grid-scale features. Both affect the proper reproduction of the actual connectivity and therefore also the depiction of the expected permeability hysteresis. Furthermore, the threshold value CTmat (1862.6 HU) depicting the matrix material represents the most sensitive input parameter of the simulations. Small variations of CTmat can cause enormous changes in simulated permeability by up to a factor of 2.6 ± 0.1 and, thus, have to be defined with caution. Nevertheless, comparison with further CT-based flow simulations indicates that the proposed method represents a valuable method to approximate actual permeabilities, particularly for smooth fractures (< 35 µm). However, further systematic investigations concerning the applicability of the method are essential for future studies. Thus, some recommendations are compiled by also including suggestions of comparable studies