Experimental study of aqueous foam generation and transport in a horizontal pipe for deliquification purposes

This work presents and analyses the results of experimental activities aimed at a preliminary characterization of foamy flows for pipeline dewatering, in order to assess whether the addition of surfactants may effectively reduce the liquid holdup in horizontal pipelines. Static tests were run to compare the foam cycle (generation and decay) for three commercial surfactants and to choose the most suitable one. Dynamic tests with the selected product were performed in a 20 m long, 60 mm i.d. Plexiglas® pipe, where a 0.3% wt. solution of surfactant in tap water was pumped after mixing with an air flow at nearly atmospheric pressure and temperature. Superficial velocities ranged between 0.03 m/s and 0.05 m/s for water and between 1.5 m/s and 11.5 m/s for air, which would determine stratified/stratified wavy flows in the case of pure water-air flow, i.e. the benchmark case. Due to the presence of the surfactant, foam formed in the mixing section, which implied a significant change in the flow patterns that were photographically recorded and classified into three main types: plug, stratified wavy and stratified with foam entrainment, as far as the air superficial velocity was increased at constant water superficial velocity. The associated pressure drop, linearly distributed along the pipeline, resulted greater than the benchmark value in all the operating conditions, with a dramatic increase (even more than 100%) for plug flows. On the other hand, the percentage relative difference was found to lower with increasing the air superficial velocity, apart for stratified wavy flows where it seemed to keep constant at about 3.3%. Finally, a theoretical model for stratified flows was used to relate the pressure drop to the void fraction in order to get at least an approximate indication of the liquid load reduction due to the surfactant addition, which ranged between 6% and 39%

Comprehensive Chemical Fingerprinting of High-Quality Cocoa at Early Stages of Processing: Effectiveness of Combined Untargeted and Targeted Approaches for Classification and Discrimination

This study investigates chemical information of volatile fractions of high-quality cocoa (<i>Theobroma cacao</i> L. Malvaceae) from different origins (Mexico, Ecuador, Venezuela, Columbia, Java, Trinidad, and Sao Tomè) produced for fine chocolate. This study explores the evolution of the entire pattern of volatiles in relation to cocoa processing (raw, roasted, steamed, and ground beans). Advanced chemical fingerprinting (e.g., combined untargeted and targeted fingerprinting) with comprehensive two-dimensional gas chromatography coupled with mass spectrometry allows advanced pattern recognition for classification, discrimination, and sensory-quality characterization. The entire data set is analyzed for 595 reliable two-dimensional peak regions, including 130 known analytes and 13 potent odorants. Multivariate analysis with unsupervised exploration (principal component analysis) and simple supervised discrimination methods (Fisher ratios and linear regression trees) reveal informative patterns of similarities and differences and identify characteristic compounds related to sample origin and manufacturing step