Addition of N-nucleophiles to gold(III)-bound isocyanides leading to short-lived gold(III) acyclic diaminocarbene complexes

Addition of hydrazone to gold(iii)–isocyanides led to the generation of rare short-lived gold(iii) acyclic diaminocarbene complexes.</p

The origins and spread of domestic horses from the Western Eurasian steppes

This is the final version. Available on open access from Nature Research via the DOI in this recordData availability: All collapsed and paired-end sequence data for samples sequenced in this study are available in compressed fastq format through the European Nucleotide Archive under accession number PRJEB44430, together with rescaled and trimmed bam sequence alignments against both the nuclear and mitochondrial horse reference genomes. Previously published ancient data used in this study are available under accession numbers PRJEB7537, PRJEB10098, PRJEB10854, PRJEB22390 and PRJEB31613, and detailed in Supplementary Table 1. The genomes of ten modern horses, publicly available, were also accessed as indicated in their corresponding original publications57,61,85-87.NOTE: see the published version available via the DOI in this record for the full list of authorsDomestication of horses fundamentally transformed long-range mobility and warfare. However, modern domesticated breeds do not descend from the earliest domestic horse lineage associated with archaeological evidence of bridling, milking and corralling at Botai, Central Asia around 3500 BC. Other longstanding candidate regions for horse domestication, such as Iberia and Anatolia, have also recently been challenged. Thus, the genetic, geographic and temporal origins of modern domestic horses have remained unknown. Here we pinpoint the Western Eurasian steppes, especially the lower Volga-Don region, as the homeland of modern domestic horses. Furthermore, we map the population changes accompanying domestication from 273 ancient horse genomes. This reveals that modern domestic horses ultimately replaced almost all other local populations as they expanded rapidly across Eurasia from about 2000 BC, synchronously with equestrian material culture, including Sintashta spoke-wheeled chariots. We find that equestrianism involved strong selection for critical locomotor and behavioural adaptations at the GSDMC and ZFPM1 genes. Our results reject the commonly held association between horseback riding and the massive expansion of Yamnaya steppe pastoralists into Europe around 3000 BC driving the spread of Indo-European languages. This contrasts with the scenario in Asia where Indo-Iranian languages, chariots and horses spread together, following the early second millennium BC Sintashta culture

First results from recent JET experiments in Hydrogen and Hydrogen-Deuterium plasmas

The hydrogen campaign completed at JET in 2016 has demonstrated isotope ratio control in JET-ILW using gas puffing and pellets for fuelling, Neutral Beam Injection alone or in combination, with D/H spectroscopy as a diagnostic. The plasma properties such as confinement, L-H threshold, density limit depend on the isotope composition. The L-H transition power increases with the hydrogen concentration with a wide plateau in the range 0.2<nH/(nD+nH)<0.8. Energy confinement is significantly lower in hydrogen than in comparable deuterium ELMy H-mode plasmas, suggesting an isotope mass scaling that is stronger than in IPB98(y,2). In L-mode, the isotope dependence of confinement is weaker. The H-mode density limit in hydrogen is up to 35% lower than in heuterium, whilst it is found to be higher in L-mode. The lower ion mass leads to reduced tungsten sputtering in hydrogen plasmas. During the campaign, the nD/(nD+nH) ratio dropped to ~1% in only a few discharges after the last deliberate introduction of deuterium, although it was seen to rise again to ~2% with several seconds of exposure of the divertor tiles to ~10MW of auxiliary heating. Several ICRH scenarios were also tested in hydrogen plasmas

Editorial for Special Issue Symmetry in Physics of Plasma Technologies

This Special Issue collected papers on hot topics in the field of controlled thermonuclear fusion (CTF), including review papers and research articles [...

Lévy Walks as a Universal Mechanism of Turbulence Nonlocality

The nonlocality (superdiffusion) of turbulence is expressed in the empiric Richardson t3 scaling law for the mean square of the mutual separation of a pair of particles in a fluid or gaseous medium. The development of the theory of nonlocality of various processes in physics and other sciences based on the concept of Lévy flights resulted in Shlesinger and colleagues’ about the possibility of describing the nonlocality of turbulence using a linear integro-differential equation with a slowly falling kernel. The approach developed by us made it possible to establish the closeness of the superdiffusion parameter of plasma density fluctuations moving across a strong magnetic field in a tokamak to the Richardson law. In this paper, we show the possibility of a universal description of the characteristics of nonlocality of transfer in a stochastic medium (including turbulence of gases and fluids) using the Biberman–Holstein approach to examine the transfer of excitation of a medium by photons, generalized in order to take into account the finiteness of the velocity of excitation carriers. This approach enables us to propose a scaling that generalizes Richardson’s t3 scaling law to the combined regime of Lévy flights and Lévy walks in fluids and gases

Spectral Intensity of Electron Cyclotron Radiation Emerging from the Plasma to the First Wall in ITER

It is predicted that in ITER, due to high values of electron temperature and magnetic field strength, electron cyclotron (EC) radiation emitted by plasma will be a significant source (together with external EC radiation injected for auxiliary plasma heating and non-inductive current drive) of additional thermal and electromagnetic loads for microwave and optical diagnostics. The spectral distribution of plasma EC radiation is particularly important to consider in millimeter-wave diagnostics, namely for high- and low-magnetic-field side reflectometry, plasma position reflectometry, and collective Thomson scattering diagnostic, because the transmission lines of these diagnostics yield the transport of EC waves emitted by the plasma. The development of semi-analytical methods used to describe the spectral distribution of plasma-generated EC radiation in tokamaks, starting from the work of S. Tamor, is based on the dominance of multiple reflections of this radiation from the first wall in a toroidal axially symmetric vacuum chamber. Here, we present calculations using the CYNEQ code of the spectral intensity of the EC radiation emerging from the plasma to the first wall and port plugs for five scenarios of ITER operation. This code uses the symmetry-based effect of approximate isotropy and homogeneity of radiation intensity in a substantial part of the phase space and has been successfully tested by comparison with first-principles codes. The energy flux density in the range of 30–200 kW/m2 is predicted for wall reflectance in the range of 0.6–0.95. The possible effect of this radiation on in-vessel components and diagnostics is assessed by calculating the surface density of the energy absorbed by various materials of the ITER first wall

New Approach to Cross-Correlation Reflectometry Diagnostics of Nonlocality of Plasma Turbulence

One of the most important properties of stochastic nonlinear processes, including the turbulence of the hydrodynamic motion of continuous media, is distant spatial correlations. To describe them, an approach was proposed by Shlesinger and colleagues based on a linear integro-differential equation with a slowly decaying kernel, which corresponds to superdiffusion (nonlocal) transfer in the regime of Lévy walks (Lévy flights when the finite velocity of the carriers is taken into account). In this paper, we formulate a similar approach that makes it possible to formulate the problem of determining these properties from the scattering spectra of electromagnetic (EM) waves and cross-correlation reflectometry. A universal description of the relationship between the observed symmetric quasi-coherent component in the spectrum of scattered EM waves in plasmas and a process of the Mandelstam–Brillouin scattering type is obtained. It is shown that the nonlocality of spatial correlations of density fluctuations in a turbulent medium is due to long-free-path carriers of the medium’s perturbations, for which the free path distribution function is described by the Lévy distribution. The effectiveness of the proposed method is shown by the example of the interpretation of the data of cross-correlation reflectometry of EM waves in the radio-frequency range for the diagnosis of turbulent plasma in magnetic confinement devices for axisymmetric toroidal thermonuclear plasma

New Approach to Cross-Correlation Reflectometry Diagnostics of Nonlocality of Plasma Turbulence

One of the most important properties of stochastic nonlinear processes, including the turbulence of the hydrodynamic motion of continuous media, is distant spatial correlations. To describe them, an approach was proposed by Shlesinger and colleagues based on a linear integro-differential equation with a slowly decaying kernel, which corresponds to superdiffusion (nonlocal) transfer in the regime of L&eacute;vy walks (L&eacute;vy flights when the finite velocity of the carriers is taken into account). In this paper, we formulate a similar approach that makes it possible to formulate the problem of determining these properties from the scattering spectra of electromagnetic (EM) waves and cross-correlation reflectometry. A universal description of the relationship between the observed symmetric quasi-coherent component in the spectrum of scattered EM waves in plasmas and a process of the Mandelstam&ndash;Brillouin scattering type is obtained. It is shown that the nonlocality of spatial correlations of density fluctuations in a turbulent medium is due to long-free-path carriers of the medium&rsquo;s perturbations, for which the free path distribution function is described by the L&eacute;vy distribution. The effectiveness of the proposed method is shown by the example of the interpretation of the data of cross-correlation reflectometry of EM waves in the radio-frequency range for the diagnosis of turbulent plasma in magnetic confinement devices for axisymmetric toroidal thermonuclear plasma