54 research outputs found
A lifecycle cost-driven system dynamics approach for considering additive re-manufacturing or repair in aero-engine component design
Aero-engine component design decisions should consider re-manufacturing and/or repair strategies and their impact on lifecycle cost. Existing design approaches do not account for alternative production technologies such as the use of additive manufacturing in life extension processes. This paper presents a modeling and optimization methodology for examining the impact of design decisions in the early development stage on component lifecycle cost during the in-service phase while considering the potential use of additive manufacturing in life extension strategies. Specifically, a system dynamics model is developed to assess different end-of-life scenarios. Finally, an optimization problem is formulated and solved to minimize lifecycle cost with respect to design variables related to remanufacturing
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Ferroelastic Control of the Multicolor Emission from a Triply Doped Organic Crystal.
Emission from crystalline organic solids is often quenched by nonemissive energy-transfer deexcitation processes. While dispersion of fluorophores in polymers or other hosts has been used to enhance the emission intensity, this strategy results in randomization of guest orientation and optical losses at grain boundaries. Here, we report the doping of inherently nonemissive single crystals of anilinium bromide with three fluorescent organic molecules. The doping process equips the crystal with emission characteristics that tune from blue to deep orange. The emission intensity can be reversibly modulated by ferroelastic twinning, which causes the material to function as a multiemissive force sensor. This approach opens up new pathways in the manipulation of emissive properties in organic crystals and may have substantial implications for optoelectronic devices and sensors
Efficient occlusion of oil droplets within calcite crystals
It is well known that oil and water do not mix. Similarly, the incorporation of oil droplets within inorganic crystals is highly counter-intuitive because there is a large difference in surface energy for these two components. Nevertheless, herein we demonstrate the efficient occlusion of ∼250–500 nm oil droplets within 20–40 μm calcite crystals. These droplets are stabilized using various amphiphilic poly(methacrylic acid)–poly(n-alkyl methacrylate) diblock copolymer emulsifiers. Both copolymer concentration and diblock compositions affect the extent of occlusion, with optimized conditions producing calcite crystals containing up to 11% oil by mass. Moreover, compressive forces exerted by the growing crystals cause significant deformation of the oil droplets during occlusion. In principle, this protocol enables the incorporation of water-insoluble dyes or hydrophobic nanoparticles within calcite, which is a cheap, naturally-occurring and environmentally-benign mineral. The single crystal nature of this host lattice ensures efficient retention of such guests, while lowering the solution pH leads to triggered release via acid dissolution
Optimization of Infectious Disease Prevention and Control Policies Using Artificial Life
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