854 research outputs found
Etude du comportement paramagnétique des actinides (IV) (Th, U, Np et Pu) en solution en présence de ligands
International audienceLa spectroscopie RMN est une technique capable de fournir des informations structurales sur des complexes métalliques en solution. Elle peut être appliquée à l’analyse de petites molécules en chimie organique, de protéines (macros molécules) en biologie mais aussi en chimie nucléaire avec la nucléarisation des spectromètres [1]. La présence d’un Actinide (An), avec des électrons 5f non appariés, génère une modification du spectre RMN (un élargissement et/ou une variation du déplacement chimique des pics) caractéristique du paramagnétisme du cation.Dans le cas des complexes paramagnétiques de Ln (éléments 4), le déplacement chimique total est modélisé par l’équation de Bleaney (équations (a) et (b)) [2]. Il dépend du déplacement chimique paramagnétique induit qui peut être décomposé en deux contributions : un terme de contact (délocalisation de l’électron sur l’atome donneur du ligand) et un terme dipolaire (interaction entre le spin électronique et nucléaire à travers l’espace). A partir de ce dernier terme, on peut déduire des informations structurales en utilisant les constantes de Bleaney
Simulations of protostellar collapse using multigroup radiation hydrodynamics. I. The first collapse
Radiative transfer plays a major role in the process of star formation. Many
simulations of gravitational collapse of a cold gas cloud followed by the
formation of a protostellar core use a grey treatment of radiative transfer
coupled to the hydrodynamics. However, dust opacities which dominate extinction
show large variations as a function of frequency. In this paper, we used
frequency-dependent radiative transfer to investigate the influence of the
opacity variations on the properties of Larson's first core. We used a
multigroup M1 moment model in a 1D radiation hydrodynamics code to simulate the
spherically symmetric collapse of a 1 solar mass cloud core. Monochromatic dust
opacities for five different temperature ranges were used to compute Planck and
Rosseland means inside each frequency group. The results are very consistent
with previous studies and only small differences were observed between the grey
and multigroup simulations. For a same central density, the multigroup
simulations tend to produce first cores with a slightly higher radius and
central temperature. We also performed simulations of the collapse of a 10 and
0.1 solar mass cloud, which showed the properties of the first core to be
independent of the initial cloud mass, with again no major differences between
grey and multigroup models. For Larson's first collapse, where temperatures
remain below 2000 K, the vast majority of the radiation energy lies in the IR
regime and the system is optically thick. In this regime, the grey
approximation does a good job reproducing the correct opacities, as long as
there are no large opacity variations on scales much smaller than the width of
the Planck function. The multigroup method is however expected to yield more
important differences in the later stages of the collapse when high energy (UV
and X-ray) radiation is present and matter and radiation are strongly
decoupled.Comment: 9 pages, 5 figures, accepted for publication in A&
Theoretical principles of petroleum hydrogeology of the West Siberian megabasin (WSMB)
Comprehensive study of the chemical and gas composition, temperatures, levels, pressure of deep underground water in deep wells is associated with the beginning of the systematic development of the oil and gas potential in Western Siberia and the first discovery of large deposits here. The development of new branches of hydrogeology is due to the fact of more and more available data. Thus, fundamental understandings of the WSMB hydrogeological conditions are being translated into new theories. Geodynamically, the WSMB structure was revised and based on hydrogeological data, regional and local prediction of oil and gas occurrence exploration criteria were developed. Based on the dispersion halo water-dissolved substance theory, exploration methodology of "neglected" deposits were formulated, conceptual issues of technogenic changes of oil and gas hydrogeosphere areas were being developed
Numerical simulation of strongly nonlinear and dispersive waves using a Green-Naghdi model
We investigate here the ability of a Green-Naghdi model to reproduce strongly
nonlinear and dispersive wave propagation. We test in particular the behavior
of the new hybrid finite-volume and finite-difference splitting approach
recently developed by the authors and collaborators on the challenging
benchmark of waves propagating over a submerged bar. Such a configuration
requires a model with very good dispersive properties, because of the
high-order harmonics generated by topography-induced nonlinear interactions. We
thus depart from the aforementioned work and choose to use a new Green-Naghdi
system with improved frequency dispersion characteristics. The absence of dry
areas also allows us to improve the treatment of the hyperbolic part of the
equations. This leads to very satisfying results for the demanding benchmarks
under consideration
Assessment of MERIS ocean color data products for European seas
The accuracy of marine data products from the Medium Resolution Imaging Spectrometer (MERIS) operated on board the Envisat platform is investigated with the aid of in situ geographically distributed measurements from different European seas. The assessment focuses on standard products from the 2012 data update commonly identified as 3rd Reprocessing. Results indicate atmospherically corrected data affected by a negative bias of several tens percent at the 413 nm center wavelength, significantly decreasing to a few percent at 560 nm and increasing again at 665 nm. Such an underestimate at the blue center wavelengths leads to an average overestimate of the algal-1 MERIS pigment index largely exceeding 100% for the considered European seas. A comparable overestimate is also observed for the algal-2 pigment index independently determined from top-of-atmosphere radiance through the application of neural networks
Dilepton production in heavy ion collisions at intermediate energies
We present a unified description of the vector meson and dilepton production
in elementary and in heavy ion reactions. The production of vector mesons
() is described via the excitation of nuclear resonances ().
The theoretical framework is an extended vector meson dominance model (eVMD).
The treatment of the resonance decays with arbitrary spin is
covariant and kinematically complete. The eVMD includes thereby excited vector
meson states in the transition form factors. This ensures correct asymptotics
and provides a unified description of photonic and mesonic decays. The
resonance model is successfully applied to the production in
reactions. The same model is applied to the dilepton production in elementary
reactions (). Corresponding data are well reproduced. However, when
the model is applied to heavy ion reactions in the BEVALAC/SIS energy range the
experimental dilepton spectra measured by the DLS Collaboration are
significantly underestimated at small invariant masses. As a possible solution
of this problem the destruction of quantum interference in a dense medium is
discussed. A decoherent emission through vector mesons decays enhances the
corresponding dilepton yield in heavy ion reactions. In the vicinity of the
-peak the reproduction of the data requires further a substantial
collisional broadening of the and in particular of the meson.Comment: 32 pages revtex, 19 figures, to appear in PR
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