Combined^147,146Sm-^143,142Nd constraints on the longevity and residence time of early terrestrial crust

Primordial silicate differentiation controlled the composition of Earth's oldest crust. Inherited 142Nd anomalies in Archean rocks are vestiges of the mantle-crust differentiation before ca. 4300 Ma. Here we report new whole-rock 147,146Sm-143,142Nd data for the Acasta Gneiss Complex (AGC; Northwest Territories, Canada). Our 147Sm-143Nd data combined with literature data define an age of 3371 ± 141 Ma (2 SD) and yield an initial ε143Nd of −5.6 ± 2.1. These results are at odds with the Acasta zircon U-Pb record, which comprises emplacement ages of 3920–3960 Ma. Ten of our thirteen samples show 142Nd deficits of −9.6 ± 4.8 ppm (2 SD) relative to the modern Earth. The discrepancy between 142Nd anomalies and a mid-Archean 147Sm-143Nd age can be reconciled with Nd isotope reequilibration of the AGC during metamorphic perturbations at ca. 3400 Ma. A model age of ca. 4310 Ma is derived for the early enrichment of the Acasta source. Two compositional end-members can be identified: a felsic component with 142Nd/144Nd identical to the modern Earth and a mafic component with 142Nd/144Nd as low as −14.1 ppm. The ca. 4310 Ma AGC source is ∼200 Myr younger than those estimated for Nuvvuagittuq (northern Québec) and Isua (Itsaq Gneiss Complex, West Greenland). The AGC does not have the same decoupled Nd-Hf isotope systematics as these other two terranes, which have been attributed to the crystallization of an early magma ocean. The Acasta signature rather is ascribed to the formation of Hadean crust that was preserved for several hundred Myr. Its longevity can be linked to 142Nd evolution in the mantle and does not require slow mantle stirring times nor modification of its convective mode.This project was funded by an ETH internal grant to BB. We thank Colin Maden for maintenance of the mass spectrometer. SJM acknowledges support from the NASA Exobiology and Evolutionary Biology Program (Investigating the Hadean Earth) and the NASA Lunar Science Institute (Center for Lunar Origin and Evolution, CLOE). Additional support to SJM came from the Laboratoire de Géologie de Lyon, Université Claude Bernard Lyon 1, and a Distinguished Professorship awarded by the Hungarian Academy of Sciences. JBT received support from the French Agence Nationale de la Recherche (Grant ANR-10-BLAN-0603 M&Ms — Mantle Melting — Measurements, Models, Mechanisms).This is the version of record, which can also be found on the publisher's website at: http://onlinelibrary.wiley.com/doi/10.1002/2014GC005313/abstract © 2014. American Geophysical Union. All Rights Reserved

Melt generation beneath Arctic Ridges: Implications from Ule

We present new 238U-230Th-226Ra-210Pb, 235U-231Pa, and Nd, Sr, Hf, and Pb isotope data for the slow- to ultraslow-spreading Mohns, Knipovich, and Gakkel Ridges. Combined with previous work, our data from the Arctic Ridges cover the full range of axial depths from the deep northernmost Gakkel Ridge shallowing upwards to the Knipovich, Mohns, and Kolbeinsey Ridges north of Iceland. Age-constrained samples from the Mohns and Knipovich Ridges have (230Th/238U) activity ratios ranging from 1.165 to 1.30 and 1.101 to 1.225, respectively. The high 230Th excesses of Kolbeinsey, Mohns, and Knipovich mid-ocean ridge basalts (MORB) are erupted from ridges producing relatively thin (Mohns, Knipovich) to thick (Kolbeinsey) oceanic crust with evidence for sources ranging from mostly peridotite (Kolbeinsey) to eclogite-rich mantle (Mohns, Knipovich). Age-constrained lavas from 85ºE on the Gakkel Ridge, on the other hand, overlie little to no crust and range from small (~5%) 230Th excesses to small 238U excesses (~5%). The strong negative correlation between (230Th/238U) values vs. axial ridge depth among Arctic ridge basalts is controlled not only by solidus depth influence on 238U-230Th disequilibria, but also by variations in mantle source lithology and depth to the base of the lithosphere, which is expected to vary at ultra-slow spreading ridges. Small 231Pa excesses (65% excess) in age constrained basalts support the presence of eclogite in the mantle source for this region. Conversely, the ultraslow-spreading Gakkel Ridge basalts are homogeneous, with Sr, Nd, and Hf radiogenic isotopic signatures indicative of a long time-averaged depleted mantle source. The Gakkel samples have minimum (226 Ra/230Th) ratios ranging from 3.07 to 3.65 ± 3%, which lie along and extend the global negative correlation between 226Ra and 230Th excesses observed in MORB. The new 230Th-226Ra data support a model for global MORB production in which deep melts record interaction with shallower materials. This scenario requires either mixing with shallow-derived melts, or melt-rock reaction with shallower rocks in the lithosphere or crust

Isotopic evolution of prehistoric magma sources of Mt. Etna, Sicily: Insights from the Valle Del Bove

Mount Etna in NE Sicily occupies an unusual tectonic position in the convergence zone between the African and Eurasian plates, near the Quaternary subduction-related Aeolian arc and above the down-going Ionian oceanic slab. Magmatic evolution broadly involves a transition from an early tholeiitic phase (~ 500 ka) to the current alkaline phase. Most geochemical investigations have focussed on either historic (> 130-years old) or recent (< 130-years old) eruptions of Mt. Etna or on the ancient basal lavas (ca. 500 ka). In this study, we have analysed and modelled the petrogenesis of alkalic lavas from the southern wall of the Valle del Bove, which represent a time span of Mt. Etna’s prehistoric magmatic activity from ~ 85 to ~ 4 ka. They exhibit geochemical variations that distinguish them as six separate lithostratigraphic and volcanic units. Isotopic data (143Nd/144Nd = 0.51283–0.51291; 87Sr/86Sr = 0.70332–0.70363; 176Hf/177Hf = 0.28288–0.28298; 206Pb/204Pb = 19.76–20.03) indicate changes in the magma source during the ~ 80 kyr of activity that do not follow the previously observed temporal trend. The oldest analysed Valle del Bove unit (Salifizio-1) erupted basaltic trachyandesites with variations in 143Nd/144Nd and 87Sr/86Sr ratios indicating a magma source remarkably similar to that of recent Etna eruptions, while four of the five subsequent units have isotopic compositions resembling those of historic Etna magmas. All five magma batches are considered to be derived from melting of a mixture of spinel lherzolite and pyroxenite (± garnet). In contrast, the sixth unit, the main Piano Provenzana formation (~ 42–30 ka), includes the most evolved trachyandesitic lavas (58–62 wt% SiO2) and exhibits notably lower 176Hf/177Hf, 143Nd/144Nd, and 206Pb/204Pb ratios than the other prehistoric Valle del Bove units. This isotopic signature has not yet been observed in any other samples from Mt. Etna and we suggest that the parental melts of the trachyandesites were derived predominantly from ancient pyroxenite in the mantle source of Etna

Hafnium isotopic variations in volcanic rocks from the Caribbean Large Igneous Province and Galápagos hotspot tracks

[1] We report Hf isotope compositions of 79 lavas that record the early (∼5–95 Ma) history of the Galápagos plume volcanism. These include lavas from the Caribbean Large Igneous Province (CLIP; ∼95–70 Ma), the accreted Galápagos paleo-hot spot track terranes (54–65 Ma) of Costa Rica (Quepos, Osa and Burica igneous complexes), and the Galápagos hot spot tracks (<20 Ma) located on the Pacific seafloor (Cocos, Carnegie, Malpelo, and Coiba Ridges and associated seamounts). These samples have previously been well characterized in terms of major and trace elements, Sr-Nd-Pb isotopes and Ar/Ar ages. As a result of the relative immobility of the high field strength and rare earth elements during syn- and post-emplacement hydrothermal activity and low-temperature alteration, combined Lu-Hf and Sm-Nd isotope systematics, when used in conjunction with Pb isotopes, provide a particular powerful tool, for evaluating the source compositions of ancient and submarine lavas. The combined Nd-Hf isotope data suggest that three of the isotopically distinct source components found today in the Galápagos Islands (the Floreana-like southern component, the Fernandina-like central component, and the depleted Genovesa-like eastern component) were present in the CLIP already by 95–70 Ma. The fourth Pinta-like northern component is first recorded at about 83–85 Ma by volcanism taking place during the transition from the plume head/CLIP to plume tail stage and has then been present in the hot spot track continuously thereafter. The identification of the unique northern and southern Galápagos Plume Hf-Nd-Pb isotope source signatures within the CLIP and the oldest hot spot track lavas provides direct evidence that the CLIP represents the plume head stage of the Galápagos hot spot. Hafnium isotopes are consistent with the possibility that two types of sediment components may have contributed to the Hf, Nd and Pb isotope compositions of the Galápagos plume lavas. One component, characterized by Δ207Pb/204Pb ≈ 0 and high positive ΔεHf has an isotope signature indicative of relatively recently recycled pelagic sediment, a signature typical of the southern Galápagos island Floreana. The other component has an EM like isotopic composition resembling modern seafloor sediments with positive Δ207Pb/204Pb and lower ΔεHf, a signature typical of the northern Galápagos island Pinta

North Atlantic hotspot-ridge interaction near Jan Mayen Island

At slow to ultraslow spreading rates along mid-ocean ridges, thicker lithosphere typically impedes magma generation and tectonic extension can play a more significant role in crustal production (Dick et al., 2003). The source of anomalously high magma supply thus remains unclear along ridges with ultraslow-spreading rates adjacent to Jan Mayen Island in the North Atlantic (Neumann and Schilling, 1984; Mertz et al., 1991; Haase et al., 1996; Schilling et al., 1999; Trønnes et al., 1999; Haase et al., 2003; Mertz et al., 2004; Blichert-Toft et al., 2005; Debaille et al., 2009). Here we show that Jan Mayen volcanism is likely the surface expression of a small mantle plume, which exerts significant influence on nearby mid-ocean ridge tectonics and volcanism. Progressive dilution of Jan Mayen geochemical signatures with distance from the hotspot is observed in lava samples from the immediately adjacent Mohns Ridge, and morphological indicators of enhanced magma supply are observed on both the Mohns Ridge and the nearby Kolbeinsey Ridge, which additionally locally overlies a highly heterogeneous, eclogite-bearing mantle source. These morphological and geochemical influences underscore the importance of heterogeneous mantle sources in modifying melt supply and thus the local expression of tectonic boundaries

Sub-arc xenolith Fe-Li-Pb isotopes and textures tell tales of their journey through the mantle wedge and crust

Island arcs provide insights into the origin and recycling of continental crust, but questions remain concerning source metasomatism, the depth of differentiation, the potential role of amphibole fractionation, and the time scales involved. Basaltic andesites on Batan Island (Philippines) contain ≥150 Ma peridotite fragments encased in hornblendite and gabbroic rinds produced via melt-rock reaction. The peridotites have some of the lightest δ7Li and δ57Fe values yet measured in mantle rocks. These values are too fractionated to have been created solely by equilibrium partial melting and thus require a combination of melt depletion and slab fluid addition and may be derived from diffusion-modified melt channel wall rocks. Stable isotope signals are easily modified by diffusive equilibration between peridotite and host magma, so the preservation of light δ7Li and δ57Fe here suggests magma ascent rates of ∼10 km yr−1. We show that melt–wall rock reactions at ∼25–30 km depth led to the crystallization of amphibole (± plagioclase) followed by gabbroic fractionation at ∼7 km depth. The former provides a location and mechanism for the “cryptic” amphibole fractionation observed in these and perhaps many other arc lavas and may obviate the requirement for delamination of cumulates

Nature of the Earth's earliest crust from hafnium isotopes in single detrital zircons

Continental crust forms from, and thus chemically depletes, the Earth's mantle. Evidence that the Earth's mantle was already chemically depleted by melting before the formation of today's oldest surviving crust has been presented in the form of Sm-Nd isotope studies of 3.8-4.0 billion years old rocks from Greenland(1-5) and Canada(5-7). But this interpretation has been questioned because of the possibility that subsequent perturbations may have re-equilibrated the neodymium-isotope compositions of these rocks(8). Independent and more robust evidence for the origin of the earliest crust and depletion of the Archaean mantle can potentially be provided by hafnium-isotope compositions of zircon, a mineral whose age can be precisely determined by U-Pb dating, and which can survive metamorphisms(4). But the amounts of hafnium in single zircon grains are too small for the isotopic composition to be precisely analysed by conventional methods. Here we report hafnium-isotope data, obtained using the new technique of multiple-collector plasma-source mass spectrometry(9), for 37 individual grains of the oldest known terrestrial zircons (from the Narryer Gneiss Complex, Australia, with U-Pb ages of up to 4.14 Gyr (refs 10-13)). We find that none of the grains has a depleted mantle signature, but that many were derived from a source with a hafnium-isotope composition similar to that of chondritic meteorites. Furthermore, more than half of the analysed grains seem to have formed by remelting of significantly older crust, indicating that crustal preservation and subsequent reworking might have been important processes from earliest times.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/62681/1/399252a0.pd

Sr-Nd isotope geochemistry of the early Precambrian sub-alkaline mafic igneous rocks from the southern Bastar craton, Central India

Sr–Nd isotope data are reported for the early Precambrian sub-alkaline mafic igneous rocks of the southern Bastar craton, central India. These mafic rocks are mostly dykes but there are a few volcanic exposures. Field relationships together with the petrological and geochemical characteristics of these mafic dykes divide them into two groups; Meso-Neoarchaean sub-alkaline mafic dykes (BD1) and Paleoproterozoic (1.88 Ga) sub-alkaline mafic dykes (BD2). The mafic volcanics are Neoarchaean in age and have very close geochemical relationships with the BD1 type. The two groups have distinctly different concentrations of high-field strength (HFSE) and rare earth elements (REE). The BD2 dykes have higher concentrations of HFSE and REE than the BD1 dykes and associated volcanics and both groups have very distinctive petrogenetic histories. These rocks display a limited range of initial 143Nd/144Nd but a wide range of apparent initial 87Sr/86Sr. Initial 143Nd/144Nd values in the BD1 dykes and associated volcanics vary between 0.509149 and 0.509466 and in the BD2 dykes the variation is between 0.510303 and 0.510511. All samples have positive &#949;Nd values the BD1 dykes and associated volcanics have &#949;Nd values between +0.3 and +6.5 and the BD2 dykes between +1.9 to +6.0. Trace element and Nd isotope data do not suggest severe crustal contamination during the emplacement of the studied rocks. The positive &#949;Nd values suggest their derivation from a depleted mantle source. Overlapping positive &#949;Nd values suggest that a similar mantle source tapped by variable melt fractions at different times was responsible for the genesis of BD1 (and associated volcanics) and BD2 mafic dykes. The Rb–Sr system is susceptible to alteration and resetting during post-magmatic alteration and metamorphism. Many of the samples studied have anomalous apparent initial 87Sr/86Sr suggesting post-magmatic changes of the Rb–Sr system which severely restricts the use of Rb–Sr for petrogenetic interpretation