Machine learning-based Naive Bayes approach for divulgence of Spam Comment in Youtube station

In the 21st Century, web-based media assumes an indispensable part in the interaction and communication of civilization. As an illustration of web-based media viz. YouTube, Facebook, Twitter, etc., can increase the social regard of a person just as a gathering. Yet, every innovation has its pros as well as cons. In some YouTube channels, a machine-made spam remark is produced on that recordings, moreover, a few phony clients additionally remark a spam comment which creates an adverse effect on that YouTube channel.  The spam remarks can be distinguished by using AI (artificial intelligence) which is based on different Algorithms namely Naive Bayes, SVM, Random Forest, ANN, etc. The present investigation is focussed on a machine learning-based Naive Bayes classifier ordered methodology for the identification of spam remarks on YouTub

Machine learning-based Naive Bayes approach for divulgence of Spam Comment in Youtube station

In the 21st Century, web-based media assumes an indispensable part in the interaction and communication of civilization. As an illustration of web-based media viz. YouTube, Facebook, Twitter, etc., can increase the social regard of a person just as a gathering. Yet, every innovation has its pros as well as cons. In some YouTube channels, a machine-made spam remark is produced on that recordings, moreover, a few phony clients additionally remark a spam comment which creates an adverse effect on that YouTube channel.  The spam remarks can be distinguished by using AI (artificial intelligence) which is based on different Algorithms namely Naive Bayes, SVM, Random Forest, ANN, etc. The present investigation is focussed on a machine learning-based Naive Bayes classifier ordered methodology for the identification of spam remarks on YouTub

Subverting covalency gives rise to ionic bonding in high spin states of heterodiatomics

Understanding chemical bonding in second row diatomics has been central to elucidating the basics of bonding itself.1 Bond strength and number of bonds are two factors that decide the reactivity of molecules. While bond strengths have been theoretically computed accurately and experimentally determined, the number of bonds has been a more contentious issue especially for complicated multi-reference systems such as C2.2,3 We have developed an experimentally verifiable approach to determine the number of bonds from excited spin state potential energy surfaces. On applying this to a series of hetero-diatomics of the second row, we obtain the surprising phenomena of an inverted charge transfer ionic state after the covalent bonds in the species are broken via higher spin states. These ionic states are ubiquitous in all heterodiatomics and quite contrary to our expectations in non-metallic systems

Resolving the Quadruple Bonding Conundrum in C2 Using Insights Derived from Excited State Potential Energy Surfaces: A Molecular Orbital Perspective

The question of quadruple bonding in C2 has emerged as a hot button issue, with opinions sharply divided between the practitioners of Valence Bond (VB) and Molecular Orbital (MO) theory. Here, we have systematically studied the Potential Energy Curves (PECs) of low lying high spin sigma states of C2, N2 and Be2 and HC≡CH using several MO based techniques such as CASSCF, RASSCF and MRCI. The analyses of the PECs for the 2S+1Σg/u (with 2S+1=1,3,5,7,9) states of C2 and comparisons with those of relevant dimers and the respective wavefunctions were conducted. We contend that unlike in the case of N2 and HC≡CH, the presence of a deep minimum in the 7Σ state of C2 and CN+ suggest a latent quadruple bonding nature in these two dimers. Hence, we have struck a reconciliatory note between the MO and VB approaches. The evidence provided by us can be experimentally verified, thus providing the window so that the narrative can move beyond theoretical conjectures

Pulmonary Function Studies of Healthy Non-smoking Male University Students of Kolkata, India — Revisited

Background: Pulmonary function tests (PFTs) need to be revisited in light of rapid economic growth and industrial development. Questions have been raised about the validity of existing population-specific norms for predicting PFTs, and therefore, the present study aimed to determine the applicability of existing norms for PFTs in young healthy non-smoking male university students of Kolkata. Methods: PFTs were carried out for 87 non-smoking male university students who were randomly sampled from the University of Calcutta, Kolkata, India. Results: The PFTs data obtained in this study did not show a significant variation with that obtained in a previous study. Significant (P < 0.001) differences in the forced expiratory volume in 1 s (FEV1%) and peak expiratory flow rate (PEFR) between the two studies may be attributed to differences in the age and body height, which exhibited significant correlations with the vital capacity (VC), forced vital capacity (FVC), FEV1, FEV1%, and PEFR. Regression equations have been computed to predict PFTs parameters from age and body height. Conclusion: Pulmonary function in the university students of Kolkata was found to have remained mostly unchanged in the last 24 years. The equations computed in this study are considered preferable owing to their substantially smaller standard error of estimate (SEE) than those proposed in the previous study

Uncovering the Synchronous Role of Bis-borane with Nucleophilic Solvent as Frustrated Lewis pair in Metal-free Catalytic Dehydrogenation of Ammonia-borane

Metal free catalysis has emerged as a viable alternative for transition metal based catalysts for enabling different chemical processes, particularly for de/hydrogenation reactions. Herein, employing theoretical studies we reveal the unexpected Frustrated Lewis Pair like reactivity of a boron based catalyst, 9,10-dichlorodiboraanthracene and the ethereal solvent to enable dehydrogenation of ammonia-borane (NH3BH3, AB) under mild conditions. The mechanistic channels thus uncovered reveal that the boron catalyst abstracts a hydride from NH3BH3 followed by crucial stabilisation of the NH3BH2+ moiety by the nucleophilic action of the solvent. H2 is released by the combination of hydride and proton from the borohydride moiety and the solvated NH3BH2+ respectively. Catalysis becomes unfeasible if the Lewis base-like action of the ethereal solvent is not taken into consideration. Thus it is suggested that the clandestine partnership of the Lewis Acid, Boron catalyst and the Lewis Base, ethereal solvent, i.e. FLP like action enables dehydrogenation of NH3BH3 in the instant case