2,609 research outputs found
Fragility and compressibility at the glass transition
Isothermal compressibilities and Brillouin sound velocities from the
literature allow to separate the compressibility at the glass transition into a
high-frequency vibrational and a low-frequency relaxational part. Their ratio
shows the linear fragility relation discovered by x-ray Brillouin scattering
[1], though the data bend away from the line at higher fragilities. Using the
concept of constrained degrees of freedom, one can show that the vibrational
part follows the fragility-independent Lindemann criterion; the fragility
dependence seems to stem from the relaxational part. The physical meaning of
this finding is discussed. [1] T. Scopigno, G. Ruocco, F. Sette and G. Monaco,
Science 302, 849 (2003)Comment: 4 pages, 2 figures, 2 tables, 33 references. Slightly changed after
refereein
The viscous slowing down of supercooled liquids as a temperature-controlled superArrhenius activated process: a description in terms of frustration-limited domains
We propose that the salient feature to be explained about the glass
transition of supercooled liquids is the temperature-controlled superArrhenius
activated nature of the viscous slowing down, more strikingly seen in
weakly-bonded, fragile systems. In the light of this observation, the relevance
of simple models of spherically interacting particles and that of models based
on free-volume congested dynamics are questioned. Finally, we discuss how the
main aspects of the phenomenology of supercooled liquids, including the
crossover from Arrhenius to superArrhenius activated behavior and the
heterogeneous character of the relaxation, can be described by an
approach based on frustration-limited domains.Comment: 13 pages, 4 figures, accepted in J. Phys.: Condensed Matter,
proceedings of the Trieste workshop on "Unifying Concepts in Glass Physics
Subdiffusion and cage effect in a sheared granular material
We investigate experimentally the diffusion properties of a bidimensional
bidisperse dry granular material under quasistatic cyclic shear.The comparison
of these properties with results obtained both in computer simulations of hard
spheres systems and Lenard-Jones liquids and experiments on colloidal systems
near the glass transition demonstrates a strong analogy between the behaviour
of granular matter and these systems. More specifically, we study in detail the
cage dynamics responsible for the subdiffusion in the slow relaxation regime,
and obtain the values of relevant time and length scales.Comment: 4 pages, 6 figures, submitted to PR
Spinodal of supercooled polarizable water
We develop a series of molecular dynamics computer simulations of liquid
water, performed with a polarizable potential model, to calculate the spinodal
line and the curve of maximum density inside the metastable supercooled region.
After analysing the structural properties,the liquid spinodal line is followed
down to T=210 K. A monotonic decrease is found in the explored region. The
curve of maximum density bends on approaching the spinodal line. These results,
in agreement with similar studies on non polarizable models of water, are
consistent with the existence of a second critical point for water.Comment: 8 pages, 5 figures, 2 tables. To be published in Phys. Re
Microscopic theory of network glasses
A molecular theory of the glass transition of network forming liquids is
developed using a combination of self-consistent phonon and liquid state
approaches. Both the dynamical transition and the entropy crisis characteristic
of random first order transitions are mapped out as a function of the degree of
bonding and the density. Using a scaling relation for a soft-core model to
crudely translate the densities into temperatures, the theory predicts that the
ratio of the dynamical transition temperature to the laboratory transition
temperature rises as the degree of bonding increases, while the Kauzmann
temperature falls relative to the laboratory transition. These results indicate
why highly coordinated liquids should be "strong" while van der Waals liquids
without coordination are "fragile".Comment: slightly revised version that has been accepted for publication in
Phys. Rev. Let
Molecular structural order and anomalies in liquid silica
The present investigation examines the relationship between structural order,
diffusivity anomalies, and density anomalies in liquid silica by means of
molecular dynamics simulations. We use previously defined orientational and
translational order parameters to quantify local structural order in atomic
configurations. Extensive simulations are performed at different state points
to measure structural order, diffusivity, and thermodynamic properties. It is
found that silica shares many trends recently reported for water [J. R.
Errington and P. G. Debenedetti, Nature 409, 318 (2001)]. At intermediate
densities, the distribution of local orientational order is bimodal. At fixed
temperature, order parameter extrema occur upon compression: a maximum in
orientational order followed by a minimum in translational order. Unlike water,
however, silica's translational order parameter minimum is broad, and there is
no range of thermodynamic conditions where both parameters are strictly
coupled. Furthermore, the temperature-density regime where both structural
order parameters decrease upon isothermal compression (the structurally
anomalous regime) does not encompass the region of diffusivity anomalies, as
was the case for water.Comment: 30 pages, 8 figure
Effect of entropy on the dynamics of supercooled liquids: New results from high pressure data
We show that for arbitrary thermodynamic conditions, master curves of the
entropy are obtained by expressing S(T,V) as a function of TV^g_G, where T is
temperature, V specific volume, and g_G the thermodynamic Gruneisen parameter.
A similar scaling is known for structural relaxation times,tau = f(TV^g);
however, we find g_G < g. We show herein that this inequality reflects
contributions to S(T,V) from processes, such as vibrations and secondary
relaxations, that do not directly influence the supercooled dynamics. An
approximate method is proposed to remove these contributions, S_0, yielding the
relationship tau = f(S-S_0).Comment: 10 pages 7 figure
Don't Distract Me When I'm Media Multitasking: Toward a Theory for Raising Advertising Recall and Recognition
Media multitasking, such as using handheld devices like smartphones and tablets while watching TV, has become prevalent but its effect on the recall and recognition of advertising subject to limited academic research. We contend that the context in which multitasking takes place affects consumer memory for advertising delivered via the primary activity (e.g., watching television). Specifically, we identify the importance of the degree of (a) congruence between the primary and second screen activity and (b) social accountability of second screen activities. We test our typology empirically by examining the determinants of next day recall and recognition for billboard advertisers (perimeter board advertisements) of a televised football (soccer) match. In line with our theory, in most cases media multitasking leads to worse recall and recognition, however, in situations where there is congruence between primary and second screen activities and secondary activities have a higher level of social accountability attached to them, then advertising recall and recognition improves
Liquid Limits: The Glass Transition and Liquid-Gas Spinodal Boundaries of Metastable Liquids
The liquid-gas spinodal and the glass transition define ultimate boundaries
beyond which substances cannot exist as (stable or metastable) liquids. The
relation between these limits is analyzed {\it via} computer simulations of a
model liquid. The results obtained indicate that the liquid - gas spinodal and
the glass transition lines intersect at a finite temperature, implying a glass
- gas mechanical instability locus at low temperatures. The glass transition
lines obtained by thermodynamic and dynamic criteria agree very well with each
other.Comment: 5 pages, 4 figures, to appear in Phys. Rev. Let
Trends in total column ozone measurements
It is important to ensure the best available data are used in any determination of possible trends in total ozone in order to have the most accurate estimates of any trends and the associated uncertainties. Accordingly, the existing total ozone records were examined in considerable detail. Once the best data set has been produced, the statistical analysis must examine the data for any effects that might indicate changes in the behavior of global total ozone. The changes at any individual measuring station could be local in nature, and herein, particular attention was paid to the seasonal and latitudinal variations of total ozone, because two dimensional photochemical models indicate that any changes in total ozone would be most pronounced at high latitudes during the winter months. The conclusions derived from this detailed examination of available total ozone can be split into two categories, one concerning the quality and the other the statistical analysis of the total ozone record
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