Equilibrios al estado sólido entre frases de solución sólida en sistemas minerales binarios: Sistema RbBr-RbI

X-ray diffraction has been used to study the de equilimixtion in solid state of Rb(BrXIi..) solid solutions The compositions of the phases in equilibrium at room temnerature are 0.18 RbBr-0.82 RbI and 0.96 RbBr-0.04 ÉZb1, respectively. The maximum critical  temperature of the demixtion is 422ºC, corresponding to the composition X~t.1= 0.35. AS a result of this experimental work the existente of a  single-phase region at high-temperature and a two-phases region at interdifracmediate and  low-temperature has been established

A Double Payload Complex between Hypericin and All-trans Retinoic Acid in the β-Lactoglobulin Protein

Combined therapies are usually used to treat acne vulgaris since this approach can tackle various foci simultaneously. Using a combination of spectroscopic, computational, and microbiological techniques and methods, herein we report on the use of β-lactoglobulin as a double payload carrier of hypericin (an antimicrobial photodynamic agent) and all-trans retinoic acid (an anti-inflammatory drug) for S. aureus in vitro photodynamic inactivation. The addition of all-trans retinoic acid to hypericinβ-lactoglobulin complex renders a photochemically safe vehicle due to the photophysical quenching of hypericin, which recovers its photodynamic activity when in contact with bacteria. The ability of hypericin to photoinactivate S. aureus was not affected by retinoic acid. β-Lactoglobulin is a novel biocompatible and photochemically safe nanovehicle with strong potential for the treatment of acne

Massive open star clusters using the VVV survey III: A young massive cluster at the far edge of the Galactic bar

Context: Young massive clusters are key to map the Milky Way's structure, and near-IR large area sky surveys have contributed strongly to the discovery of new obscured massive stellar clusters. Aims: We present the third article in a series of papers focused on young and massive clusters discovered in the VVV survey. This article is dedicated to the physical characterization of VVV CL086, using part of its OB-stellar population. Methods: We physically characterized the cluster using $JHK_S$ near-infrared photometry from ESO public survey VVV images, using the VVV-SkZ pipeline, and near-infrared $K$-band spectroscopy, following the methodology presented in the first article of the series. Results: Individual distances for two observed stars indicate that the cluster is located at the far edge of the Galactic bar. These stars, which are probable cluster members from the statistically field-star decontaminated CMD, have spectral types between O9 and B0V. According to our analysis, this young cluster ($1.0$ Myr $<$ age $< 5.0$ Myr) is located at a distance of $11^{+5}_{-6}$ kpc, and we estimate a lower limit for the cluster total mass of $(2.8^{+1.6}_{-1.4})\cdot10^3 {M}_{\odot}$. It is likely that the cluster contains even earlier and more massive stars.Comment: Accepted for publication as a Letter in A&

Quadratic transverse anisotropy term due to dislocations in Mn12-Ac directly obtained by EPR spectroscopy

High-Sensitivity Electron Paramagnetic Resonance experiments have been carried out in fresh and stressed Mn12-Acetate single crystals for frequencies ranging from 40 GHz up to 110 GHz. The high number of crystal dislocations formed in the stressing process introduces a E(S_x^2-S_y^2) transverse anisotropy term in the spin hamiltonian. From the behaviour of the resonant absorptions on the applied transverse magnetic field we have obtained an average value for E = 22 mK, corresponding to a concentration of dislocations per unit cell of c = 10^-3.Comment: 13 pages and 4 figure

Dirac Gauginos, Negative Supertraces and Gauge Mediation

In an attempt to maximize General Gauge Mediated parameter space, I propose simple models in which gauginos and scalars are generated from disconnected mechanisms. In my models Dirac gauginos are generated through the supersoft mechanism, while independent R-symmetric scalar masses are generated through operators involving non-zero messenger supertrace. I propose several new methods for generating negative messenger supertraces which result in viable positive mass squareds for MSSM scalars. The resultant spectra are novel, compressed and may contain light fermionic SM adjoint fields.Comment: 16 pages 3 figure

Formulation and constraints on decaying dark matter with finite mass daughter particles

Decaying dark matter cosmological models have been proposed to remedy the overproduction problem at small scales in the standard cold dark matter paradigm. We consider a decaying dark matter model in which one CDM mother particle decays into two daughter particles, with arbitrary masses. A complete set of Boltzmann equations of dark matter particles is derived which is necessary to calculate the evolutions of their energy densities and their density perturbations. By comparing the expansion history of the universe in this model and the free-streaming scale of daughter particles with astronomical observational data, we give constraints on the lifetime of the mother particle, $\Gamma^{-1}$, and the mass ratio between the daughter and the mother particles $m_{\rm D}/m_{\rm M}$. From the distance to the last scattering surface of the cosmic microwave background, we obtain $\Gamma^{-1}>$ 30 Gyr in the massless limit of daughter particles and, on the other hand, we obtain $m_{\rm D} >$ 0.97$m_{\rm M}$ in the limit $\Gamma^{-1}\to 0$. The free-streaming constraint tightens the bound on the mass ratio as $(\Gamma^{-1}/10^{-2}{\rm Gyr}) \lesssim ((1-m_{\rm D1}/m_{\rm M})/10^{-2})^{-3/2}$ for $\Gamma^{-1} < H^{-1}(z=3)$.Comment: 20 pages, 7 figure

Goldstini Can Give the Higgs a Boost

Supersymmetric collider phenomenology depends crucially on whether the lightest observable-sector supersymmetric particle (LOSP) decays, and if so, what the LOSP decay products are. For instance, in SUSY models where the gravitino is lighter than the LOSP, the LOSP decays to its superpartner and a longitudinal gravitino via supercurrent couplings. In this paper, we show that LOSP decays can be substantially modified when there are multiple sectors that break supersymmetry, where in addition to the gravitino there are light uneaten goldstini. As a particularly striking example, a bino-like LOSP can have a near 100% branching fraction to a higgs boson and an uneaten goldstino, even if the LOSP has negligible higgsino fraction. This occurs because the uneaten goldstino is unconstrained by the supercurrent, allowing additional operators to mediate LOSP decay. These operators can be enhanced in the presence of an R symmetry, leading to copious boosted higgs production in SUSY cascade decays.Comment: 30 pages, 12 figures; v2: title change, clarifications added, version to appear in JHE

Optimization of an Adsorbed Natural Gas System with Phase Change Material using the Topology Optimization Method

Abstract. Natural Gas has been drawing industrial sectors attention as a promising alternative fuel. This solutions attractiveness depends on the quality and efficiency of the storage and transport methods employed. Porous media are known to be an efficient manner to store natural gas by the adsorption mechanism, also known as Adsorbed Natural Gas (ANG). Temperatureexerts significant influence on adsorption efficiency. Studies applying Phase Change Materials (PCM) as heat exchanger in ANG systems suggests the combination improves the vessel capacity and adsorption and desorption rates behavior. In addition, the PCM bodies shape and position inside adsorption systems greatly affects the benefits they bring. For this reason, theTopology Optimization Method (TOM) is indicated for this problem. The topology optimization method is a versatile tool for material distribution inside a domain and in the last few decades its capabilities of exploring manufacturing process characteristics as well as its implementation have been improved. This study aims to increase the capacity and performance of Adsorbed Natural Gas (ANG) Vessels using TOM to distribute PCM material in the vessel interior. Thephysical model consider a coupled heat and mass transfer trough an ANG vessel with PCM in its interior, the boundary conditions are dictated by a pressure input in the vessels extremity and the natural convection on the vessels walls. FEniCS Project libraries are employed in the governing equations implementation and to work the solution for the differential equations and dolphin-adjoint libraries are applied to perform the sensitivities calculus. The project variable for the optimization is defined as the PCM distribution inside the vessel. Thermal properties corrections are performed according to an analytical solution for the phase change problem.Phase change enthalpy corrections are performed in the level of the variational problem to model the phase change phenomena. The amount of heat transferred to the phase change enthalpy dictates the phase composition in the domain. The implementation benefits the topology optimization approach as it maintains the duality between the adsorbent volume to adsorb gas and the PCM volume to store heat. An experimental work from the literature is modelled andcompared to the numerical results for software validation and model properties calibration. As results a 2D ANG vessel optimization is performed, the final topologies are presented and their total adsorption volume and charging/discharging time are compared.Keywords: Adsorption, Optimization, PCM, ANG, Desorptio

New galactic star clusters discovered in the VVV survey : Candidates projected on the inner disk and bulge

Context. VISTA Variables in the Vía Láctea (VVV) is one of six ESO Public Surveys using the 4 meter Visible and Infrared Survey Telescope for Astronomy (VISTA). The VVV survey covers the Milky Way bulge and an adjacent section of the disk, and one of the principal objectives is to search for new star clusters within previously unreachable obscured parts of the Galaxy. Aims. The primary motivation behind this work is to discover and analyze obscured star clusters in the direction of the inner Galactic disk and bulge. Methods. Regions of the inner disk and bulge covered by the VVV survey were visually inspected using composite JHKS color images to select new cluster candidates on the basis of apparent overdensities. DR1, DR2, CASU, and point spread function photometry of 10 × 10 arcmin fields centered on each candidate cluster were used to construct color-magnitude and color-color diagrams. Follow-up spectroscopy of the brightest members of several cluster candidates was obtained in order to clarify their nature. Results. We report the discovery of 58 new infrared cluster candidates. Fundamental parameters such as age, distance, and metallicity were determined for 20 of the most populous clusters.Peer reviewedFinal Accepted Versio