246 research outputs found
Transverse Entanglement Migration in Hilbert Space
We show that, although the amount of mutual entanglement of photons
propagating in free space is fixed, the type of correlations between the
photons that determine the entanglement can dramatically change during
propagation. We show that this amounts to a migration of entanglement in
Hilbert space, rather than real space. For the case of spontaneous parametric
down conversion, the migration of entanglement in transverse coordinates takes
place from modulus to phase of the bi-photon state and back again. We propose
an experiment to observe this migration in Hilbert space and to determine the
full entanglement.Comment: 4 pages, 3 figure
Photophysics of 3-hydroxyflavone in supercritical CO2: a probe to study the microenvironment of SCF
The excitation of 3-hydroxyflavone (3HF) to its second excited singlet state (S2) gives rise to dual fluorescence in supercritical carbon dioxide. The ultraviolet fluorescence originated from the S2 state of 3HF is well separated from the green emission emanating from the tautomeric form, produced via the excited state intramolecular proton transfer. The relative intensity of the S2 to the tautomer fluorescence (S2/T) has been studied as a function of pressure and temperature. It is shown that this ratio reflects the microheterogeneity of the supercritical CO2, and confirms the value of fluorometric probes in disclosing the microscopic properties of supercritical fluids.http://www.sciencedirect.com/science/article/B6TFN-4BVP7G9-3/1/02dd61c567fe3e9c8d6ac86a01f79ce
New Halogenated Phenylbacteriochlorins and Their Efficiency in Singlet-Oxygen Sensitization
Halogenated phenylbacteriochlorins are synthesized with high yields in a two-step procedure. They have strong absorbances in the red and are very stable to air and light at room temperature. Flash photolysis measurements show that the triplet states of these bacteriochlorins have 30 μs lifetimes in deaerated toluene, that are quenched with diffusion-controlled rate constants by molecular oxygen. Time-resolved photoacoustic measurements, with nanosecond and nanocalorie resolution, show that these bacteriochlorins sensitize the formation of singlet oxygen with nearly unity quantum yield. However, singlet-oxygen phosphorescence measurements indicate that physical quenching occurs before the singlet-oxygen molecules diffuse into solution, and nearly half of the sensitized singlet states are lost
Entangled Bessel beams
Orbital angular momentum (OAM) entanglement is investigated in the
Bessel-Gauss (BG) basis. Having a readily adjustable radial scale, BG modes
provide a more favourable basis for OAM entanglement over Laguerre-Gaussian
(LG) modes. The OAM bandwidth in terms of BG modes can be increased by
selection of particular radial modes and leads to a flattening of the spectrum.
The flattening of the spectrum allows for higher entanglement. We demonstrate
increased entanglement in terms of BG modes by performing a Bell-type
experiment and violating the appropriate Clauser Horne Shimony Holt (CHSH)
inequality. In addition, we reconstruct the quantum state of BG modes entangled
in high-dimensions.Comment: 8 pages, 4 figure
Entanglement of photons
It is argued that the title of this paper represents a misconception.
Contrary to widespread beliefs it is electromagnetic field modes that are
``systems'' and can be entangled, not photons. The amount of entanglement in a
given state is shown to depend on redefinitions of the modes; we calculate the
minimum and maximum over all such redefinitions for several examples.Comment: 5 pages ReVTe
In vitro antimicrobial and antiproliferative activity of amphipterygium adstringens
Amphipterygium adstringens is a plant widely used in Mexican traditional medicine for its known anti-inflammatory and antiulcer properties. In this work, we evaluated the in vitro antimicrobial and antiproliferative activities of the methanolic extract of A. adstringens against oral pathogens such as Streptococcus mutans, Porphyromonas gingivalis, Aggregatibacter actinomycetemcomitans, Candida albicans, and Candida dubliniensis, using microdilution (MIC) and agar diffusion methods (MBC), and the antiproliferative activity evaluating total growth inhibition (TGI) by staining the protein content with sulforhodamine B (SRB), using nine human cancer cell lines. Crude extract (CE) of A. adstringens showed some degree of activity against one or more of the strains with a MIC from 0.125 mg/mL to 63 mg/mL and MBC from 1.6 to 6.3 mg/mL and cytotoxic activity, particularly against NCI-ADR/RES, (a)n ovarian cell line expressing multiple resistance drugs phenotype. The CE is a complex mixture of possible multitarget metabolites that could be responsible for both antimicrobial and antiproliferative activities, and further investigation is required to elucidate the identity of active compounds. Nevertheless the CE itself is useful in the development of new antimicrobial treatment based on natural products to prevent oral diseases and as alternative natural source for cancer treatment and prevention2015PROMEP, Mexic
Photochemistry and photophysics of thienocarbazoles
Two methylated thienocarbazoles and two of their synthetic nitro-precursors have been examined by absorption, luminescence, laser flash photolysis and photoacoustic techniques. Their spectroscopic and photophysical characterization involves fluorescence spectra, fluorescence quantum yields and lifetimes, and phosphorescence spectra and phosphorescence lifetimes for all the compounds. Triplet-singlet difference absorption spectra, triplet molar absorption coefficients, triplet lifetimes, intersystem crossing S-1 similar tosimilar to--> T-1 and singlet molecular oxygen yields were obtained for the thienocarbazoles. In the case of the thienocarbazoles it was found that the lowest-lying singlet and triplet excited states, S, and T-1, are of pi,pi* origin, whereas for their precursors S-1 is n,pi*, and T-1 is pi,pi*. In both thienocarbazoles it appears that the thianaphthene ring dictates the S, T, yield, albeit there is less predominance of that ring in the triplet state of the linear thienocarbazole, which leads to a decrease in the observed Phi(T) value.info:eu-repo/semantics/publishedVersio
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