Evidence for Miocene subduction beneath the Alboran Sea (Western Mediterranean) from 40Ar/39Ar age dating and the geochemistry of volcanic rocks from holes 977A and 978A

Volcanic pebbles in gravels from Sites 977 and 978 in the Alboran Sea (western Mediterranean) were dated (using the 40Ar/ 39Ar single-crystal laser technique) and analyzed for their major- and trace-element compositions (determined by X-ray fluorescence and inductively coupled plasma-mass spectrometry). The samples range from basalts to rhyolites, and belong to the tholeiitic, calc-alkaline, and shoshonitic series. Single-crystal and step-heating laser 40Ar/39Ar analyses of plagioclase, sanidine, biotite, and amphibole phenocrysts from basaltic to rhyolitic samples indicate that eruptions occurred between 6.1 and 12.1 Ma. The age data conform to the stratigraphy and agree with microfossil ages, when available. The major-element and compatible trace-element data of samples with H2O < 4 wt% show systematic variations, consistent with fractionation of the observed phenocryst phases (plagioclase, olivine, clinopyroxene, magnetite, hornblende, quartz, and biotite). The incompatible-element patterns formed by normalizing to primitive mantle for all samples show spiked patterns with peaks generally at mobile elements and troughs at immobile elements, in particular Nb and Ta. The calc-alkaline affinities and the incompatible-element systematics are characteristic of subduction zone volcanism, which indicates that subduction occurred beneath the eastern Alboran from 6 to at least 12 Ma. We propose that the change in chemistry from calc-alkaline and potassic to sodic compositions between 5– 6 Ma reflects detachment of the subducting slab. Uplift of the Strait of Gibraltar, associated with this detachment, could have caused the Messinian Salinity Crises

MPI-DING reference glasses for in situ microanalysis: New reference values for element concentrations and isotope ratios

We present new analytical data of major and trace elements for the geological MPI-DING glasses KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, BM90/21-G, T1-G, and ATHO-G. Different analytical methods were used to obtain a large spectrum of major and trace element data, in particular, EPMA, SIMS, LA-ICPMS, and isotope dilution by TIMS and ICPMS. Altogether, more than 60 qualified geochemical laboratories worldwide contributed to the analyses, allowing us to present new reference and information values and their uncertainties (at 95% confidence level) for up to 74 elements. We complied with the recommendations for the certification of geological reference materials by the International Association of Geoanalysts (IAG). The reference values were derived from the results of 16 independent techniques, including definitive (isotope dilution) and comparative bulk (e.g., INAA, ICPMS, SSMS) and microanalytical (e.g., LA-ICPMS, SIMS, EPMA) methods. Agreement between two or more independent methods and the use of definitive methods provided traceability to the fullest extent possible. We also present new and recently published data for the isotopic compositions of H, B, Li, O, Ca, Sr, Nd, Hf, and Pb. The results were mainly obtained by high-precision bulk techniques, such as TIMS and MC-ICPMS. In addition, LA-ICPMS and SIMS isotope data of B, Li, and Pb are presented. Copyright 2006 by the American Geophysical Union

MPI-Ding reference glasses for in situ microanalysis: New reference values for element concentrations and isotope ratios

We present new analytical data of major and trace elements for the geological MPI-DING glasses KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, BM90/21-G, T1-G, and ATHO-G. Different analytical methods were used to obtain a large spectrum of major and trace element data, in particular, EPMA, SIMS, LA-ICPMS, and isotope dilution by TIMS and ICPMS. Altogether, more than 60 qualified geochemical laboratories worldwide contributed to the analyses, allowing us to present new reference and information values and their uncertainties (at 95% confidence level) for up to 74 elements. We complied with the recommendations for the certification of geological reference materials by the International Association of Geoanalysts (IAG). The reference values were derived from the results of 16 independent techniques, including definitive (isotope dilution) and comparative bulk (e.g., INAA, ICPMS, SSMS) and microanalytical (e.g., LA-ICPMS, SIMS, EPMA) methods. Agreement between two or more independent methods and the use of definitive methods provided traceability to the fullest extent possible. We also present new and recently published data for the isotopic compositions of H, B, Li, O, Ca, Sr, Nd, Hf, and Pb. The results were mainly obtained by high-precision bulk techniques, such as TIMS and MC-ICPMS. In addition, LA-ICPMS and SIMS isotope data of B, Li, and Pb are presented