357 research outputs found
Catching a Glimpse: A Directorial Investigation & Collaboration on PROCEDURE TO EXIT AN ENCLOSED SPACE
Senior Project submitted to The Division of Arts of Bard College
The contribution of hydrogen to the corrosion of 2024 aluminium alloy exposed to thermal and environmental cycling in chloride media
This work is focused on the role of hydrogen in corrosion damage induced by the cyclic exposure of 2024 aluminium alloy to chloride media with air emersion periods at room and/or negative temperatures. Various analysis and microscopic observation techniques were applied at intergranular corrosion defects. A mechanism involving the contribution of hydrogen to the degradation of the alloy mechanical properties is presented. Several consecutive stress states appear during cycling, resulting from volume expansion of the electrolyte trapped in the intergranular defects during emersion phases at -20°C. These stress states lead to hydrogen diffusion, transport and trapping
Hydrogen-enhanced local plasticity in aluminum: an ab initio study
Dislocation core properties of Al with and without H impurities are studied
using the Peierls-Nabarro model with parameters determined by ab initio
calculations. We find that H not only facilitates dislocation emission from the
crack tip but also enhances dislocation mobility dramatically, leading to
macroscopically softening and thinning of the material ahead of the crack tip.
We observe strong binding between H and dislocation cores, with the binding
energy depending on dislocation character. This dependence can directly affect
the mechanical properties of Al by inhibiting dislocation cross-slip and
developing slip planarity.Comment: 4 pages, 3 figure
Ab initio study of the modification of elastic properties of alpha-iron by hydrostatic strain and by hydrogen interstitials
The effect of hydrostatic strain and of interstitial hydrogen on the elastic
properties of -iron is investigated using \textit{ab initio}
density-functional theory calculations. We find that the cubic elastic
constants and the polycrystalline elastic moduli to a good approximation
decrease linearly with increasing hydrogen concentration. This net strength
reduction can be partitioned into a strengthening electronic effect which is
overcome by a softening volumetric effect. The calculated hydrogen-dependent
elastic constants are used to determine the polycrystalline elastic moduli and
anisotropic elastic shear moduli. For the key slip planes in -iron,
and , we find a shear modulus reduction of
approximately 1.6% per at.% H.Comment: Updated first part of 1009.378
Computer simulation of intergranular stress corrosion cracking via hydrogen embrittlement
Fractographic study of transverse cracks in a fibre composite
Transverse fracture of unidirectional fibre composites was studied in a model glass/epoxy composite in which 1 mm-diameter rods had been used in place of fibres. The fracture surface resulting from transverse cracking in this model system was studied by scanning electron microscopy (SEM). The interaction of the crack with the epoxy matrix resin and the glass rods was the following: Cracks in the resin appeared to have effected a debonding at the glassmatrix interface before reaching the glass. The debonding then propagated along the interface and induced secondary cracks ahead of the primary debonding crack. The confluence of the secondary and primary cracks resulted in sharp ridges being formed on the matrix resin surface, produced by plastic deformation of the rigid epoxy resin. These appeared as a field of parabolic marks. Considering the brittleness of the resin, the amount of plastic deformation indicated by the ridges was astonishing. As the debonding continued around the glass rod, a transverse corrugated texture developed on the resin surface, again produced by plastic deformation. Finally, the cracks reentered the matrix from small patches of polymer adhering especially strongly to the glass surface. The overall fracture energy of transverse cracking of unidirectional fibre composites is suggested to consist, therefore, of the following elements in addition to crack propagation in the matrix resin: (a) the glass-resin debonding before the incoming cracks reach the glass, (b) the initiation of secondary cracks or debonds at the interface, (c) the plastic deformation in generating the ridges on the rigid resin surface, appearing both as the paraboloids and the transverse corrugation, and (d) cracking of the matrix reinitiated at the opposite side of the glass. The use of an enlarged glass reinforcement in this study provided a more direct observation of the properties of transverse crack propagation in composite materials than would have been possible with the small, roughly 10 μ m fibres.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/44691/1/10853_2005_Article_BF01111915.pd
Investigation of hydrogen assisted cracking in acicular ferrite using site-specific micro-fracture tests
CHARTING THE FRACTURE TOUGHNESS CHARACTERISTICS OF CASTINGS USING THE DOUBLE TORSION METHOD
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