819 research outputs found
Factors that affect scrub practitioner non-technical skills: A literature review
Non-technical skills are the cognitive and interpersonal behaviours that compliment clinical competence in surgery. Effective use of non-technical skills is essential for scrub practice, because they facilitate anticipation of the surgeon’s requirements and promote appropriate communication behaviours. This literature review analyses the factors that may influence a scrub practitioner’s use of non-technical skills during surgery. Recommendations are made that are intended to improve their use by reducing behavioural variations during surgery
Electronic Structure of the Complex Hydride NaAlH4
Density functional calculations of the electronic structure of the complex
hydride NaAlH4 and the reference systems NaH and AlH3 are reported. We find a
substantially ionic electronic structure for NaAlH4, which emphasizes the
importance of solid state effects in this material. The relaxed hydrogen
positions in NaAlH4 are in good agreement with recent experiment. The
electronic structure of AlH3 is also ionic. Implications for the binding of
complex hydrides are discussed.Comment: 4 pages, 5 figure
Carbide Type Influence on Tribological Properties of Hard Faced Steel Layer Part II- Experimental Results
In this paper is presented a preceding procedure that should be conducted in order to successfully regenerate damaged forging dies by the hard facing process. After the tool damage types identification, as well as their causes, we have chosen the procedure and the parameters of hard facing that we further corrected by conducting the test hard facings on models. Thus, we were able to relate the experimental results outputs with the repair technology, taking as a criterion the quality of the surface layers wear resistance such as friction coefficient and width of hard faced zone, hardness and its distribution in cross section, then microstructure of characteristic of hard faced zones, etc. This research points out significancy of tribological properties of certain types of carbides and their effects on metal matrix, in which carbides are embedded. Our tribological investigations have shown that the working life of the hard faced tool can be longer than that of the new tool
Multi-phonon scattering and Ti-induced hydrogen dynamics in sodium alanate
We use ab initio methods and neutron inelastic scattering (NIS) to study the
structure, energetics, and dynamics of pure and Ti-doped sodium alanate
(NaAlH_4), focusing on the possibility of substitutional Ti doping. The NIS
spectrum is found to exhibit surprisingly strong and sharp two-phonon features.
The calculations reveal that substitutional Ti doping is energetically
possible. Ti prefers to substitute for Na and is a powerful hydrogen attractor
that facilitates multiple Al--H bond breaking. Our results hint at new ways of
improving the hydrogen dynamics and storage capacity of the alanates.Comment: 5 pages, with 4 postscript figures embedded. Uses REVTEX4 and
graphicx macro
Carbide Type Influence on Tribological Properties of Hard Faced Steel Layer - Part I - Theoretical Considerations
This paper gives a theoretical review of influence of the most important alloying elements on steel, and review of the most important carbide-forming elements and states the conditions which elements should fulfill in order to be considered as carbide-forming. It primarily involves alloying elements which in the iron-carbon system can form simple, complex or special carbides, i.e. phases of interstitial and substitutive type. It also gives a review of carbide types that are formed during either production or reparatory hard facing of steel parts with different types of filler materials
Structure and Thermodynamics of the Mixed Alkali Alanates
The thermodynamics and structural properties of the hexahydride alanates
(M2M'AlH6) with the elpasolite structure have been investigated. A series of
mixed alkali alanates (Na2LiAlH6, K2LiAlH6 and K2NaAlH6) were synthesized and
found to reversibly absorb and desorb hydrogen without the need for a catalyst.
Pressure-composition isotherms were measured to investigate the thermodynamics
of the absorption and desorption reactions with hydrogen. Isotherms for
catalyzed (4 mol% TiCl3) and uncatalyzed Na2LiAlH6 exhibited an increase in
kinetics, but no change in the bulk thermodynamics with the addition of a
dopant. A structural analysis using synchrotron x-ray diffraction showed that
these compounds favor the Fm-3m space group with the smaller ion (M') occupying
an octahedral site. These results demonstrate that appropriate cation
substitutions can be used to stabilize or destabilize the material and may
provide an avenue to improving the unfavorable thermodynamics of a number of
materials with promising gravimetric hydrogen densities.Comment: 6 pages, 7 figures,3 tables, submitted to PR
Electronic structure and optical properties of lightweight metal hydrides
We study the electronic structures and dielectric functions of the simple
hydrides LiH, NaH, MgH2 and AlH3, and the complex hydrides Li3AlH6, Na3AlH6,
LiAlH4, NaAlH4 and Mg(AlH4)2, using first principles density functional theory
and GW calculations. All these compounds are large gap insulators with GW
single particle band gaps varying from 3.5 eV in AlH3 to 6.5 eV in the MAlH4
compounds. The valence bands are dominated by the hydrogen atoms, whereas the
conduction bands have mixed contributions from the hydrogens and the metal
cations. The electronic structure of the aluminium compounds is determined
mainly by aluminium hydride complexes and their mutual interactions. Despite
considerable differences between the band structures and the band gaps of the
various compounds, their optical responses are qualitatively similar. In most
of the spectra the optical absorption rises sharply above 6 eV and has a strong
peak around 8 eV. The quantitative differences in the optical spectra are
interpreted in terms of the structure and the electronic structure of the
compounds.Comment: 13 pages, 10 figure
Massive Black Hole Binary Inspirals: Results from the LISA Parameter Estimation Taskforce
The LISA Parameter Estimation (LISAPE) Taskforce was formed in September 2007
to provide the LISA Project with vetted codes, source distribution models, and
results related to parameter estimation. The Taskforce's goal is to be able to
quickly calculate the impact of any mission design changes on LISA's science
capabilities, based on reasonable estimates of the distribution of
astrophysical sources in the universe. This paper describes our Taskforce's
work on massive black-hole binaries (MBHBs). Given present uncertainties in the
formation history of MBHBs, we adopt four different population models, based on
(i) whether the initial black-hole seeds are small or large, and (ii) whether
accretion is efficient or inefficient at spinning up the holes. We compare four
largely independent codes for calculating LISA's parameter-estimation
capabilities. All codes are based on the Fisher-matrix approximation, but in
the past they used somewhat different signal models, source parametrizations
and noise curves. We show that once these differences are removed, the four
codes give results in extremely close agreement with each other. Using a code
that includes both spin precession and higher harmonics in the
gravitational-wave signal, we carry out Monte Carlo simulations and determine
the number of events that can be detected and accurately localized in our four
population models.Comment: 14 pages, 2 figures, 5 tables, minor changes to match version to be
published in the proceedings of the 7th LISA Symposium. For more information
see the Taskforce's wiki at http://www.tapir.caltech.edu/dokuwiki/lisape:hom
The Current Status of Binary Black Hole Simulations in Numerical Relativity
Since the breakthroughs in 2005 which have led to long term stable solutions
of the binary black hole problem in numerical relativity, much progress has
been made. I present here a short summary of the state of the field, including
the capabilities of numerical relativity codes, recent physical results
obtained from simulations, and improvements to the methods used to evolve and
analyse binary black hole spacetimes.Comment: 14 pages; minor changes and corrections in response to referee
Discovery of the Onset of Rapid Accretion by a Dormant Massive Black Hole
Massive black holes are believed to reside at the centres of most galaxies.
They can be- come detectable by accretion of matter, either continuously from a
large gas reservoir or impulsively from the tidal disruption of a passing star,
and conversion of the gravitational energy of the infalling matter to light.
Continuous accretion drives Active Galactic Nuclei (AGN), which are known to be
variable but have never been observed to turn on or off. Tidal disruption of
stars by dormant massive black holes has been inferred indirectly but the on-
set of a tidal disruption event has never been observed. Here we report the
first discovery of the onset of a relativistic accretion-powered jet in the new
extragalactic transient, Swift J164449.3+573451. The behaviour of this new
source differs from both theoretical models of tidal disruption events and
observations of the jet-dominated AGN known as blazars. These differences may
stem from transient effects associated with the onset of a powerful jet. Such
an event in the massive black hole at the centre of our Milky Way galaxy could
strongly ionize the upper atmosphere of the Earth, if beamed towards us.Comment: Submitted to Nature. 4 pages, 3 figures (main paper). 26 pages, 13
figures (supplementary information
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