Abundant Z-cyanomethanimine in the interstellar medium: paving the way to the synthesis of adenine

We report the first detection in the interstellar medium of the Z-isomer of cyanomethanimine (HNCHCN), an HCN dimer proposed as precursor of adenine. We identified six transitions of Z-cyanomethanimine, along with five transitions of E-cyanomethanimine, using IRAM 30m observations towards the Galactic Center quiescent molecular cloud G+0.693. The Z-isomer has a column density of (2.0$\pm$0.6)$\times$10$^{14}$ cm$^{-2}$ and an abundance of 1.5$\times$10$^{-9}$. The relative abundance ratio between the isomers is [Z/E]$\sim$6. This value cannot be explained by the two chemical formation routes previously proposed (gas-phase and grain surface), which predicts abundances ratios between 0.9 and 1.5. The observed [Z/E] ratio is in good agreement with thermodynamic equilibrium at the gas kinetic temperature (130$-$210 K). Since isomerization is not possible in the ISM, the two species may be formed at high temperature. New chemical models, including surface chemistry on dust grains and gas-phase reactions, should be explored to explain our findings. Whatever the formation mechanism, the high abundance of Z-HNCHCN shows that precursors of adenine are efficiently formed in the ISM.Comment: Accepted in Monthly Notices of the Royal Astronomical Society Letter

3 mm spectral line survey of two lines of sight toward two typical cloud complexes in the Galactic Center

We present the results of two Mopra 3-mm spectral line surveys of the Lines of Sight (LOS) toward the Galactic Center (GC) molecular complexes Sgr B2 (LOS+0.693) and Sgr A (LOS-0.11). The spectra covered the frequency ranges of ~77-93 GHz and ~105-113 GHz. We have detected 38 molecular species and 25 isotopologues. The isotopic ratios derived from column density ratios are consistent with the canonical values, indicating that chemical isotopic fractionation and/or selective photodissociation can be considered negligible (<10%) for the GC physical conditions. The derived abundance and rotational temperatures are very similar for both LOSs, indicating very similar chemical and excitation conditions for the molecular gas in the GC. The excitation conditions are also very similar to those found for the nucleus of the starburst galaxy NGC 253. We report for the first time the detection of HCO and HOC+ emission in LOS+0.693. Our comparison of the abundance ratios between CS, HCO, HOC+ and HCO+ found in the two LOSs with those in typical Galactic photodissociation regions (PDRs) and starbursts galaxies does not show any clear trend to distinguish between UV and X-ray induced chemistries. We propose that the CS/HOC+ ratio could be used as a tracer of the PDR components in the molecular clouds in the nuclei of galaxies

Complex organic molecules in the Galactic Centre: the N-bearing family

We present an unbiased spectral line survey toward the Galactic Centre (GC) quiescent giant molecular cloud (QGMC), G+0.693 using the GBT and IRAM 30$\,$ telescopes. Our study highlights an extremely rich organic inventory of abundant amounts of nitrogen (N)-bearing species in a source without signatures of star formation. We report the detection of 17 N-bearing species in this source, of which 8 are complex organic molecules (COMs). A comparison of the derived abundances relative to H$_2$ is made across various galactic and extragalactic environments. We conclude that the unique chemistry in this source is likely to be dominated by low-velocity shocks with X-rays/cosmic rays also playing an important role in the chemistry. Like previous findings obtained for O-bearing molecules, our results for N-bearing species suggest a more efficient hydrogenation of these species on dust grains in G+0.693 than in hot cores in the Galactic disk, as a consequence of the low dust temperatures coupled with energetic processing by X-ray/cosmic ray radiation in the GC.Comment: 24 pages, 23 figures, 7 tables, accepted for publication in MNRA

Herschel water maps towards the vicinity of the black hole Sgr A*

Aims: We study the spatial distribution and kinematics of water emission in a ~64 pc$^2$ region of the Galactic Center (GC) around Sgr A*. We also analyze the water excitation to derive the physical conditions and water abundances in the CND and the `quiescent clouds'. Methods: We presented the integrated intensity maps of the ortho 1$_{10}-1_{01}$, and para 2$_{02}-1_{11}$ and 1$_{11}-0_{00}$ water transitions observed with the HIFI instrument on board Herschel. To study the water excitation we used ground state ortho and para H$_2^{18}$O transitions. In our study, we also used SPIRE continuum measurements of the CND. Using a non-LTE radiative transfer code, the water line profiles and dust continuum were modeled. We also used a rotating ring model to reproduce the CND kinematics represented by the PV diagram. Results: We identify the water emission arising from the CND, the Western Streamer, and the 20 and 50 km s$^{-1}$ clouds. The ortho water maps show absorption structures in the range of [-220,10] km s$^{-1}$. The PV diagram shows that the 2$_{02}-1_{11}$ H$_2$O emission traces the CND. We derive high X$_{H_2O}$ of $\sim$(0.1-1.3)$\times$10$^{-5}$, V$_t$ of 14-23 km s$^{-1}$ and T$_d$ of 15-45 K for the CND, and the lower X$_{\rm H_2O}$ of 4$\times$10$^{-8}$ and V$_t$ of 9 km s$^{-1}$ for the 20 km s$^{-1}$ cloud. Collisional excitation and dust effects are responsible for the water excitation in the southwest lobe of the CND and the 20 km s$^{-1}$ cloud, whereas only collisions can account for the water excitation in the northeast lobe of the CND. We propose that the water vapor in the CND is caused by grain sputtering by shocks of 10-20 km s$^{-1}$, with some contribution of high temperature and cosmic-ray chemistries plus a PDR chemistry. The low X$_{\rm H_2O}$ derived for the 20 km s$^{-1}$ cloud could be partially a consequence of the water freeze-out on grains.Comment: 15 pages, 11 figure

Kinematics of Galactic Centre clouds shaped by shear-seeded solenoidal turbulence

The Central Molecular Zone (CMZ; the central ~ 500 pc of the Galaxy) is a kinematically unusual environment relative to the Galactic disc, with high velocity dispersions and a steep size-linewidth relation of the molecular clouds. In addition, the CMZ region has a significantly lower star formation rate (SFR) than expected by its large amount of dense gas. An important factor in explaining the low SFR is the turbulent state of the star-forming gas, which seems to be dominated by rotational modes. However, the turbulence driving mechanism remains unclear. In this work, we investigate how the Galactic gravitational potential affects the turbulence in CMZ clouds. We focus on the CMZ cloud G0.253+0.016 (`the Brick'), which is very quiescent and unlikely to be kinematically dominated by stellar feedback. We demonstrate that several kinematic properties of the Brick arise naturally in a cloud-scale hydrodynamics simulation that takes into account the Galactic gravitational potential. These properties include the line-of-sight velocity distribution, the steepened size-linewidth relation, and the predominantly solenoidal nature of the turbulence. Within the simulation, these properties result from the Galactic shear in combination with the cloud's gravitational collapse. This is a strong indication that the Galactic gravitational potential plays a crucial role in shaping the CMZ gas kinematics, and is a major contributor to suppressing the SFR by inducing predominantly solenoidal turbulent modes.Comment: 7 pages, 8 figures; accepted to MNRAS (July 24th 2023

Kinematics of Galactic Centre clouds shaped by shear-seeded solenoidal turbulence

The Central Molecular Zone (CMZ; the central ∼500 pc of the Galaxy) is a kinematically unusual environment relative to the Galactic disc, with high velocity dispersions and a steep size-linewidth relation of the molecular clouds. In addition, the CMZ region has a significantly lower star formation rate (SFR) than expected by its large amount of dense gas. An important factor in explaining the low SFR is the turbulent state of the star-forming gas, which seems to be dominated by rotational modes. However, the turbulence driving mechanism remains unclear. In this work, we investigate how the Galactic gravitational potential affects the turbulence in CMZ clouds. We focus on the CMZ cloud G0.253+0.016 (‘the Brick’), which is very quiescent and unlikely to be kinematically dominated by stellar feedback. We demonstrate that several kinematic properties of the Brick arise naturally in a cloud-scale hydrodynamics simulation that takes into account the Galactic gravitational potential. These properties include the line-of-sight velocity distribution, the steepened size-linewidth relation, and the predominantly solenoidal nature of the turbulence. Within the simulation, these properties result from the Galactic shear in combination with the cloud’s gravitational collapse. This is a strong indication that the Galactic gravitational potential plays a crucial role in shaping the CMZ gas kinematics, and is a major contributor to suppressing the SFR by inducing predominantly solenoidal turbulent modes

Broad-line Region Clouds orbiting an AGN sample

We present a spectral and temporal analysis of XMM-Newton data from a sample of six galaxies (NGC 3783, Mrk 279, Mrk 766, NGC 3227, NGC 7314, and NGC 3516). Using the hardness-ratio curves, we identify time-intervals in which clouds are eclipsing the central X-ray source in five of the six sources. We detect three occultations in NGC 3227 and one occultation in NGC 3783, NGC 7314, and NGC 3516, together with the well-known occultations in Mrk 766. We estimate the physical properties of the eclipsing clouds. The derived physical size of the X-ray sources ($\sim$(3-28)$\times$10$^{13}$ cm) is less than that of the eclipsing clouds with column densities of $\sim$10$^{22}$-10$^{23}$ cm$^{-2}$, thus a single cloud may block the X-ray source, leading to notorious temporal variability of the X-ray flux. The eclipsing clouds in Mrk 766, NGC 3227, NGC 7314, and NGC 3516 with distances from the X-ray source of $\sim$(0.3-3.6)$\times$10$^4$ $R_g$ are moving at Keplerian velocities $>$1122 km s$^{-1}$, typical parameters of broad-line region clouds, while the eclipsing cloud in NGC 3783 is likely located in the dusty torus. We also find a good anti-correlation with a slope of -187$\pm$62 between the known masses of the supermassive black hole in the center of the galaxies with the equivalent width (EW) of the 6.4 keV Fe line for the five Seyfert 1 galaxies of our sample, while the Seyfert 2 galaxy NGC 7314 shows an average EW value of 100$\pm$11 eV inconsistent with the above anti-correlation.Comment: 13 pages, 15 figures, accepted for publication in MNRA

Structure and kinematics of shocked gas in Sgr B2: Further evidence of a cloud-cloud collision from SiO emission maps

We present SiO J = 2-1 maps of the Sgr B2 molecular cloud, which show shocked gas with a turbulent substructure comprising at least three cavities at velocities of [10,40]km s-1 and an arc at velocities of [-20,10] kms-1. The spatial anticorrelation of shocked gas at low and high velocities, and the presence of bridging features in position-velocity diagrams suggest that these structures formed in a cloud-cloud collision. Some of the known compact H ii regions spatially overlap with sites of strong SiO emission at velocities of [40,85]kms-1 and are between or along the edges of SiO gas features at [100,120]kms-1, suggesting that the stars responsible for ionizing the compact H ii regions formed in compressed gas due to this collision. We find gas densities and kinetic temperatures of the order of nm H2∼ 105cm-3 and ∼ 30K, respectively, towards three positions of Sgr B2. The average values of the SiO relative abundances, integrated line intensities, and line widths are ∼10-9, ∼ 11 Kkms-1, and ∼ 31kms-1, respectively. These values agree with those obtained with chemical models that mimic grain sputtering by C-type shocks. A comparison of our observations with hydrodynamical simulations shows that a cloud-cloud collision that took place 0.5 Myr ago can explain the density distribution with a mean column density of NrmH2 5× 1022cm-2, and the morphology and kinematics of shocked gas in different velocity channels. Colliding clouds are efficient at producing internal shocks with velocities ∼ 5-50kms-1. High-velocity shocks are produced during the early stages of the collision and can readily ignite star formation, while moderate- and low-velocity shocks are important over longer time-scales and can explain the widespread SiO emission in Sgr B2.With funding from the Spanish government through the "María de Maeztu Unit of Excellence" accreditation (MDM-2017-0737

On the Effects of UV Photons/X-Rays on the Chemistry of the Sgr B2 Cloud

The lines of HOC, HCO, and CO are considered good tracers of photon-dominated regions (PDRs) and X-ray-dominated regions. We study these tracers toward regions of the Sgr B2 cloud selected to be affected by different heating mechanisms. We find the lowest values of the column density ratios of HCO versus HOC, HCO, and CO in dense H ii gas, where UV photons dominate the heating and chemistry of the gas. The HOC, HCO, and CO abundances and the above ratios are compared with those of chemical modeling, finding that high-temperature chemistry, a cosmic-ray ionization rate of 10 s, and timescales >10 yr explain well the HOC abundances in quiescent Sgr B2 regions, while shocks are also needed to explain the highest HCO abundances derived for these regions. The CO is mainly formed in PDRs, since the highest CO abundances of ∼(6-10) 10 are found in H ii regions with electron densities >540 cm and CO emission is undetected in quiescent gas. Among the ratios, the HCO/HCO ratio is sensitive to the electron density, as it shows different values in dense and diffuse H ii regions. We compare SiO J = 2-1 emission maps of Sgr B2 with X-ray maps from 2004 and 2012. One known spot shown on the 2012 X-ray map is likely associated with molecular gas at velocities of 15-25 km s. We also derive the X-ray ionization rate of ∼10 s for Sgr B2 regions pervaded by X-rays in 2004, which is quite low to affect the chemistry of the molecular gas.With funding from the Spanish government through the "María de Maeztu Unit of Excellence" accreditation (MDM-2017-0737