Carrier-envelope phase control over pathway interference in strong-field dissociation of H2+_2^+

The dissociation of an H$_2^+$ molecular-ion beam by linearly polarized, carrier-envelope-phase-tagged 5 fs pulses at 4$\times10^{14}$W/cm$^2$ with a central wavelength of 730 nm was studied using a coincidence 3D momentum imaging technique. Carrier-envelope-phase-dependent asymmetries in the emission direction of H$^+$ fragments relative to the laser polarization were observed. These asymmetries are caused by interference of odd and even photon number pathways, where net-zero photon and 1-photon interference predominantly contributes at H$^+$+H kinetic energy releases of 0.2 -- 0.45 eV, and net-2-photon and 1-photon interference contributes at 1.65 -- 1.9 eV. These measurements of the benchmark H$_2^+$ molecule offer the distinct advantage that they can be quantitatively compared with \textit{ab initio} theory to confirm our understanding of strong-field coherent control via the carrier-envelope phase

A computational framework for polyconvex large strain elasticity for geometrically exact beam theory

In this paper, a new computational framework is presented for the analysis of nonlinear beam finite elements subjected to large strains. Specifically, the methodology recently introduced in Bonet et al. (Comput Methods Appl Mech Eng 283:1061–1094, 2015) in the context of three dimensional polyconvex elasticity is extended to the geometrically exact beam model of Simo (Comput Methods Appl Mech Eng 49:55–70, 1985), the starting point of so many other finite element beam type formulations. This new variational framework can be viewed as a continuum degenerate formulation which, moreover, is enhanced by three key novelties. First, in order to facilitate the implementation of the sophisticated polyconvex constitutive laws particularly associated with beams undergoing large strains, a novel tensor cross product algebra by Bonet et al. (Comput Methods Appl Mech Eng 283:1061–1094, 2015) is adopted, leading to an elegant and physically meaningful representation of an otherwise complex computational framework. Second, the paper shows how the novel algebra facilitates the re-expression of any invariant of the deformation gradient, its cofactor and its determinant in terms of the classical beam strain measures. The latter being very useful whenever a classical beam implementation is preferred. This is particularised for the case of a Mooney–Rivlin model although the technique can be straightforwardly generalised to other more complex isotropic and anisotropic polyconvex models. Third, the connection between the two most accepted restrictions for the definition of constitutive models in three dimensional elasticity and beams is shown, bridging the gap between the continuum and its degenerate beam description. This is carried out via a novel insightful representation of the tangent operator

Detailed comparison of the pp -> \pi^+pn and pp -> \pi^+d reactions at 951 MeV

The positively charged pions produced in proton-proton collisions at a beam momentum of 1640 MeV/c were measured in the forward direction with a high resolution magnetic spectrograph. The missing mass distribution shows the bound state (deuteron) clearly separated from the $pn$ continuum. Despite the very good resolution, there is no evidence for any significant production of the $pn$ system in the spin-singlet state. However, the $\sigma(pp\to \pi^+pn)/\sigma(pp\to \pi^+d)$ cross section ratio is about twice as large as that predicted from $S$-wave final-state-interaction theory and it is suggested that this is due to $D$-state effects in the $pn$ system.Comment: 8 pages, 3 figure

The importance of Rydberg orbitals in dissociative ionization of small hydrocarbon molecules in intense laser fields

Much of our intuition about strong-field processes is built upon studies of diatomic molecules, which typically have electronic states that are relatively well separated in energy. In polyatomic molecules, however, the electronic states are closer together, leading to more complex interactions. A combined experimental and theoretical investigation of strong-field ionization followed by hydrogen elimination in the hydrocarbon series C2D2, C2D4 and C2D6 reveals that the photofragment angular distributions can only be understood when the field-dressed orbitals rather than the field-free orbitals are considered. Our measured angular distributions and intensity dependence show that these field-dressed orbitals can have strong Rydberg character for certain orientations of the molecule relative to the laser polarization and that they may contribute significantly to the hydrogen elimination dissociative ionization yield. These findings suggest that Rydberg contributions to field-dressed orbitals should be routinely considered when studying polyatomic molecules in intense laser fields

The role of intuition in entrepreneurship and business venturing decisions

Entrepreneurial intuition is the affectively charged recognition and evaluation of a business venturing opportunity arising as a result of involuntary, rapid, non-conscious, associative processing. This article integrates theories of dual-processing and models of the business venturing (opportunity recognition, evaluation, and exploitation) in a model of entrepreneurial intuition, which links intuitive expertise, cognitive style, somatic state, and the affect heuristic with System 2 interventions and the contingencies of the decision environment. Six research propositions are offered with suggestions for how they can be tested. The theoretical and practical implications of entrepreneurial intuition are discussed in terms of the unfolding of a research agenda relating to this important but under-theorized and under-researched construct in work and organizational psychology

Strong-field dissociation dynamics of molecular dications

Citation: Jochim, B., Severt, T., Zohrabi, M., Ablikim, U., Berry, B., Gaire, B., . . . Ben-Itzhak, I. (2015). Strong-field dissociation dynamics of molecular dications. 635(11). doi:10.1088/1742-6596/635/11/112044We focus on the dissociation of metastable molecular dications induced by intense, ultrafast laser pulses. In particular, we demonstrate the dominant role of commonly-neglected permanent-dipole transitions and drive dissociation via a pump-dump-like mechanism within a single laser pulse. © Published under licence by IOP Publishing Ltd

Carrier-envelope phase control over fragmentation of H2 + and D2

Citation: Zohrabi, M., Berry, B., Kling, N. G., Jochim, B., Severt, T., Ablikim, U., . . . Ben-Itzhak, I. (2015). Carrier-envelope phase control over fragmentation of H2 + and D2. 635(11). doi:10.1088/1742-6596/635/11/112045We demonstrate control over fragmentation of H2 + and D2 molecules via the carrier-envelope phase of sub-5 fs laser pulses. Moreover, we attribute our findings to interferences between different pathways involving different net numbers of photons, revealing "high-order" pathways and the importance of the bandwidth. © Published under licence by IOP Publishing Ltd

Titanium dioxide engineered for near-dispersionless high terahertz permittivity and ultra-low-loss

Realising engineering ceramics to serve as substrate materials in high-performance terahertz(THz) that are low-cost, have low dielectric loss and near-dispersionless broadband, high permittivity, is exceedingly demanding. Such substrates are deployed in, for example, integrated circuits for synthesizing and converting nonplanar and 3D structures into planar forms. The Rutile form of titanium dioxide (TiO2) has been widely accepted as commercially economical candidate substrate that meets demands for both low-loss and high permittivities at sub-THz bands. However, the relationship between its mechanisms of dielectric response to the microstructure have never been systematically investigated in order to engineer ultra-low dielectric-loss and high value, dispersionless permittivities. Here we show TiO2 THz dielectrics with high permittivity (ca. 102.30) and ultra-low loss (ca. 0.0042). These were prepared by insight gleaned from a broad use of materials characterisation methods to successfully engineer porosities, second phase, crystallography shear-planes and oxygen vacancies during sintering. The dielectric loss achieved here is not only with negligible dispersion over 0.2-0.8 THz, but also has the lowest value measured for known high-permittivity dielectrics. We expect the insight afforded by this study will underpin the development of subwavelength-scale, planar integrated circuits, compact high Q-resonators and broadband, slow-light devices in the THz band

The importance of Rydberg orbitals in dissociative ionization of small hydrocarbon molecules in intense few-cycle laser pulses

Citation: Jochim, B., Siemering, R., Zohrabi, M., Voznyuk, A., Mahowald, J. B., Schmitz, D. G., . . . De Vivie-Riedle, R. (2015). The importance of Rydberg orbitals in dissociative ionization of small hydrocarbon molecules in intense few-cycle laser pulses. 635(11). doi:10.1088/1742-6596/635/11/112043We demonstrate the importance of ionization from Rydberg orbitals via experimental and theoretical work focusing on the strong-field dissociative single ionization of small hydrocarbons. Our findings suggest that Rydberg states should be routinely considered when studying polyatomic molecules in intense laser fields. © Published under licence by IOP Publishing Ltd.Additional Authors: Wells, E.;De Vivie-Riedle, R