Effects of external global noise on the catalytic CO oxidation on Pt(110)

Oxidation reaction of CO on a single platinum crystal is a reaction-diffusion system that may exhibit bistable, excitable, and oscillatory behavior. We studied the effect of a stochastic signal artificially introduced into the system through the partial pressure of CO. First, the external signal is employed as a turbulence suppression tool, and second, it modifies the boundaries in the bistable transition between the CO and oxygen covered phases. Experiments using photoemission electron microscopy (PEEM) together with numerical simulations performed with the Krischer-Eiswirth-Ertl (KEE) model are presented.Comment: 15 pages, 7 figures, accepted in J. Chem. Phy

Quicksort with unreliable comparisons: a probabilistic analysis

We provide a probabilistic analysis of the output of Quicksort when comparisons can err.Comment: 29 pages, 3 figure

Further constraints on the optical transmission spectrum of HAT-P-1b

We report on novel observations of HAT-P-1 aimed at constraining the optical transmission spectrum of the atmosphere of its transiting Hot-Jupiter exoplanet. Ground-based differential spectrophotometry was performed over two transit windows using the DOLORES spectrograph at the Telescopio Nazionale Galileo (TNG). Our measurements imply an average planet to star radius ratio equal to $\rm R_p/R_{\star}$=(0.1159$\pm$0.0005). This result is consistent with the value obtained from recent near infrared measurements of this object but differs from previously reported optical measurements being lower by around 4.4 exoplanet scale heights. Analyzing the data over 5 different spectral bins 600\AA$\,$ wide we observed a single peaked spectrum (3.7 $\rm\sigma$ level) with a blue cut-off corresponding to the blue edge of the broad absorption wing of sodium and an increased absorption in the region in between 6180-7400\AA. We also infer that the width of the broad absorption wings due to alkali metals is likely narrower than the one implied by solar abundance clear atmospheric models. We interpret the result as evidence that HAT-P-1b has a partially clear atmosphere at optical wavelengths with a more modest contribution from an optical absorber than previously reported.Comment: Accepted by Ap

NLTE determination of the aluminium abundance in a homogeneous sample of extremely metal-poor stars

Aims: Aluminium is a key element to constrain the models of the chemical enrichment and the yields of the first supernovae. But obtaining precise Al abundances in extremely metal-poor (EMP) stars requires that the non-LTE effects be carefully taken into account. Methods: The NLTE profiles of the blue resonance aluminium lines have been computed in a sample of 53 extremely metal-poor stars with a modified version of the program MULTI applied to an atomic model of the Al atom with 78 levels of Al I and 13 levels of Al II, and compared to the observations. Results: With these new determinations, all the stars of the sample show a ratio Al/Fe close to the solar value: [Al/Fe] =-0.06 +- 0.10 with a very small scatter. These results are compared to the models of the chemical evolution of the halo using different models of SN II and are compatible with recent computations. The sodium-rich giants are not found to be also aluminium-rich and thus, as expected, the convection in these giants only brings to the surface the products of the Ne-Na cycle.Comment: To be published on A&

Spectroscopic characterization and detection of Ethyl Mercaptan in Orion

New laboratory data of ethyl mercaptan, CH$_{3}$CH$_{2}$SH, in the millimeter and submillimeter-wave domains (up to 880 GHz) provided very precise values of the spectroscopic constants that allowed the detection of $gauche$-CH$_3$CH$_2$SH towards Orion KL. 77 unblended or slightly blended lines plus no missing transitions in the range 80-280 GHz support this identification. A detection of methyl mercaptan, CH$_{3}$SH, in the spectral survey of Orion KL is reported as well. Our column density results indicate that methyl mercaptan is $\simeq$ 5 times more abundant than ethyl mercaptan in the hot core of Orion KL.Comment: Accepted for publication in ApJL (30 January 2014)/ submitted (8 January 2014

Semiclassical expansions in the Toda hierarchy and the hermitian matrix model

An iterative algorithm for determining a class of solutions of the dispersionful 2-Toda hierarchy characterized by string equations is developed. This class includes the solution which underlies the large N-limit of the Hermitian matrix model in the one-cut case. It is also shown how the double scaling limit can be naturally formulated in this schemeComment: 22 page

Efficient formalism for large scale ab initio molecular dynamics based on time-dependent density functional theory

A new "on the fly" method to perform Born-Oppenheimer ab initio molecular dynamics (AIMD) is presented. Inspired by Ehrenfest dynamics in time-dependent density functional theory, the electronic orbitals are evolved by a Schroedinger-like equation, where the orbital time derivative is multiplied by a parameter. This parameter controls the time scale of the fictitious electronic motion and speeds up the calculations with respect to standard Ehrenfest dynamics. In contrast to other methods, wave function orthogonality needs not be imposed as it is automatically preserved, which is of paramount relevance for large scale AIMD simulations.Comment: 5 pages, 3 color figures, revtex4 packag