Diffuse radio sources in the cluster of galaxies Abell 548b

We report extensive VLA and ATCA observations of the two diffuse radio sources in the cluster of galaxies Abell 548b, which confirm their classification as relics. The two relics (named A and B) show similar flux density, extent, shape, polarization and spectral index and are located at projected distances of about 430 and 500 kpc from the cluster center, on the same side of the cluster's X-ray peak. On the basis of spectral indices of discrete radio sources embedded within the diffuse features, we have attempted to distinguish emission peaks of the diffuse sources from unrelated sources. We have found that both relics, in particular the B-relic, show possible fine structure, when observed at high resolution. Another diffuse source (named C) is detected close in projection to the cluster center. High-resolution images show that it contains two discrete radio sources and a diffuse component, which might be a candidate for a small relic source. The nature and properties of the diffuse radio sources are discussed. We conclude that they are likely related to the merger activity in the cluster.Comment: Accepted for publication in MNRAS. 11 pages, 7 figures. Some figures are degraded to reduce their size. A version with high resolution images is available at http://www.ira.inaf.it/~lferetti/OUTGOING/papA548b.ps.g

Deriving a practical analytical-probabilistic method to size flood routing reservoirs

In the engineering practice routing reservoir sizing is commonly performed by using the design storm method, although its effectiveness has been debated for a long time. Conversely, continuous simulations and direct statistical analyses of recorded hydrographs are considered more reliable and comprehensive, but are indeed complex or seldom practicable. In this paper a handier tool is provided by the analytical-probabilistic approach to construct probability functions of peak discharges issuing from natural watersheds or routed through on-line and off-line reservoirs. A simplified routing scheme and a rainfall-runoff model based on a few essential hydrological parameters were implemented. To validate the proposed design methodology, on-line and off-line routing reservoirs were firstly sized by means of a conventional design storm method for a test watershed located in northern Italy. Their routing efficiencies were then estimated by both analytical-probabilistic models and benchmarking continuous simulations. Bearing in mind practical design purposes, adopted models evidenced a satisfactory consistency

Potential climate change effects on the meteorological forcing and the design efficiency of urban drainage systems

Urban drainage systems design and management are strictly connected to meteorological forcing. For design purposes synthetic forms (e.g. depth duration frequency curves) are usually adopted to represent the meteorological solicitation, while a stochastic representation could be more promptly used to investigate the effects of potential climate change both on the design and on the efficiency of urban drainage devices. A simplified semi-probabilistic approach, relying on simple models of the stochastic rainfall process and of the rainfall-runoff (hydrological) transformation, is expected to be a sound tool. Since the rainfall process is described through the definition of three random variables and their probability distribution, the main advantage is the possibility of changing one, two or more characteristics of the rainfall model at a time. The effect of the change can then be easily evaluated through the application of the hydrological model. The semi-probabilistic approach is applied to study some aspects of the drainage system design for locations in the Italian territory. Potential effects of climate change on fictitious urban basins are evaluated through a rainfall stochastic model calibrated on the basis of long series observations recorded at site. Precipitation climate change scenarios were defined on the basis of both international climate studies report and local meteorological observation analysis. The effects on the urban drainage system are evaluated with respect to specific urban drainage devices and the efficiency of the design procedure in the hypothesis of climate change is finally discussed

Soil erosion evaluation in a small watershed in Brazil through 137 Cs fallout redistribution analysis and conventional models

An investigation of rates and patterns of soil erosion on agricultural land cultivated with sugarcane was undert a ken using the 137Cs technique, USLE (Universal Soil Loss Equation) and WEPP (Water Erosion Prediction Project) model. The study was carried out on a representative catchment of a small watershed of the Piracicaba river basin, State of São Paulo, Brazil, called Ceveiro watershed, well known for its severe soil degradation caused by erosion. The results from the 137Cs technique indicate that most part of the studied area (94%) are eroded at erosion rates that go up to 59 Mg ha-1 y-1, with a weighted average rate of 23 Mg ha-1 y-1 . The weighted average rate of infield deposition and sediment retrieval that occurs in only 6% of the total area was estimated to be around 12 Mg ha-1 y-1 . These values led to very high net soil loss from the field, with rates of the order of 21 Mg ha-1 y-1 , which represents a sediment delive ry ratio of 97%. A linear correlation between soil erosion rate estimated by the 137Cs technique and the amount of available K in the top soil layer (0-20 cm) was observed. Based on this correlation the estimated amounts of net and gross K loss in the grid area due to soil erosion were of 0.2 and 1.52 kg ha-1 y-1, respectively. The erosion rate estimated by USLE was 39 Mg ha-1 y-1 and by WEPP model 16.5 Mg ha-1 y-1 with a sediment delivery of 12.4 Mg ha-1 y-1 (75%). The results are a confirmation that the soil conservation practices adopted in the area are very poor and can explain the high siltation level of water reservoirs in the watershed

Fundamentos econômicos da formação do preço internacional de açucar e dos preços domésticos de açucar e etanol.

O objetivo deste estudo foi investigar os fatores que afetam o comportamento do etanol no mercado interno e os preços do açúcar nos mercados doméstico e internacional. Três ordens de fatores explicativos são considerados para o preço internacional: (a) índice geral de preços das commodities CRB Spot, (b) macro-fatores (taxa de câmbio, juros, liquidez) (c) fatores idiossincráticos relacionados ao mercado mundial de açúcar. Os fatores explicativos para os preços brasileiros de açúcar e etanol são: (a) preço internacional do açúcar, (b) macro fatores nacionais e internacionais (c) fatores idiossincráticos (clima, produtividade). O preço internacional é previsto principalmente pelo índice CRB e preços do petróleo. Relacionado ao mercado interno, o preço do açúcar foi previsto pelos preços internacionais e taxa de câmbio do real. Os erros de previsão permaneceram na faixa de 20%. No caso dos preços de etanol, os preços internacionais e domésticos do açúcar foram os principais preditores, embora os erros tenham atingido 40%. Como o etanol é commodity menos negociadas no exterior, seus preços são mais sensíveis a fatores idiossincráticos. No entanto, permanece a conclusão geral de que o comportamento dos preços do açúcar e etanol no mercado brasileiro é bastante coerente com o mercado global de commodities

Produtividade da agricultura: resultados para o Brasil e estados selecionados.

Este trabalho analisa a produtividade da agricultura nos anos recentes, em especial no período de 2000 a 2012. O artigo estima indicadores de produtividade não apenas para o Brasil, mas também para uma seleção de estados. Estes foram escolhidos pela sua relevância na produção nacional de grãos e carnes. Para isso, foram escolhidos os estados da Bahia, Minas Gerais, São Paulo, Paraná, Rio Grande do Sul, Mato Grosso e Goiás. Utilizou-se o conceito de produtividade total dos fatores (PTF) porque ele oferece uma definição mais abrangente de produtividade do que medidas que comparam o produto a apenas um insumo, como trabalho ou terra. Esta última forma de mensuração da produtividade é chamada produtividade parcial. A PTF considera, em sua definição, a reunião de todos os produtos das lavouras e da pecuária e os relaciona com todos os insumos usados na produção

Soil erosion evaluation in a small watershed in Brazil through 137 Cs fallout redistribution analysis and conventional models

An investigation of rates and patterns of soil erosion on agricultural land cultivated with sugarcane was undert a ken using the 137Cs technique, USLE (Universal Soil Loss Equation) and WEPP (Water Erosion Prediction Project) model. The study was carried out on a representative catchment of a small watershed of the Piracicaba river basin, State of São Paulo, Brazil, called Ceveiro watershed, well known for its severe soil degradation caused by erosion. The results from the 137Cs technique indicate that most part of the studied area (94%) are eroded at erosion rates that go up to 59 Mg ha-1 y-1, with a weighted average rate of 23 Mg ha-1 y-1 . The weighted average rate of infield deposition and sediment retrieval that occurs in only 6% of the total area was estimated to be around 12 Mg ha-1 y-1 . These values led to very high net soil loss from the field, with rates of the order of 21 Mg ha-1 y-1 , which represents a sediment delive ry ratio of 97%. A linear correlation between soil erosion rate estimated by the 137Cs technique and the amount of available K in the top soil layer (0-20 cm) was observed. Based on this correlation the estimated amounts of net and gross K loss in the grid area due to soil erosion were of 0.2 and 1.52 kg ha-1 y-1, respectively. The erosion rate estimated by USLE was 39 Mg ha-1 y-1 and by WEPP model 16.5 Mg ha-1 y-1 with a sediment delivery of 12.4 Mg ha-1 y-1 (75%). The results are a confirmation that the soil conservation practices adopted in the area are very poor and can explain the high siltation level of water reservoirs in the watershed

The chiral 1:2 adduct (S)S(S)C(-)589-ethyl 2-phenylbutyl sulphide-mercury (II) chloride:(-)589[(S)S(S)C-Et(2-PhBu)S.(HgCl2)2]. Stereoselective synthesis, asymmetric oxidation, crystal and molecular structure and circular dichroism spectra

Optically active (-)589ethyl (S)-2-phenylbutyl thioether, (-)(S)C-Et(PhBu)S (I), and its new diastereoisomeric mercury (II) chloride adduct, 1:2, (-)[(S)S(S)C-Et(PhBu)S.(HgCl2)2]2, (II) were stereoselectively synthesized; the absorbance (UV) and circular dichroism (CD) spectra were measured and the crystal and molecular structure of complex (II) was determined by single-crystal X-ray diffraction. Two different Hg centres are present whose coordination environments are built by two short bonds to chloride ligands in one case, and to one chloride and one sulphur in the other one. These originate digonal units. Electroneutrality is achieved by a further chlorine, which can be considered prevalently ionic and bonded to the two Hg centres, forming square bridging systems nearly perpendicular to the digonal molecules. The coordination polyhedra can be interpreted as 2 + 4 tetragonally-compressed octahedra with the four longer contacts lying in the equatorial plane. IR spectroscopic data are consistent with the presence of one bent and one linear Cl–Hg–Cl moiety. The absolute configurations at both stereogenic centres of the formed diastereoisomeric complex (II) are (S). The (S)S absolute configuration at the stereogenic sulphur atom bonded to the mercury(II) atom in complex (II) has been related with the negative Cotton effect assigned in its circular dichroism (CD) spectrum to a charge-transfer transition at ca. 230 nm. The stereoselective oxidation of (I) and (II) with hydrogen peroxide, induced by the stereogenic carbon atom (S)C of the enantiopure sulphide, gave (-)598ethyl (S)C-2-phenylbutyl(S)S-sulphoxide, (-)598[(S)S(S)C-Et(PhBu)SO], (III), having 18.1% de. Oxidations carried out in the presence of a 200 molar excess of mercury(II) chloride gave (-)598ethyl (S)C-2-phenylbutyl(R)S-sulphoxide, (-) 598[(R)S(S)C-Et(PhBu)SO], (IV) with 31% de, showing the cooperative influence of mercury(II) chloride on the selectivity of the oxidation reaction

Mathematical modelling of polyamine metabolism in bloodstream-form trypanosoma brucei: An application to drug target identification

© 2013 Gu et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are creditedThis article has been made available through the Brunel Open Access Publishing Fund.We present the first computational kinetic model of polyamine metabolism in bloodstream-form Trypanosoma brucei, the causative agent of human African trypanosomiasis. We systematically extracted the polyamine pathway from the complete metabolic network while still maintaining the predictive capability of the pathway. The kinetic model is constructed on the basis of information gleaned from the experimental biology literature and defined as a set of ordinary differential equations. We applied Michaelis-Menten kinetics featuring regulatory factors to describe enzymatic activities that are well defined. Uncharacterised enzyme kinetics were approximated and justified with available physiological properties of the system. Optimisation-based dynamic simulations were performed to train the model with experimental data and inconsistent predictions prompted an iterative procedure of model refinement. Good agreement between simulation results and measured data reported in various experimental conditions shows that the model has good applicability in spite of there being gaps in the required data. With this kinetic model, the relative importance of the individual pathway enzymes was assessed. We observed that, at low-to-moderate levels of inhibition, enzymes catalysing reactions of de novo AdoMet (MAT) and ornithine production (OrnPt) have more efficient inhibitory effect on total trypanothione content in comparison to other enzymes in the pathway. In our model, prozyme and TSHSyn (the production catalyst of total trypanothione) were also found to exhibit potent control on total trypanothione content but only when they were strongly inhibited. Different chemotherapeutic strategies against T. brucei were investigated using this model and interruption of polyamine synthesis via joint inhibition of MAT or OrnPt together with other polyamine enzymes was identified as an optimal therapeutic strategy.The work was carried out under a PhD programme partly funded by Prof. Ray Welland, School of Computing Science, University of Glasgo