The first all-sky view of the Milky Way stellar halo with Gaia+2MASS RR Lyrae

We exploit the first \gaia data release to study the properties of the Galactic stellar halo as traced by RR Lyrae. We demonstrate that it is possible to select a pure sample of RR Lyrae using only photometric information available in the Gaia+2MASS catalogue. The final sample contains about 21600 RR Lyrae covering an unprecedented fraction ($\sim60\%$) of the volume of the Galactic inner halo ($\text{R}<28$ kpc). We study the morphology of the stellar halo by analysing the RR Lyrae distribution with parametric and non-parametric techniques. Taking advantage of the uniform all-sky coverage, we test halo models more sophisticated than usually considered in the literature, such as those with varying flattening, tilt and/or offset of the halo with respect to the Galactic disc. A consistent picture emerges: the inner halo is well reproduced by a smooth distribution of stars settled on triaxial ellipsoids. The minor axis is perpendicular to the Milky Ways disc, while the major axis is misaligned by $\sim20^{\circ}$ from the Galactic Y axis. The elongation along the major axis is mild ($\text{p}=1.27$), and the vertical flattening is shown to evolve from a squashed state with $\text{q}\approx0.57$ in the centre to a more spherical $\text{q}\approx0.75$ at the outer edge of our dataset. The density slope is well approximated by a single power-law with exponent $\alpha=-2.96$. Within the range probed, we see no significant evidence for a change of the radial density slope, out of the plane tilt or an offset of the halo with respect to the Galaxy's centre.Comment: Accepted for publication in MNRA

A deeper look at the GD1 stream::density variations and wiggles

Using deep photometric data from CFHT/Megacam, we study the morphology and density of the GD-1 stream, one of the longest and coldest stellar streams in the Milky Way. Our deep data recovers the lower main sequence of the stream with unprecedented quality, clearly separating it from Milky Way foreground and background stars. An analysis of the distance to different parts of the stream shows that GD-1 lies at a heliocentric distance between 8 and 10 kpc, with only a shallow gradient across 45 deg on the sky. Matched filter maps of the stream density show clear density variations, such as deviations from a single orbital track and tentative evidence for stream fanning. We also detect a clear under-density in the middle of the stream track at $\varphi_{1}$=-45 deg surrounded by overdense stream segments on either side. This location is a promising candidate for the elusive missing progenitor of the GD-1 stream. We conclude that the GD-1 stream has clearly been disturbed by interactions with the Milky Way disk or other sub-halos.Comment: submitted to MNRAS, comments welcom

Dark Matter in the Milky Way's Dwarf Spheroidal Satellites

The Milky Way's dwarf spheroidal satellites include the nearest, smallest and least luminous galaxies known. They also exhibit the largest discrepancies between dynamical and luminous masses. This article reviews the development of empirical constraints on the structure and kinematics of dSph stellar populations and discusses how this phenomenology translates into constraints on the amount and distribution of dark matter within dSphs. Some implications for cosmology and the particle nature of dark matter are discussed, and some topics/questions for future study are identified.Comment: A version with full-resolution figures is available at http://www.cfa.harvard.edu/~mwalker/mwdsph_review.pdf; 70 pages, 22 figures; invited review article to be published in Vol. 5 of the book "Planets, Stars, and Stellar Systems", published by Springe

X-ray photoelectron spectroscopy characterization of composite TiO2–poly(vinylidenefluoride) films synthesised for applications in pesticide photocatalytic degradation

X-ray photoelectron spectroscopy (XPS) was adopted for the analytical characterization of composite titanium dioxide– poly(vinylidenefluoride) (TiO2–PVDF) films developed for applications in the photocatalytic degradation of pollutants. The composites were deposited on glass substrates by casting or spin coating from TiO2–PVDF suspensions in dimethylformamide (DMF). XPS data on the TiO2–PVDF surface composition were used to optimize preparation conditions (composition of the TiO2/PVDF suspension, deposition technique) in terms of titanium dioxide surface amount and film stability. The use of spin-coating deposition and the increase of TiO2 amount in the DMF suspensions were found to improve the titanium surface content, although high TiO2/PVDF ratios led to film instability. PVDF–TiO2 films were also used in preliminary photocatalytic degradation tests on isoproturon, a phenylurea herbicide, under solar UVirradiation; the results were compared to direct photolysis to evaluate the catalytic efficiency of immobilized TiO2 and the role played by the PVDF film during the degradation process

Simultaneous determination of phenyl- and sulfonyl-urea herbicides in river water at sub-parts-per-billion level by on-line preconcentration and liquid chromatography–tandem mass spectrometry

A method based on on-line preconcentration followed by liquid chromatography-electrospray ionization–tandem mass spectrometry (LCESI– MS/MS) was developed for the determination of three sulfonyl-urea (thifensulfuron, metsulfuron, chlorsulfuron) and two phenyl-urea (isoproturon and chlortoluron) herbicides in water at sub-ppb concentration ranges. Preconcentration was accomplished using on-line enrichment on a C18 cartridge; the procedure was optimized by an evaluation of the breakthrough volumes for the target analytes. Subsequently, LC-ESI–MS/MS was adopted for analytes separation and detection. In particular, a selective reaction monitoring (SRM) approach, based on the detection of a peculiar fragment for each analyte, was chosen for MS/MS analysis, in order to enhance selectivity. Normalization to the response of a phenyl-urea herbicide (chloroxuron), used as an internal standard, was also adopted to achieve a reproducibility enhancement. The described method was applied to the analysis of the target analytes in river water samples and LOD values ranging between 8 and 30 ppt were obtained