6,232 research outputs found
Theory of asymmetric non-additive binary hard-sphere mixtures
We show that the formal procedure of integrating out the degrees of freedom
of the small spheres in a binary hard-sphere mixture works equally well for
non-additive as it does for additive mixtures. For highly asymmetric mixtures
(small size ratios) the resulting effective Hamiltonian of the one-component
fluid of big spheres, which consists of an infinite number of many-body
interactions, should be accurately approximated by truncating after the term
describing the effective pair interaction. Using a density functional treatment
developed originally for additive hard-sphere mixtures we determine the zero,
one, and two-body contribution to the effective Hamiltonian. We demonstrate
that even small degrees of positive or negative non-additivity have significant
effect on the shape of the depletion potential. The second virial coefficient
, corresponding to the effective pair interaction between two big spheres,
is found to be a sensitive measure of the effects of non-additivity. The
variation of with the density of the small spheres shows significantly
different behavior for additive, slightly positive and slightly negative
non-additive mixtures. We discuss the possible repercussions of these results
for the phase behavior of binary hard-sphere mixtures and suggest that
measurements of might provide a means of determining the degree of
non-additivity in real colloidal mixtures
On the Detectability of the Hydrogen 3-cm Fine Structure Line from the EoR
A soft ultraviolet radiation field, 10.2 eV < E <13.6 eV, that permeates
neutral intergalactic gas during the Epoch of Reionization (EoR) excites the 2p
(directly) and 2s (indirectly) states of atomic hydrogen. Because the 2s state
is metastable, the lifetime of atoms in this level is relatively long, which
may cause the 2s state to be overpopulated relative to the 2p state. It has
recently been proposed that for this reason, neutral intergalactic atomic
hydrogen gas may be detected in absorption in its 3-cm fine-structure line
(2s_1/2 -> 2p_3/2) against the Cosmic Microwave Background out to very high
redshifts. In particular, the optical depth in the fine-structure line through
neutral intergalactic gas surrounding bright quasars during the EoR may reach
tau~1e-5. The resulting surface brightness temperature of tens of micro K (in
absorption) may be detectable with existing radio telescopes. Motivated by this
exciting proposal, we perform a detailed analysis of the transfer of Lyman
beta,gamma,delta,... radiation, and re-analyze the detectability of the
fine-structure line in neutral intergalactic gas surrounding high-redshift
quasars. We find that proper radiative transfer modeling causes the
fine-structure absorption signature to be reduced tremendously to tau< 1e-10.
We therefore conclude that neutral intergalactic gas during the EoR cannot
reveal its presence in the 3-cm fine-structure line to existing radio
telescopes.Comment: 7 pages, 4 figures, MNRAS in press; v2. some typos fixe
Fluids of platelike particles near a hard wall
Fluids consisting of hard platelike particles near a hard wall are
investigated using density functional theory. The density and orientational
profiles as well as the surface tension and the excess coverage are determined
and compared with those of a fluid of rodlike particles. Even for low densities
slight orientational packing effects are found for the platelet fluid due to
larger intermolecular interactions between platelets as compared with those
between rods. A net depletion of platelets near the wall is exhibited by the
excess coverage, whereas a change of sign of the excess coverage of hard-rod
fluids is found upon increasing the bulk density.Comment: 6 pages, 9 figure
The 10 ÎŒm Feature of M-Type Stars in the Large Magellanic Cloud and the Dust Condensation Sequence
doi: 10.1086/498415We present 7-14 mm Infrared Space Observatory (ISO) spectroscopy of 12 M-type evolved stars in the Large Magellanic Cloud (LMC), in order to study the dust mineralogy and condensation process around these stars. The sample stars show a broad dust feature in the 7-14 mm region, which is seen in either emission or (self-) absorption. The shape of the feature changes with increasing mass-loss rate, M, suggesting a change in dust ËM mineralogy as the central star evolves. At low mass-loss rates amorphous alumina and amorphous silicates are observed, while at high mass- loss rates only amorphous silicates are seen, in agreement with the classical condensation sequence expected for these materials.We find a clear correlation between and the peak wavelength ËM position of the broad dust feature. Our data suggest a strong dependence of the dust mineralogy on the temperature at the dust condensation radius.This work was supported by the NASA Astrophysical Data Program (NAG 5-12675) and the University of Missouri Research Board
Sedimentation of binary mixtures of like- and oppositely charged colloids: the primitive model or effective pair potentials?
We study sedimentation equilibrium of low-salt suspensions of binary mixtures
of charged colloids, both by Monte Carlo simulations of an effective
colloids-only system and by Poisson-Boltzmann theory of a colloid-ion mixture.
We show that the theoretically predicted lifting and layering effect, which
involves the entropy of the screening ions and a spontaneous macroscopic
electric field [J. Zwanikken and R. van Roij, Europhys. Lett. {\bf 71}, 480
(2005)], can also be understood on the basis of an effective colloid-only
system with pairwise screened-Coulomb interactions. We consider, by theory and
by simulation, both repelling like-charged colloids and attracting oppositely
charged colloids, and we find a re-entrant lifting and layering phenomenon when
the charge ratio of the colloids varies from large positive through zero to
large negative values
Depletion potential in hard-sphere mixtures: theory and applications
We present a versatile density functional approach (DFT) for calculating the
depletion potential in general fluid mixtures. In contrast to brute force DFT,
our approach requires only the equilibrium density profile of the small
particles {\em before} the big (test) particle is inserted. For a big particle
near a planar wall or a cylinder or another fixed big particle the relevant
density profiles are functions of a single variable, which avoids the numerical
complications inherent in brute force DFT. We implement our approach for
additive hard-sphere mixtures. By investigating the depletion potential for
high size asymmetries we assess the regime of validity of the well-known
Derjaguin approximation for hard-sphere mixtures and argue that this fails. We
provide an accurate parametrization of the depletion potential in hard-sphere
fluids which should be useful for effective Hamiltonian studies of phase
behavior and colloid structure
Structure of laponite-styrene precursor dispersions for production of advanced polymer-clay nanocomposites
One method for production of polymer-clay nanocomposites involves dispersal of surface-modified clay in a polymerisable monomeric solvent, followed by fast in situ polymerisation. In order to tailor the properties of the final material we aim to control the dispersion state of the clay in the precursor solvent. Here, we study dispersions of surface-modified Laponite, a synthetic clay, in styrene via large-scale Monte-Carlo simulations and experimentally, using small angle X-ray and static light scattering. By tuning the effective interaction between simulated laponite particles we are able to reproduce the experimental scattering intensity patterns for this system, with good accuracy over a wide range of length scales. However, this agreement could only be obtained by introducing a permanent electrostatic dipole moment into the plane of each Laponite particle, which we explain in terms of the distribution of substituted metal atoms within each Laponite particle. This suggests that Laponite dispersions, and perhaps other clay suspensions, should display some of the structural characteristics of dipolar fluids. Our simulated structures show aggregation regimes ranging from networks of long chains to dense clusters of Laponite particles, and we also obtain some intriguing âglobularâ clusters, similar to capsids. We see no indication of any âhouse-of-cardsâ structures. The simulation that most closely matches experimental results indicates that gel-like networks are obtained in Laponite dispersions, which however appear optically clear and non-sedimenting over extended periods of time. This suggests it could be difficult to obtain truly isotropic equilibrium dispersion as a starting point for synthesis of advanced polymer-clay nanocomposites with controlled structures
Clustering of Ly-alpha emitters around luminous quasars at z = 2-3: an alternative probe of reionization on galaxy formation
Narrowband observations have detected no Ly-alpha emission within a 70 pMpc^3
volume centered on the z = 2.168 quasar PKS 0424-131. This is in contrast to
surveys of Ly-alpha emitters in the field at similar redshifts and flux limits,
which indicate that tens of sources should be visible within the same volume.
The observed difference indicates that the quasar environment has a significant
influence on the observed density of Ly-alpha emitters. To quantify this effect
we have constructed a semi-analytic model to simulate the effect of a luminous
quasar on nearby Ly-alpha emitters. We find the null detection around PKS
0424-131 implies that the minimum isothermal temperature of Ly-alpha emitter
host halos is greater than 3.4 x 10^6 K (68% level), corresponding to a virial
mass of ~1.2 x 10^12 M_solar. This indicates that the intense UV emission of
the quasar may be suppressing the star formation in nearby galaxies. Our study
illustrates that low redshift quasar environments may serve as a surrogate for
studying the radiative suppression of galaxy formation during the epoch of
reionization.Comment: 9 pages, 5 figures, submitted to MNRA
Biodegradable versus titanium osteosynthesis in maxillofacial traumatology:A systematic review with meta-analysis and trial sequential analysis
Titanium osteosynthesis is currently the fixation system of choice in maxillofacial traumatology. Biodegradable osteosynthesis systems have the ability to degrade in the human body. The aim of this study was to conduct a systematic review, with meta- and trial sequential analyses, to assess the efficacy and morbidity of biodegradable versus titanium osteosynthesis after maxillofacial trauma. MEDLINE, Embase, and CENTRAL were searched for randomized controlled trials and prospective and retrospective controlled studies. Five time periods were studied: perioperative, short-term (0-4 weeks), intermediate (6-12 weeks), long-term (>12 weeks), and overall follow-up. After screening 3542 records, 24 were included. All had a high risk of performance and detection bias due to the nature of the interventions. Meta-analysis showed no differences in efficacy or morbidity between biodegradable and titanium osteosynthesis. The risk of perioperative screw breakage was significantly higher (risk ratio 17.13, 95% confidence interval 2.19-34.18) and the symptomatic plate removal rate lower in the biodegradable group (risk ratio 0.11, 95% confidence interval 0.02-0.57), which was confirmed by the trial sequential analysis. The quality of evidence ranged from very low to moderate. Based on the narrative review and meta-analyses, current evidence shows that biodegradable osteosynthesis is a viable alternative to titanium osteosynthesis when applied in the treatment of maxillofacial trauma, with similar efficacy but significantly lower symptomatic plate removal rates. Perioperative screw breakage occurred significantly more often in the biodegradable group compared to the titanium group
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