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Nanodielectics (A "Universal" Panacea for Solving All Electrical Insualation Problems?)
This text summarizes the keynote presentation that is based on the full-length paper of the same title. Dr. FreÌchette's oral presentation should not be seen as a summary of the âBrainstorm paperâ but a glance at some major accomplishments, hinrances and still remaining questions relative to nanodielectrics. Are nanodielectrics a âuniversalâ panacea? The answer to that question is no - but they've got a lot of potential
Application of operando X-ray diffraction and Raman spectroscopies in elucidating the behavior of cathode in lithium-ion batteries
With the advances in characterization techniques, various operando/in-situ methods were applied in studying rechargeable batteries in order to improve the electrochemical properties of electrode materials, prolonging the battery life and developing new battery materials. In the present review, we focus on the characterization of electrode materials with operando/in-situ X-ray diffraction and Raman spectroscopies. By correlating the results obtained via these two techniques in different electrode chemistry: (a) intercalation materials, such as layered metal oxides and (b) conversion materials, such as elemental sulfur. We demonstrate the importance of using operando/in-situ techniques in examining the microstructural changes of the electrodes under various operating conditions, in both macro and micro-scales. These techniques also reveal the working and the degradation mechanisms of the electrodes and the possible side reactions involved. The comprehension of these mechanisms is fundamental for ameliorating the electrode materials, enhancing the battery performance and lengthening its cycling life
The Red Rectangle: Its Shaping Mechanism and its Source of Ultraviolet Photons
The proto-planetary Red Rectangle nebula is powered by HD 44179, a
spectroscopic binary (P = 318 d), in which a luminous post-AGB component is the
primary source of both luminosity and current mass loss. Here, we present the
results of a seven-year, eight-orbit spectroscopic monitoring program of HD
44179, designed to uncover new information about the source of the
Lyman/far-ultraviolet continuum in the system as well as the driving mechanism
for the bipolar outflow producing the current nebula. Our observations of the
H-alpha line profile around the orbital phase of superior conjunction reveal
the secondary component to be the origin of the fast (max. v~560^{-1}\sun_{max} \ge 17,0002 -
5\times10^{-5}\sun^{-1}\sun$, about 5% of the
luminosity of the entire system. (abridged)Comment: Accepted for publication in Ap
Mid-IR period-magnitude relations for AGB stars
Asymptotic Giant Branch variables are found to obey period-luminosity
relations in the mid-IR similar to those seen at K_S (2.14 microns), even at 24
microns where emission from circumstellar dust is expected to be dominant.
Their loci in the M, logP diagrams are essentially the same for the LMC and for
NGC6522 in spite of different ages and metallicities. There is no systematic
trend of slope with wavelength. The offsets of the apparent magnitude vs. logP
relations imply a difference between the two fields of 3.8 in distance modulus.
The colours of the variables confirm that a principal period with log P > 1.75
is a necessary condition for detectable mass-loss. At the longest observed
wavelength, 24 microns, many semi-regular variables have dust shells comparable
in luminosity to those around Miras. There is a clear bifurcation in LMC
colour-magnitude diagrams involving 24 micron magnitudes.Comment: 5 pages, 4 figure
The Excitation of Extended Red Emission: New Constraints on its Carrier From HST Observations of NGC 7023
The carrier of the dust-associated photoluminescence process causing the
extended red emission (ERE) in many dusty interstellar environments remains
unidentified. Several competing models are more or less able to match the
observed broad, unstructured ERE band. We now constrain the character of the
ERE carrier further by determining the wavelengths of the radiation that
initiates the ERE. Using the imaging capabilities of the Hubble Space
Telescope, we have resolved the width of narrow ERE filaments appearing on the
surfaces of externally illuminated molecular clouds in the bright reflection
nebula NGC 7023 and compared them with the depth of penetration of radiation of
known wavelengths into the same cloud surfaces. We identify photons with
wavelengths shortward of 118 nm as the source of ERE initiation, not to be
confused with ERE excitation, however. There are strong indications from the
well-studied ERE in the Red Rectangle nebula and in the high-|b| Galactic
cirrus that the photon flux with wavelengths shortward of 118 nm is too small
to actually excite the observed ERE, even with 100% quantum efficiency. We
conclude, therefore, that ERE excitation results from a two-step process. While
none of the previously proposed ERE models can match these new constraints, we
note that under interstellar conditions most polycyclic aromatic hydrocarbon
(PAH) molecules are ionized to the di-cation stage by photons with E > 10.5 eV
and that the electronic energy level structure of PAH di-cations is consistent
with fluorescence in the wavelength band of the ERE. Therefore, PAH di-cations
deserve further study as potential carriers of the ERE. (abridged)Comment: Accepted for Publication in the Ap
Herschel Observations of a Newly Discovered UX Ori Star in the Large Magellanic Cloud
The LMC star, SSTISAGE1C J050756.44-703453.9, was first noticed during a
survey of EROS-2 lightcurves for stars with large irregular brightness
variations typical of the R Coronae Borealis (RCB) class. However, the visible
spectrum showing emission lines including the Balmer and Paschen series as well
as many Fe II lines is emphatically not that of an RCB star. This star has all
of the characteristics of a typical UX Ori star. It has a spectral type of
approximately A2 and has excited an H II region in its vicinity. However, if it
is an LMC member, then it is very luminous for a Herbig Ae/Be star. It shows
irregular drops in brightness of up to 2 mag, and displays the reddening and
"blueing" typical of this class of stars. Its spectrum, showing a combination
of emission and absorption lines, is typical of a UX Ori star that is in a
decline caused by obscuration from the circumstellar dust. SSTISAGE1C
J050756.44-703453.9 has a strong IR excess and significant emission is present
out to 500 micron. Monte Carlo radiative transfer modeling of the SED requires
that SSTISAGE1C J050756.44-703453.9 has both a dusty disk as well as a large
extended diffuse envelope to fit both the mid- and far-IR dust emission. This
star is a new member of the UX Ori subclass of the Herbig Ae/Be stars and only
the second such star to be discovered in the LMC.Comment: ApJ, in press. 9 pages, 5 figure
The Dust-to-Gas Ratio in the Small Magellanic Cloud Tail
The Tail region of the Small Magellanic Cloud (SMC) was imaged using the MIPS
instrument on the Spitzer Space Telescope as part of the SAGE-SMC Spitzer
Legacy. Diffuse infrared emission from dust was detected in all the MIPS bands.
The Tail gas-to-dust ratio was measured to be 1200 +/- 350 using the MIPS
observations combined with existing IRAS and HI observations. This gas-to-dust
ratio is higher than the expected 500-800 from the known Tail metallicity
indicating possible destruction of dust grains. Two cluster regions in the Tail
were resolved into multiple sources in the MIPS observations and local
gas-to-dust ratios were measured to be ~440 and ~250 suggests dust formation
and/or significant amounts of ionized gas in these regions. These results
support the interpretation that the SMC Tail is a tidal tail recently stripped
from the SMC that includes gas, dust, and young stars.Comment: 6 pages, 3 figures, ApJ Letters, in press, (version with full
resolution figures at
http://www.stsci.edu/~kgordon/papers/PS_files/sage-smc_taildust_v1.62.pdf
Understanding the Reactivity of a Thin Li1.5Al0.5Ge1.5(PO4)3 Solid-State Electrolyte toward Metallic Lithium Anode
The thickness of solid-state electrolytes (SSEs) significantly affects the energy density and safety performance of all-solid-state lithium batteries. However, a sufficient understanding of the reactivity toward lithium metal of ultrathin SSEs (<100 ”m) based on NASICON remains lacking. Herein, for the first time, a self-standing and ultrathin (70 ”m) NASICON-type Li1.5Al0.5Ge1.5(PO4)3 (LAGP) electrolyte via a scalable solution process is developed, and X-ray photoelectron spectroscopy reveals that changes in LAGP at the metastable LiâLAGP interface during battery operation is temperature dependent. Severe germanium reduction and decrease in LAGP particle size are detected at the LiâLAGP interface at elevated temperature. Oriented plating of lithium metal on its preferred (110) face occurs during in situ X-ray diffraction cycling
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