Wood Flour Modified by Poly(furfuryl alcohol) as a Filler in Rigid Polyurethane Foams: Effect on Water Uptake

The use of lignocellulosic fillers in rigid polyurethane foams (RPUFs) has been receiving great attention due to their good mechanical and insulation properties and the high sustainable appeal of the obtained cellular polymers, although high water uptakes are found in most of these systems. To mitigate this detrimental effect, RPUFs filled with wood flour (2.5% wt) were fabricated with the addition of furfuryl alcohol (FA) to create a polymer grafted with the wood filler. Two concentrations of FA (10 wt% and 15 wt%) were investigated in relation to the wood flour, and the RPUFs were characterized for cell morphology, density, compressive properties, thermal stability, and water uptake. The introduction of wood flour as a filler decreased the cell size and increased the anisotropy index of the RPUFs and, in addition to that, the FA grafting increased these effects even more. In general, there were no significant changes in both mechanical and thermal properties ascribed to the incorporation of the fillers. On the other hand, a reduction of up to 200% in water uptake was ascribed to the FA-treated fillers.This work was supported by the Coordination for the Improvement of Higher Education—CAPES (code 001), the National Council for Scientific and Technological Development—CNPq (Financial code 301758/2019-0) and the University of Basque Country (COLAB20/04)

Wood under fresh water: Effect on the chemical properties and on decay resistance

This study aimed to evaluate the effect of waterlogging on the chemical properties and on decay resistance of two fast-growing eucalypt species. Samples of spotted gum and rose gum wood were placed underwater and taken out at different times: after 4, 8 and 12 months. Chemical properties were performed via wet chemical quantification (Tappi standards), monomeric sugars by HPLC, and qualitative evaluation of extractives by Py-GC/MS and ATR-IR spectroscopy; biological performance was investigated using Trametes versicolor and Gloeophyllum trabeum rot fungi. The results showed slight changes to the chemical properties of both wood species, with an increase in lignin represented by the reduction of sugars due to waterlogging. Both species showed higher susceptibility to Gloeophyllum trabeum mainly in the sapwood, with no influence on decay resistance due the waterlogging

Massive spinal-ischial dysplasia and extensive spinal dyssygmentation in a Tunisian child with severe form of Cleido- cranial dysplasia

Abstract Kyphoscoliosis is a complication of some bone dysplasias, including Cleido-cranial dysplasia (CCD). We report on massive spinal dysplasia secondary to severe spinal dyssygmentation associated with marked defective ossification of the ischium, detected in a Tunisian female child with a severe form of Cleido-cranial dysplasia. Literature review on Cleido cranial dysplasia and associated spinal abnormalities showed no previous similar reports as encountered in our patient

Tolllike receptor 4 (TLR4) polymorphisms in Tunisian patients with Crohn's disease: genotype-phenotype correlation

<p>Abstract</p> <p>Background</p> <p>The immune responses to bacterial products through the pattern recognition receptor (PRR) play a pivotal role in pathogenesis of Crohn's disease. A recent study described an association between CD and some gene coding for bacterial receptor like NOD2/CARD15 gene and TLR4. In this study, we sought to determine whether TLR4 gene was associated with Crohn's disease (CD) among the Tunisian population and its correlation with clinical manifestation of the disease.</p> <p>Methods</p> <p>90 patients with CD and 80 healthy individuals are genotyped for the <it>Asp299Gly </it>and <it>Thr399Ile </it>polymorphisms by restriction fragment length polymorphism analysis.</p> <p>Results</p> <p>The allele and genotype frequency of the TLR4 polymorphisms did not differ between patients and controls. The genotype-phenotype correlation permitted to show that the <it>Thr399Ile </it>polymorphism was associated with early onset disease.</p> <p>Conclusion</p> <p>this study reported the absence of association between CD and TLR4 gene in the Tunisian population, but this gene could play a role in clinical expression of the disease.</p

Structural, optical and dielectric properties of Cu1.5Mn1.5O4 spinel nanoparticles

In this study, a Cu1.5Mn1.5O4 spinel was successfully synthesized by a sol-gel method at 500 °C for 5 h and characterized by different techniques. X-ray diffraction (XRD), Fourier transformation infrared (FTIR) spectroscopy and Raman spectroscopic analyses confirmed the formation of a spinel cubic structure with the Fd3̄m space group. The SEM proves that the grain size of our compound is of the order of 48 nm. Crystallite sizes determined from three estimates are closer to the grain size obtained from the SEM, indicating the single domain nature of the sample. The optical properties of UV-visible spectroscopy for our sample showed that the gap value is equal to 3.82 eV, making our compound a good candidate for optoelectronic applications. For electrical properties, impedance spectroscopy was performed at a frequency range of 40 ≤ frequency ≤ 106 Hz. This suggested hoping conduction due to three theoretical models. The latter can be attributed to the correlated barrier hopping (CBH) model in region I, overlapping large polaron tunneling (OLPT) in region II and non-overlapping small polaron tunneling (NSPT) mechanism in region III. One dielectric relaxation is detected from the dielectric impedance and modulus, attributed to grain contributions. This behavior was confirmed by both Nyquist and Argand's plots of dielectric impedance at different measuring temperatures

Wood under fresh water: Effect on the chemical properties and on decay resistance

This study aimed to evaluate the effect of waterlogging on the chemical properties and on decay resistance of two fast-growing eucalypt species. Samples of spotted gum and rose gum wood were placed underwater and taken out at different times: after 4, 8 and 12 months. Chemical properties were performed via wet chemical quantification (Tappi standards), monomeric sugars by HPLC, and qualitative evaluation of extractives by Py-GC/MS and ATR-IR spectroscopy; biological performance was investigated using Trametes versicolor and Gloeophyllum trabeum rot fungi. The results showed slight changes to the chemical properties of both wood species, with an increase in lignin represented by the reduction of sugars due to waterlogging. Both species showed higher susceptibility to Gloeophyllum trabeum mainly in the sapwood, with no influence on decay resistance due the waterlogging

Wood under fresh water: Effect on the chemical properties and on decay resistance

This study aimed to evaluate the effect of waterlogging on the chemical properties and on decay resistance of two fast-growing eucalypt species. Samples of spotted gum and rose gum wood were placed underwater and taken out at different times: after 4, 8 and 12 months. Chemical properties were performed via wet chemical quantification (Tappi standards), monomeric sugars by HPLC, and qualitative evaluation of extractives by Py-GC/MS and ATR-IR spectroscopy; biological performance was investigated using Trametes versicolor and Gloeophyllum trabeum rot fungi. The results showed slight changes to the chemical properties of both wood species, with an increase in lignin represented by the reduction of sugars due to waterlogging. Both species showed higher susceptibility to Gloeophyllum trabeum mainly in the sapwood, with no influence on decay resistance due the waterlogging