The Money or the Media? Lessons from Contrasting Developments in US and Australian Whistleblowing Laws

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Polydimethylsiloxane (PDMS)-based microfluidic channel with integrated commercial pressure sensors

The precise characterisation of boiling in microchannels is essential for the optimisation of applications requiring two phase cooling. In this paper polydimethylsiloxane (PDMS) is employed to make microchannels for characterising microboiling. In particular the material properties of PDMS facilitate rapid prototyping and its optical transparency provides the capability to directly view any fluid flow. The production of microchannels is complicated by the need to integrate custom made sensors. This paper presents a PDMS microfluidic device with integrated commercial pressure sensors, which have been used to perform a detailed characterisation of microboiling phenomena. The proposed approach of integrating commercial pressure sensors into the channel also has potential applications in a range of other microsystems

Cloud water interception and resilience of tropical montane bryophytes to climate change in cloud forests of La Reunion

Tropical montane cloud forests (TMCFs) are characterized by frequent cloud immersion, host a high diversity of global biodiversity and provide vital ecosystem services to insular populations. Climate change on islands, is expected to both raise the cloud height base as a result of temperature increase and to increase the frequency of extreme events like drought. Bryophytes contribute a significant biomass in these systems yet the role of cloud water and the resilience of bryophytes to drought in island TMCFs is still poorly known. In La Reunion, we implemented a novel method to follow cloud water interception by bryophytes in the TMCF using in situlysimeters. We showed that two abundant TMCF liverworts possess an excellent ability to intercept and store cloud water, and that stored water fluctuated according to climatic conditions. In order to better understand the ecophysiology of TMCF bryophytes, we examined chlorophyll fluorescence, under laboratory conditions, for 16 bryophyte species in response to dehydration and rehydration. This was accompanied by measurements of water retention capacity and relative water content of each species. Highest Water Retention Capacity and Relative Water Content were recorded for Sphagnumsp ( 2174 %: 91,37 %) and Anthocerossp ( 1540 %; 7815 %). Dry down curves showed that species with high water storage capacity are favored by maintaining longer optimal photosynthetic activity. After one week of desiccation, half of the species could recover 50 % of their optimal photosynthetic activity within 24 h of rehydration. Most species, after 7 weeks of desiccation, could not recover their original photosynthetic activity after rehydration. These experiments highlight the presence of various strategies for managing desiccation by TMCF bryophytes at the microhabitat level. Bryophytes inhabiting the TMCF, exhibit a strong strategy in either tolerance or drought avoidance or a combination of both strategies, indicating a better adaptation to drought than expected. However, impact of repetitive drought on the physiology of the TMCF species remains unknown. The multiplicity of responses recorded for TMCF bryophytes regarding their physiology and life forms indicate that climate change will have distinct impacts on species

A Hydrostratigraphic Framework for the Paleozoic Bedrock of Southern Ontario

Groundwater systems in the intermediate to deep subsurface of southern Ontario are poorly understood, despite their value for a number of societal uses. A regional hydrostratigraphic framework is a necessary precursor for improving our understanding of groundwater systems and enabling development of a 3-D hydrostratigraphic model to visualize these groundwater systems. This study is a compilation and integration of published and unpublished geological, hydrogeological, hydrochemical and isotopic data collected over the past 10 years to develop that framework.Bedrock is covered by a thin veneer of surficial sediments that comprise an aquifer/aquitard system of considerable local variability and complexity. Aquifers in the bedrock are thin and regionally extensive, separated by thick aquitards, within a well-defined lithostratigraphic framework and a well-developed hydrochemical depth zonation comprising a shallow fresh water regime, an intermediate brackish to saline sulphur water regime, and a deep brine regime of ancient, evaporated seawater. Occurrence and movement of groundwater in shallow bedrock is principally controlled by modern (Quaternary) karstic dissolution of subcropping carbonate and evaporite rocks, and in the intermediate to deep subsurface by paleokarst horizons developed during the Paleozoic. Flow directions in the surficial sediments of the shallow groundwater regime are down-gradient from topographic highs and down the regional dip of bedrock formations in the intermediate regime. Shallow karst is the entry point for groundwater penetration into the intermediate regime, with paleo-recharge by glacial meltwater and limited recent recharge by meteoric water at subcrop edges, and down-dip hydraulic gradients in confined aquifers. Hydraulic gradient is up-dip in the deep brine regime, at least for the Guelph Aquifer and the Cambrian Aquifer, with no isotopic or hydrochemical evidence of infiltration of meteoric water and no discharge to the surface.Fourteen bedrock hydrostratigraphic units are proposed, and one unit comprising all the surficial sediments. Assignment of lithostratigraphic units as hydrostratigraphic units is based principally on hydrogeological characteristics of Paleozoic bedrock formations in the intermediate to deep groundwater regimes, below the influence of modern meteoric water. Carbonate and evaporite rocks which form aquitards in the subsurface may form aquifers at or near the surface, due to karstic dissolution by acidic meteoric water, necessitating compromises in assignment of hydrostratigraphic units.Les systèmes d'eaux souterraines du sous-sol intermédiaire à profond du sud de l'Ontario sont mal compris, malgré leur valeur pour de nombreux usages par la société. Un cadre hydrostratigraphique régional est un préalable nécessaire à l’amélioration de notre compréhension des systèmes d'eaux souterraines et au développement d'un modèle hydrostratigraphique 3D pour visualiser ces systèmes d'eaux souterraines. Cette étude est une compilation et une intégration de données géologiques, hydrogéologiques, hydrochimiques et isotopiques publiées et non publiées recueillies au cours des 10 dernières années afin de développer ce cadre.Le substrat rocheux est recouvert d'un mince placage de sédiments de surface qui comprend un système d’aquifères et d’aquitards d'une variabilité et d'une complexité locales considérables. Les aquifères du substrat rocheux sont minces et étendus au niveau régional, séparés par des aquitards épais, dans un cadre lithostratigraphique bien défini et une zonation hydrochimique verticale bien développée comprenant un régime peu profond d'eau douce, un régime intermédiaire d'eau sulfureuse saumâtre à saline et un régime profond de saumure résultant de l’évaporation d'eau de mer ancienne. La présence et le mouvement des eaux souterraines dans le substrat rocheux peu profond sont principalement contrôlés par la dissolution karstique moderne (quaternaire) des roches carbonatées et évaporitiques sub-affleurantes, et dans le sous-sol intermédiaire à profond par les horizons paléokarstiques développés au Paléozoïque. Les directions d'écoulement des eaux dans les sédiments de surface du régime peu profond sont en aval des sommets topographiques et en aval du pendage régional des formations de substrat rocheux dans le régime intermédiaire. Le karst peu profond est le point d'entrée pour l’infiltration des eaux souterraines dans le régime intermédiaire, avec une paléo-recharge d'eau de fonte glaciaire et une recharge récente limitée d'eau météorique aux bords de sous-affleurement, et un gradient hydraulique en aval-pendage dans les aquifères confinés. Le gradient hydraulique est en amont-pendage dans le régime profond de saumure, au moins pour l'aquifère de Guelph et l'aquifère du Cambrien, sans indication isotopique ou hydrochimique d'infiltration d'eau météorique et sans déversement à la surface.Quatorze unités hydrostratigraphiques du substrat rocheux sont proposées, et une unité comprenant tous les sédiments de surface. L'attribution des unités lithostratigraphiques en tant qu’unités hydrostratigraphiques repose principalement sur les caractéristiques hydrogéologiques des formations du substrat rocheux du Paléozoïque dans les régimes intermédiaires à profonds des eaux souterraines, sous l'influence des eaux météoriques modernes. Les roches carbonatées et évaporitiques qui forment les aquitards dans le sous-sol peuvent former des aquifères à la surface ou près de la surface, en raison de la dissolution karstique par l'eau météorique acide, ce qui nécessite des compromis dans l'attribution des unités hydrostratigraphiques

Modification and characterisation of material hydrophobicity for surface acoustic wave driven microfluidics

Surface acoustic waves (SAW) generated in a piezoelectric substrate may be used to manipulate micro-scale droplets of liquid in a digital microfluidic system for lab-on-a-chip applications. The wettability of the surface over which a droplet is driven determines the ease and speed with which the droplet is propelled. This provides the opportunity to achieve fine control of SAW driven droplets simply by patterning of the surface into areas with different levels of wettability. This paper evaluates a number of different materials and surface preparation techniques and assesses their manufacturability and efficacy for this application. Test structures have been designed and developed to help optimise a fabrication process using the biocompatible polymer Parylene. Early results obtained using airflow as a driving force show that it is possible to manipulate droplets through direction changes of up to 60°. Additional work has been done using surface acoustic waves as the driving force to determine the extent to which droplets can be guided to desired locations

Fast versus gradual adaptation of soft daily disposable contact lenses in neophyte wearers

Purpose Despite the widespread practice of gradually adapting all new soft contact lens wearers (neophytes), there is little evidence-based research underpinning such practice. This work determined if a gradual adaptation period is necessary for neophytes when fitted with modern hydrogel or silicone-hydrogel daily disposable contact lenses. Method At four sites, neophytes (19–32 years) were randomly assigned to an adaptation schedule: fast (10 h wear from the first day) or gradual (4 h on the first day, increasing their wear-time by 2 h on each subsequent day until they had reached 10 h) with hydrogel (n = 24 fast; n = 21 gradual) or silicone-hydrogel (n = 10 fast; n = 10 gradual) contact lenses. Masked investigators graded ocular surface physiology and non-invasive tear breakup time (NIBUT). A range of subjective scores (using 0–100 visual analogue scales) were recorded at the initial visit and after 10 h of lens wear, 4–6 days and 12–14 days after initial fitting. Subjective scores were also repeated after 7 days. Results There was no difference (p > 0.05) in ocular surface physiology between the fast and gradual adaptation groups at any time point in either lens type. NIBUT was similar at all time points for both adaptation groups in both lens types with the exception that the gradual adaptation silicone-hydrogel wearers had a slightly longer NIBUT (p = 0.007) than the fast adaptation group at 12-14 days. Subjective scores were also similar across the visits and lens types with the exception of ‘lens awareness’ and ‘ease of lens removal’ which were better (p < 0.05) in the fast compared with the gradual adaptation hydrogel lens group at day 7. Additionally, ‘end-of-day discomfort’ was better (p = 0.02) in the fast compared with the gradual adaptation hydrogel lens group at 12–14 days. Conclusion There appears to be no benefit in daily disposable soft contact lens adaptation for neophytes with modern contact lens materials