210 research outputs found

    ΠœΠ΅Ρ‚ΠΎΠ΄ΠΎΠ»ΠΎΠ³ΠΈΡ‡Π΅ΡΠΊΠΈΠ΅ возмоТности β€œΠ‘Π»ΡƒΠΌΠΈΠ½Π³Ρ‚ΠΎΠ½ΡΠΊΠΎΠΉ ΡˆΠΊΠΎΠ»Ρ‹β€: ΠΈ пСрспСктивы развития соврСмСнного нСоинституционализма

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    Π’ ΡΡ‚Π°Ρ‚ΡŒΠ΅ Π°Π½Π°Π»ΠΈΠ·ΠΈΡ€ΡƒΡŽΡ‚ΡΡ ΠΈΠ½ΡΡ‚ΠΈΡ‚ΡƒΡ†ΠΈΠΎΠ½Π°Π»ΡŒΠ½Ρ‹Π΅ процСссы формирования Π½Π°ΡƒΡ‡Π½ΠΎΠΉ Блумингтонской ΡˆΠΊΠΎΠ»Ρ‹ Π·Π° послСднюю Ρ‡Π΅Ρ‚Π²Π΅Ρ€Ρ‚ΡŒ Π²Π΅ΠΊΠ°, которая тСсно связана с ΠΊΠΎΠ½Ρ†Π΅ΠΏΡ‚ΡƒΠ°Π»ΡŒΠ½Ρ‹ΠΌ ΠΈ мСтодологичСским наслСдиСм Π­Π»ΠΈΠ½ΠΎΡ€ ΠžΡΡ‚Ρ€ΠΎΠΌ, Π° Ρ‚Π°ΠΊΠΆΠ΅ Ρ€Π°Π±ΠΎΡ‚Π°ΠΌΠΈ Π΅Π΅ ΠΊΠΎΠ»Π»Π΅Π³ ΠΈ ΡƒΡ‡Π΅Π½ΠΈΠΊΠΎΠ². Автор ΠΏΠΎΠ΄Ρ‡Π΅Ρ€ΠΊΠΈΠ²Π°Π΅Ρ‚ Π·Π½Π°Ρ‡ΠΈΠΌΠΎΡΡ‚ΡŒ Π½Π΅ΠΎΠΈΠ½ΡΡ‚ΠΈΡ‚ΡƒΡ†ΠΈΠΎΠ½Π°Π»ΡŒΠ½ΠΎΠΉ ΠΌΠ΅Ρ‚ΠΎΠ΄ΠΎΠ»ΠΎΠ³ΠΈΠΈ Π² соврСмСнной социологичСской мысли, Π² исслСдованиях ΡΠΎΡ†ΠΈΠ°Π»ΡŒΠ½Ρ‹Ρ… Π΄ΠΈΠ»Π΅ΠΌΠΌ, ΠΎΠ±Ρ‰ΠΈΡ… рСсурсов, ΠΊΠΎΠ»Π»Π΅ΠΊΡ‚ΠΈΠ²Π½Ρ‹Ρ… дСйствий ΠΈ идСнтичности. По мнСнию Π°Π²Ρ‚ΠΎΡ€Π°, исслСдования Блумингтонской ΡˆΠΊΠΎΠ»Ρ‹ ΠΏΠΎΠΏΡ‹Ρ‚Π°Π»ΠΈΡΡŒ ΠΏΡ€Π΅Π΄Π»ΠΎΠΆΠΈΡ‚ΡŒ Ρ€Π΅ΡˆΠ΅Π½ΠΈΠ΅ ΠΏΡ€ΠΎΠ±Π»Π΅ΠΌΡ‹ ΡΠΎΡ†ΠΈΠ°Π»ΡŒΠ½ΠΎ-экономичСского развития Ρ‚Ρ€Π°Π΄ΠΈΡ†ΠΈΠΎΠ½Π½Ρ‹Ρ… сообщСств Π² ΡΡ‚Π°Π±ΠΈΠ»ΡŒΠ½ΠΎΡΡ‚ΠΈ Π² условиях ΡΠΎΡ†ΠΈΠ΅Ρ‚Π°Π»ΡŒΠ½ΠΎΠΉ нСопрСдСлСнности, ΠΈΡΠΏΠΎΠ»ΡŒΠ·ΡƒΡ Π½Π΅ΠΎΠΈΠ½ΡΡ‚ΠΈΡ‚ΡƒΡ†ΠΈΠΎΠ½Π°Π»ΡŒΠ½ΡƒΡŽ ΠΌΠ΅Ρ‚ΠΎΠ΄ΠΎΠ»ΠΎΠ³ΠΈΡŽ. Π”Π°Π»ΡŒΠ½Π΅ΠΉΡˆΠ΅Π΅ мСтодологичСскоС Ρ€Π°Π·Π²ΠΈΡ‚ΠΈΠ΅ Блумингтонской ΡˆΠΊΠΎΠ»Ρ‹ Π°Π²Ρ‚ΠΎΡ€ связываСт с ΠΊΠΎΠ½ΠΊΡ€Π΅Ρ‚ΠΈΠ·Π°Ρ†ΠΈΠ΅ΠΉ ΠΎΠΏΡ€Π΅Π΄Π΅Π»Π΅Π½ΠΈΠΉ ΡΠΎΡ†ΠΈΠ°Π»ΡŒΠ½Ρ‹Ρ… Π΄ΠΈΠ»Π΅ΠΌΠΌ ΠΈ ΠΎΠ±Ρ‰ΠΈΡ… рСсурсов, ΠΈΠ·ΡƒΡ‡Π΅Π½ΠΈΠ΅ΠΌ ΠΏΡ€ΠΎΠ±Π»Π΅ΠΌ ΠΊΠ°ΠΊ устойчивости, Ρ‚Π°ΠΊ ΠΈ распада институтов, ΠΈ ΠΈΡ… трансформации ΠΈΠ· динамичСского равновСсия с ΠΏΠΎΠ·ΠΈΡ‚ΠΈΠ²Π½Ρ‹ΠΌΠΈ Π³Π½Π΅Π·Π΄ΠΎΠ²Ρ‹ΠΌΠΈ экстСрналиями Π² Π΄Π΅Π²ΠΈΠ°Π½Ρ‚Π½ΠΎΠ΅ нСравновСсиС. In the article the institutional processes of Bloomington school formation are analyzed. Such processes are closely connected to the conceptual and methodological heritage of Elinor Ostrom and her colleagues and students. The author underlies importance of neo-institutional methodology in the contemporary sociological thought, in studies of social dilemmas, common-pool resources, collective actions and identity. In author’s opinion, by using neo-institutional methodology, studies of the Bloomington school have tried to find a solution of the problem of stable social-economic development of traditional societies. In author’s opinion, the further development of the Bloomington school is connected with further defining social dilemmas and common-pool resources, studies of institutional stability and institutional disintegration and transformations of institutions from dynamic equilibrium with positive nested externalities to dynamic non-equilibrium

    Lyapunov-like Conditions of Forward Invariance and Boundedness for a Class of Unstable Systems

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    We provide Lyapunov-like characterizations of boundedness and convergence of non-trivial solutions for a class of systems with unstable invariant sets. Examples of systems to which the results may apply include interconnections of stable subsystems with one-dimensional unstable dynamics or critically stable dynamics. Systems of this type arise in problems of nonlinear output regulation, parameter estimation and adaptive control. In addition to providing boundedness and convergence criteria the results allow to derive domains of initial conditions corresponding to solutions leaving a given neighborhood of the origin at least once. In contrast to other works addressing convergence issues in unstable systems, our results require neither input-output characterizations for the stable part nor estimates of convergence rates. The results are illustrated with examples, including the analysis of phase synchronization of neural oscillators with heterogenous coupling

    ΠœΠ΅Ρ‚ΠΎΠ΄ΠΎΠ»ΠΎΠ³ΠΈΡ‡Π΅ΡΠΊΠΈΠ΅ возмоТности β€œΠ‘Π»ΡƒΠΌΠΈΠ½Π³Ρ‚ΠΎΠ½ΡΠΊΠΎΠΉ ΡˆΠΊΠΎΠ»Ρ‹β€: ΠΈ пСрспСктивы развития соврСмСнного нСоинституционализма

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    Π’ ΡΡ‚Π°Ρ‚ΡŒΠ΅ Π°Π½Π°Π»ΠΈΠ·ΠΈΡ€ΡƒΡŽΡ‚ΡΡ ΠΈΠ½ΡΡ‚ΠΈΡ‚ΡƒΡ†ΠΈΠΎΠ½Π°Π»ΡŒΠ½Ρ‹Π΅ процСссы формирования Π½Π°ΡƒΡ‡Π½ΠΎΠΉ Блумингтонской ΡˆΠΊΠΎΠ»Ρ‹ Π·Π° послСднюю Ρ‡Π΅Ρ‚Π²Π΅Ρ€Ρ‚ΡŒ Π²Π΅ΠΊΠ°, которая тСсно связана с ΠΊΠΎΠ½Ρ†Π΅ΠΏΡ‚ΡƒΠ°Π»ΡŒΠ½Ρ‹ΠΌ ΠΈ мСтодологичСским наслСдиСм Π­Π»ΠΈΠ½ΠΎΡ€ ΠžΡΡ‚Ρ€ΠΎΠΌ, Π° Ρ‚Π°ΠΊΠΆΠ΅ Ρ€Π°Π±ΠΎΡ‚Π°ΠΌΠΈ Π΅Π΅ ΠΊΠΎΠ»Π»Π΅Π³ ΠΈ ΡƒΡ‡Π΅Π½ΠΈΠΊΠΎΠ². Автор ΠΏΠΎΠ΄Ρ‡Π΅Ρ€ΠΊΠΈΠ²Π°Π΅Ρ‚ Π·Π½Π°Ρ‡ΠΈΠΌΠΎΡΡ‚ΡŒ Π½Π΅ΠΎΠΈΠ½ΡΡ‚ΠΈΡ‚ΡƒΡ†ΠΈΠΎΠ½Π°Π»ΡŒΠ½ΠΎΠΉ ΠΌΠ΅Ρ‚ΠΎΠ΄ΠΎΠ»ΠΎΠ³ΠΈΠΈ Π² соврСмСнной социологичСской мысли, Π² исслСдованиях ΡΠΎΡ†ΠΈΠ°Π»ΡŒΠ½Ρ‹Ρ… Π΄ΠΈΠ»Π΅ΠΌΠΌ, ΠΎΠ±Ρ‰ΠΈΡ… рСсурсов, ΠΊΠΎΠ»Π»Π΅ΠΊΡ‚ΠΈΠ²Π½Ρ‹Ρ… дСйствий ΠΈ идСнтичности. По мнСнию Π°Π²Ρ‚ΠΎΡ€Π°, исслСдования Блумингтонской ΡˆΠΊΠΎΠ»Ρ‹ ΠΏΠΎΠΏΡ‹Ρ‚Π°Π»ΠΈΡΡŒ ΠΏΡ€Π΅Π΄Π»ΠΎΠΆΠΈΡ‚ΡŒ Ρ€Π΅ΡˆΠ΅Π½ΠΈΠ΅ ΠΏΡ€ΠΎΠ±Π»Π΅ΠΌΡ‹ ΡΠΎΡ†ΠΈΠ°Π»ΡŒΠ½ΠΎ-экономичСского развития Ρ‚Ρ€Π°Π΄ΠΈΡ†ΠΈΠΎΠ½Π½Ρ‹Ρ… сообщСств Π² ΡΡ‚Π°Π±ΠΈΠ»ΡŒΠ½ΠΎΡΡ‚ΠΈ Π² условиях ΡΠΎΡ†ΠΈΠ΅Ρ‚Π°Π»ΡŒΠ½ΠΎΠΉ нСопрСдСлСнности, ΠΈΡΠΏΠΎΠ»ΡŒΠ·ΡƒΡ Π½Π΅ΠΎΠΈΠ½ΡΡ‚ΠΈΡ‚ΡƒΡ†ΠΈΠΎΠ½Π°Π»ΡŒΠ½ΡƒΡŽ ΠΌΠ΅Ρ‚ΠΎΠ΄ΠΎΠ»ΠΎΠ³ΠΈΡŽ. Π”Π°Π»ΡŒΠ½Π΅ΠΉΡˆΠ΅Π΅ мСтодологичСскоС Ρ€Π°Π·Π²ΠΈΡ‚ΠΈΠ΅ Блумингтонской ΡˆΠΊΠΎΠ»Ρ‹ Π°Π²Ρ‚ΠΎΡ€ связываСт с ΠΊΠΎΠ½ΠΊΡ€Π΅Ρ‚ΠΈΠ·Π°Ρ†ΠΈΠ΅ΠΉ ΠΎΠΏΡ€Π΅Π΄Π΅Π»Π΅Π½ΠΈΠΉ ΡΠΎΡ†ΠΈΠ°Π»ΡŒΠ½Ρ‹Ρ… Π΄ΠΈΠ»Π΅ΠΌΠΌ ΠΈ ΠΎΠ±Ρ‰ΠΈΡ… рСсурсов, ΠΈΠ·ΡƒΡ‡Π΅Π½ΠΈΠ΅ΠΌ ΠΏΡ€ΠΎΠ±Π»Π΅ΠΌ ΠΊΠ°ΠΊ устойчивости, Ρ‚Π°ΠΊ ΠΈ распада институтов, ΠΈ ΠΈΡ… трансформации ΠΈΠ· динамичСского равновСсия с ΠΏΠΎΠ·ΠΈΡ‚ΠΈΠ²Π½Ρ‹ΠΌΠΈ Π³Π½Π΅Π·Π΄ΠΎΠ²Ρ‹ΠΌΠΈ экстСрналиями Π² Π΄Π΅Π²ΠΈΠ°Π½Ρ‚Π½ΠΎΠ΅ нСравновСсиС. In the article the institutional processes of Bloomington school formation are analyzed. Such processes are closely connected to the conceptual and methodological heritage of Elinor Ostrom and her colleagues and students. The author underlies importance of neo-institutional methodology in the contemporary sociological thought, in studies of social dilemmas, common-pool resources, collective actions and identity. In author’s opinion, by using neo-institutional methodology, studies of the Bloomington school have tried to find a solution of the problem of stable social-economic development of traditional societies. In author’s opinion, the further development of the Bloomington school is connected with further defining social dilemmas and common-pool resources, studies of institutional stability and institutional disintegration and transformations of institutions from dynamic equilibrium with positive nested externalities to dynamic non-equilibrium

    Production, Physicochemical and Catalytic Properties of Gallium-Containing Zeolite Catalysts

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    Crystalline galloalumino- and gallosilicates with pentasil structure were synthesised under hydrother-mal conditions. The influence of gallium concentration and binder amount both on physicochemical and catalytic properties of a zeolite in the process of C2-C4 light alkanes aromatization and on catalyst deacti-vation due to carbidization has been studied. Acidic properties of gallium-containing pentasils with differ-ent composition were studied using the method of thermoprogrammed ammonia desorption. The forma-tion of strong aproton acidic sites whose composition includes gallium ions was found. It has been shown that isomorphic aluminium replacement by gallium in the pentasil lattice leads to a significant increase in aromatizing activity and period of stable catalyst operation. A decrease in intensity of coking and the formation of less condensed coke deposits with a wide distribution by the structure are observed with the increase in gallium concentration. The introduction of a binder to galloaluminosilicate results in a signifi-cant increase in mechanical strength of a catalyst. It was established that the most efficient catalyst of the above process is a zeolite containing 2.2% of gallium oxide and 1.3% of aluminium oxide and mixed with 20% of the pseudobeumite. The selectivity of the formation of aromatic hydrocarbons reaches 55-60%, the period of stable operation exceeds 350 h. In accordance with the data obtained suggested are the principles of the selection of efficient catalysts of light alkanes aromatization and optimum conditions of the process

    On the birth of limit cycles for non-smooth dynamical systems

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    The main objective of this work is to develop, via Brower degree theory and regularization theory, a variation of the classical averaging method for detecting limit cycles of certain piecewise continuous dynamical systems. In fact, overall results are presented to ensure the existence of limit cycles of such systems. These results may represent new insights in averaging, in particular its relation with non smooth dynamical systems theory. An application is presented in careful detail

    Acidic and Catalytic Properties of Mo-Containing Zeolite Catalysts for Non-Oxidative Methane Conversion

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    The conversion of methane into benzene, toluene and naphthalene at the reaction temperature of 750 Π’Β°C and gas hourly space velocity (GHSV) of 500-1500 h-1 over zeolites modified via impregnation with ammonium heptamolybdate and mechanical mixing with Mo oxide and nanopowder is studied under non-oxidative conditions. It has been established that the highest methane conversion per one run and maximal yield of aromatic hydrocarbons are reached for the sample containing 4.0 mass.% the Mo nanopowder. The stability of Mo-containing zeolite catalysts in the process of methane dehydroaromatization at different GHSV has been studied and a characteristic presence of the induction period caused by the formation of active Mo forms both on the external surface and into the zeolite channels has been established. Both the duration of induction period and stable catalyst operation are decreasing with increasing of GHSV. It was demonstrated that acidic properties of a Mo-containing zeolite catalyst depend on the Mo concentration and method of its introduction

    ВлияниС Ρ‰Π΅Π»ΠΎΡ‡Π½ΠΎΠΉ ΠΎΠ±Ρ€Π°Π±ΠΎΡ‚ΠΊΠΈ Π½Π° Ρ„ΠΈΠ·ΠΈΠΊΠΎ-химичСскиС ΠΈ каталитичСскиС свойства Ρ†Π΅ΠΎΠ»ΠΈΡ‚Π° Ρ‚ΠΈΠΏΠ° ZSM‑5 Π² процСссС прСвращСния прямогонной Π±Π΅Π½Π·ΠΈΠ½ΠΎΠ²ΠΎΠΉ Ρ„Ρ€Π°ΠΊΡ†ΠΈΠΈ Π½Π΅Ρ„Ρ‚ΠΈ

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    Postsynthetic treatment of a ZSM‑5 type zeolite with aqueous solutions of NaOH of various concentrations is carried out. Structural, acidic, and catalytic properties of the initial zeolite and treated samples are investigated in the course of conversion of straight-run gasoline fraction of oil. The main operational characteristics of the obtained high-octane gasolines are determined. The dynamics of deactivation of the initial ZSM‑5 zeolite and the sample subjected to alkaline treatment is reported and the structure of coke deposits is studied. It is found out that alkaline treatment of zeolites leads to a decrease in their crystallinity, specific surface area and specific mesopore volume, while the average pore diameter increases. Also a decrease in the concentration of acid sites with an increase in their strength is observed. As a result of changes in the properties of zeolites, the performance and stability of the catalysts obtained on their basis increase, which contributes to the improvement of the quality of gasoline formed over these catalysts during the conversion of straight-run gasoline fraction of oilΠŸΡ€ΠΎΠ²Π΅Π΄Π΅Π½Π° постсинтСтичСская ΠΎΠ±Ρ€Π°Π±ΠΎΡ‚ΠΊΠ° Ρ†Π΅ΠΎΠ»ΠΈΡ‚Π° Ρ‚ΠΈΠΏΠ° ZSM‑5 Π²ΠΎΠ΄Π½Ρ‹ΠΌΠΈ растворами NaOH Ρ€Π°Π·Π»ΠΈΡ‡Π½ΠΎΠΉ ΠΊΠΎΠ½Ρ†Π΅Π½Ρ‚Ρ€Π°Ρ†ΠΈΠΈ. Π˜ΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½Ρ‹ структурныС, кислотныС ΠΈ каталитичСскиС свойства исходного Ρ†Π΅ΠΎΠ»ΠΈΡ‚Π° ΠΈ ΠΎΠ±Ρ€Π°Π±ΠΎΡ‚Π°Π½Π½Ρ‹Ρ… ΠΎΠ±Ρ€Π°Π·Ρ†ΠΎΠ² Π² процСссС прСвращСния прямогонной Π±Π΅Π½Π·ΠΈΠ½ΠΎΠ²ΠΎΠΉ Ρ„Ρ€Π°ΠΊΡ†ΠΈΠΈ Π½Π΅Ρ„Ρ‚ΠΈ. ΠžΠΏΡ€Π΅Π΄Π΅Π»Π΅Π½Ρ‹ основныС эксплуатационныС характСристики ΠΏΠΎΠ»ΡƒΡ‡Π΅Π½Π½Ρ‹Ρ… высокооктановых Π±Π΅Π½Π·ΠΈΠ½ΠΎΠ². ΠŸΡ€ΠΈΠ²Π΅Π΄Π΅Π½Π° Π΄ΠΈΠ½Π°ΠΌΠΈΠΊΠ° Π΄Π΅Π·Π°ΠΊΡ‚ΠΈΠ²Π°Ρ†ΠΈΠΈ исходного Ρ†Π΅ΠΎΠ»ΠΈΡ‚Π° ZSM‑5 ΠΈ ΠΎΠ±Ρ€Π°Π·Ρ†Π°, ΠΏΠΎΠ΄Π²Π΅Ρ€Π³Π½ΡƒΡ‚ΠΎΠ³ΠΎ Ρ‰Π΅Π»ΠΎΡ‡Π½ΠΎΠΉ ΠΎΠ±Ρ€Π°Π±ΠΎΡ‚ΠΊΠ΅, ΠΈΠ·ΡƒΡ‡Π΅Π½Π° структура коксовых ΠΎΡ‚Π»ΠΎΠΆΠ΅Π½ΠΈΠΉ. УстановлСно, Ρ‡Ρ‚ΠΎ щСлочная ΠΎΠ±Ρ€Π°Π±ΠΎΡ‚ΠΊΠ° Ρ†Π΅ΠΎΠ»ΠΈΡ‚ΠΎΠ² ΠΏΡ€ΠΈΠ²ΠΎΠ΄ΠΈΡ‚ ΠΊ сниТСнию ΠΈΡ… кристалличности, Π²Π΅Π»ΠΈΡ‡ΠΈΠ½Ρ‹ ΡƒΠ΄Π΅Π»ΡŒΠ½ΠΎΠΉ повСрхности ΠΈ ΡƒΠ΄Π΅Π»ΡŒΠ½ΠΎΠ³ΠΎ ΠΎΠ±ΡŠΡ‘ΠΌΠ° ΠΌΠ΅Π·ΠΎΠΏΠΎΡ€, ΡƒΠ²Π΅Π»ΠΈΡ‡Π΅Π½ΠΈΡŽ срСднСго Π΄ΠΈΠ°ΠΌΠ΅Ρ‚Ρ€Π° ΠΏΠΎΡ€, ΡƒΠΌΠ΅Π½ΡŒΡˆΠ΅Π½ΠΈΡŽ ΠΊΠΎΠ½Ρ†Π΅Π½Ρ‚Ρ€Π°Ρ†ΠΈΠΈ кислотных Ρ†Π΅Π½Ρ‚Ρ€ΠΎΠ² ΠΈ ΡƒΠ²Π΅Π»ΠΈΡ‡Π΅Π½ΠΈΡŽ ΠΈΡ… силы. Π’ Ρ€Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Π΅ происходящих ΠΈΠ·ΠΌΠ΅Π½Π΅Π½ΠΈΠΉ свойств Ρ†Π΅ΠΎΠ»ΠΈΡ‚ΠΎΠ² ΠΏΠΎΠ²Ρ‹ΡˆΠ°Π΅Ρ‚ΡΡ ΠΏΡ€ΠΎΠΈΠ·Π²ΠΎΠ΄ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎΡΡ‚ΡŒ ΠΈ ΡΡ‚Π°Π±ΠΈΠ»ΡŒΠ½ΠΎΡΡ‚ΡŒ Ρ€Π°Π±ΠΎΡ‚Ρ‹ ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€ΠΎΠ², ΠΏΠΎΠ»ΡƒΡ‡Π΅Π½Π½Ρ‹Ρ… Π½Π° ΠΈΡ… основС, Π° Ρ‚Π°ΠΊΠΆΠ΅ ΡƒΠ»ΡƒΡ‡ΡˆΠ°Π΅Ρ‚ΡΡ качСство Π±Π΅Π½Π·ΠΈΠ½ΠΎΠ², ΠΎΠ±Ρ€Π°Π·ΡƒΡŽΡ‰ΠΈΡ…ΡΡ Π½Π° Π½ΠΈΡ… Π² процСссС прСвращСния прямогонной Π±Π΅Π½Π·ΠΈΠ½ΠΎΠ²ΠΎΠΉ Ρ„Ρ€Π°ΠΊΡ†ΠΈΠΈ Π½Π΅Ρ„Ρ‚

    Study of the Impact of Post-Synthetic Treatment on the Physicochemical and Catalytic Properties of Zeolite in the Propane-to-Olefin Transformation Process

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    ΠŸΡ€ΠΎΠ²Π΅Π΄Π΅Π½ΠΎ исслСдованиС влияния кислотной ΠΈ Ρ‚Π΅Ρ€ΠΌΠΎΠΏΠ°Ρ€ΠΎΠ²ΠΎΠΉ ΠΎΠ±Ρ€Π°Π±ΠΎΡ‚ΠΎΠΊ Ρ†Π΅ΠΎΠ»ΠΈΡ‚Π° Ρ‚ΠΈΠΏΠ° ZSM‑5 Π½Π° Π΅Π³ΠΎ структурныС, кислотныС ΠΈ каталитичСскиС свойства Π² процСссС прСвращСния ΠΏΡ€ΠΎΠΏΠ°Π½Π° Π² ΠΎΠ»Π΅Ρ„ΠΈΠ½ΠΎΠ²Ρ‹Π΅ ΡƒΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡ€ΠΎΠ΄Ρ‹. На основС ΠΏΠΎΠ»ΡƒΡ‡Π΅Π½Π½Ρ‹Ρ… Π΄Π°Π½Π½Ρ‹Ρ… установлСно, Ρ‡Ρ‚ΠΎ кислотная ΠΎΠ±Ρ€Π°Π±ΠΎΡ‚ΠΊΠ° Ρ†Π΅ΠΎΠ»ΠΈΡ‚Π° ΠΏΡ€ΠΈΠ²ΠΎΠ΄ΠΈΡ‚ ΠΊ ΠΏΠΎΠ²Ρ‹ΡˆΠ΅Π½ΠΈΡŽ Π΅Π³ΠΎ Π΄Π΅Π³ΠΈΠ΄Ρ€ΠΈΡ€ΡƒΡŽΡ‰Π΅ΠΉ активности ΠΈ позволяСт ΡΠ½ΠΈΠ·ΠΈΡ‚ΡŒ Ρ‚Π΅ΠΌΠΏΠ΅Ρ€Π°Ρ‚ΡƒΡ€Ρƒ провСдСния процСсса. Показано, Ρ‡Ρ‚ΠΎ ΠΏΡ€ΠΎΠ²Π΅Π΄Π΅Π½ΠΈΠ΅ ΠΏΡ€Π΅Π΄Π²Π°Ρ€ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎΠΉ Ρ‚Π΅Ρ€ΠΌΠΎΠΏΠ°Ρ€ΠΎΠ²ΠΎΠΉ ΠΎΠ±Ρ€Π°Π±ΠΎΡ‚ΠΊΠΈ Ρ†Π΅ΠΎΠ»ΠΈΡ‚Π½ΠΎΠ³ΠΎ ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€Π° ΠΎΠΊΠ°Π·Ρ‹Π²Π°Π΅Ρ‚ влияниС Π½Π° Π΅Π³ΠΎ структурныС характСристики ΠΈ распрСдСлСниС кислотных Ρ†Π΅Π½Ρ‚Ρ€ΠΎΠ², приводя ΠΊ ΡƒΠΌΠ΅Π½ΡŒΡˆΠ΅Π½ΠΈΡŽ силы ΠΈ ΠΊΠΎΠ½Ρ†Π΅Π½Ρ‚Ρ€Π°Ρ†ΠΈΠΈ ΡΠΈΠ»ΡŒΠ½Ρ‹Ρ… кислотных Ρ†Π΅Π½Ρ‚Ρ€ΠΎΠ², Ρ‡Ρ‚ΠΎ способствуСт ΡƒΠ²Π΅Π»ΠΈΡ‡Π΅Π½ΠΈΡŽ сСлСктивности образования ΠΎΠ»Π΅Ρ„ΠΈΠ½ΠΎΠ²Ρ‹Ρ… ΡƒΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡ€ΠΎΠ΄ΠΎΠ² ΠΈΠ· ΠΏΡ€ΠΎΠΏΠ°Π½Π°A study was carried out of the influence of acid and thermosteam treatments of ZSM‑5 type zeolite on its structural, acid and catalytic properties in the process of converting propane into olefin hydrocarbons. Based on the data obtained, it was established that acid treatment of zeolite leads to an increase in its dehydrogenation activity and allows the temperature of the process to be reduced. It has been shown that preliminary thermosteam treatment of a zeolite catalyst affects its structural characteristics and the distribution of acid sites, leading to a decrease in the strength and concentration of strong acid sites, which helps to increase the selectivity of the formation of olefin hydrocarbons from propan

    FEEDBACK DESIGN OF DIFFERENTIAL EQUATIONS OF RECONSTRUCTION FOR SECOND-ORDER DISTRIBUTED PARAMETER SYSTEMS

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    The paper aims at studying a class of second-order partial differential equations subject to uncertainty involving unknown inputs for which no probabilistic information is available. Developing an approach of feedback control with a model, we derive an efficient reconstruction procedure and thereby design differential equations of reconstruction. A characteristic feature of the obtained equations is that their inputs formed by the feedback control principle constructively approximate unknown inputs of the given second-order distributed parameter system
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