Mg isotope systematics during magmatic processes: Inter-mineral fractionation in mafic to ultramafic Hawaiian xenoliths

© 2018 Elsevier Ltd Observed differences in Mg isotope ratios between bulk magmatic rocks are small, often on a sub per mill level. Inter–mineral differences in the 26Mg/24Mg ratio (expressed as δ26Mg) in plutonic rocks are on a similar scale, and have mostly been attributed to equilibrium isotope fractionation at magmatic temperatures. Here we report Mg isotope data on minerals in spinel peridotite and garnet pyroxenite xenoliths from the rejuvenated stage of volcanism on Oahu and Kauai, Hawaii. The new data are compared to literature data and to theoretical predictions to investigate the processes responsible for inter–mineral Mg isotope fractionation at magmatic temperatures. Theory predicts up to per mill level differences in δ26Mg between olivine and spinel at magmatic temperatures and a general decrease in Δ26Mgolivine-spinel (=δ26Mgolivine – δ26Mgspinel) with increasing temperature, but also with increasing Cr# in spinel. For peridotites with a simple petrogenetic history by melt depletion, where increasing depletion relates to increasing melting temperatures, Δ26Mgolivine-spinel should thus systematically decrease with increasing Cr# in spinel. However, most natural peridotites, including the Hawaiian spinel peridotites investigated in this study, are overprinted by variable extents of melt-rock reaction, which disturb the systematic primary temperature and compositionally related olivine–spinel Mg isotope systematics. Diffusion, subsolidus re-equilibration, or surface alteration may further affect the observed olivine–spinel Mg isotope fractionation in peridotites, making Δ26Mgolivine-spinel in peridotites a difficult–to–apply geothermometer. The available Mg isotope data on clinopyroxene and garnet suggest that this mineral pair is a more promising geothermometer, but its application is restricted to garnet–bearing igneous (garnet pyroxenites) and metamorphic rocks (eclogites). Although the observed δ26Mg variation is on a sub per mill range in bulk magmatic rocks, the clearly resolvable inter–mineral Mg isotope differences imply that crystallization or preferential melting of isotopically distinct minerals such garnet, spinel, and clinopyroxene should cause Mg isotope fractionation between bulk melt and residue. Calculated Mg isotope variations during partial mantle melting indeed predict differences between melt and residue, but these are analytically resolvable only for melting of mafic lithologies, that is, garnet pyroxenites. Contributions from garnet pyroxenite melts may thus account for some of the isotopically light δ26Mg observed in ocean island basalts and trace lithological mantle heterogeneity. Consequently, applications for high-temperature Mg isotope fractionations are promising and diverse, and recent advances in analytical precision may allow the full petrogenetic potential inherent in the sub per mill variations in δ26Mg in magmatic rocks to be exploited

The habitability of a stagnant-lid Earth

Plate tectonics is a fundamental component for the habitability of the Earth. Yet whether it is a recurrent feature of terrestrial bodies orbiting other stars or unique to the Earth is unknown. The stagnant lid may rather be the most common tectonic expression on such bodies. To understand whether a stagnant-lid planet can be habitable, i.e. host liquid water at its surface, we model the thermal evolution of the mantle, volcanic outgassing of H$_2$O and CO$_2$, and resulting climate of an Earth-like planet lacking plate tectonics. We used a 1D model of parameterized convection to simulate the evolution of melt generation and the build-up of an atmosphere of H$_2$O and CO$_2$ over 4.5 Gyr. We then employed a 1D radiative-convective atmosphere model to calculate the global mean atmospheric temperature and the boundaries of the habitable zone (HZ). The evolution of the interior is characterized by the initial production of a large amount of partial melt accompanied by a rapid outgassing of H$_2$O and CO$_2$. At 1 au, the obtained temperatures generally allow for liquid water on the surface nearly over the entire evolution. While the outer edge of the HZ is mostly influenced by the amount of outgassed CO$_2$, the inner edge presents a more complex behaviour that is dependent on the partial pressures of both gases. At 1 au, the stagnant-lid planet considered would be regarded as habitable. The width of the HZ at the end of the evolution, albeit influenced by the amount of outgassed CO$_2$, can vary in a non-monotonic way depending on the extent of the outgassed H$_2$O reservoir. Our results suggest that stagnant-lid planets can be habitable over geological timescales and that joint modelling of interior evolution, volcanic outgassing, and accompanying climate is necessary to robustly characterize planetary habitability

A standardised PRISMA-based protocol for systematic reviews of the scientific literature on Artificial Intelligence and education (AI&ED)

By using standardised approaches, systematic reviews of the educational, scientific literature can inform educational research and influence educational policies and practices. However, the various systematic reviews of the scientific literature in the field of Artificial Intelligence (AI) and education all adopt individual approaches, making it challenging to systematically compare their conclusions. Accordingly, this paper presents a standardised protocol for conducting systematic reviews of the scientific literature on AI and education (AI&ED), including both literature on teaching and learning with AI (AIED) and literature on teaching and learning about AI (AI literacy). Our protocol applies the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines and is presented here for the purpose of replication and validation. We exemplify our protocol by means of a systematic review of the scientific literature on trustworthy and ethical AI&ED, which was undertaken iteratively in symbiosis with the development of the protocol, informing each other throughout. In the future, we intend to apply our novel protocol for other search terms of relevance to AI&ED, as well as for the same search terms over a longer time period, in order to allow comparisons and the exploration of trends

Channelized melt flow in downwelling mantle: Implications for 226Ra-210Pb disequilibria in arc magmas

We present the results of an analytical model of porous flow of viscous melt into a steadily dilating ‘‘channel’’ (defined as a cluster of smaller veins) in downwelling subarc mantle. The model predicts the pressure drop in the mantle wedge matrix surrounding the channel needed to drive melt flow as a function of position and time. Melt is sucked toward the dilatant region at a near-constant velocity (105 s1) until veins comprising the channel stop opening (t = t). Fluid elements that complete their journey within the time span t < t arrive at a channel. Our results make it possible to calculate the region of influence sampled by melt that surrounds the channel. This region is large compared to the model size of the channelized region driving flow. For a baseline dilation time of 1 year and channel half width of 2 m, melt can be sampled over an 80-m radius and has the opportunity to sample matrix material with potentially contrasting chemistry on geologically short timescales. Our mechanical results are consistent with a downgoing arc mantle wedge source region where melting and melt extraction by porous flow to a channel network are sufficiently rapid to preserve source-derived 238U-230Th-226Ra, and potentially also 226 Ra-210Pb, disequilibria, prior to magma ascent to the surface. Since this is the rate-determining step in the overall process, it allows the possibility that such short-lived disequilibria measured in arc rocks at the surface are derived from deep in the mantle wedge. Stresses due to partial melting do not appear capable of producing the desired sucking effect, while the order of magnitude rate of shear required to drive dilation of 107 s1 is much larger than values resulting from steady state subduction. We conclude that local deformation rates in excess of background plate tectonic rates are needed to ‘‘switch on’’ the dilatant channel network and to initiate the sucking effect

Petrogenesis of synorogenic high-temperature leucogranites (Damara orogen, Namibia): Constraints from U–Pb monazite ages and Nd, Sr and Pb isotopes

Highlights: • Geochemical data from high-T leucogranites imply pure crustal melting. • New U–Pb monazite ages constrain intrusion time close to peak metamorphism. • Updated Sr–Nd–Pb isotope data imply metasedimentary sources. Two suites of leucogranites were emplaced at 508 ± 5.9 Ma in the Okombahe District of the Damara belt (Namibia) synchronous with the peak of regional high-temperature metamorphism. The Sr (87Sr/86Srinit: 0.707 to 0.711), Nd (εNdinit: − 4.5 to − 6.6), and Pb isotopic (206Pb/204Pb: 18.51–19.13; 207Pb/204Pb: 15.63–15.69; 208Pb/204Pb: 38.08–38.66) compositions indicate that these peraluminous S-type granites were derived from mid- to lower-crustal rocks, which are slightly different to the metapelitic rocks into which they intruded. Since the leucogranites are unfractionated and show no evidence for assimilation or contamination, they constrain the temperature and pressure conditions of their formation. Calculated Zr and LREE saturation temperatures of ca. 850 °C indicate high-temperature crustal melts. High Rb/Sr and low Sr/Ba ratios are consistent with biotite dehydration melting of pelitic source rocks. Qz–Ab–Or systematics reveal that melting and segregation for the least fractionated samples occurred at ca. 7 kbar corresponding to a mid-crustal level of ca. 26 km. However, there is no evidence for a mantle component that could have served as a local heat source for crustal melting. Therefore, the hot felsic magmas that formed close to the time of peak metamorphism are the result of long-lasting high temperature regional metamorphic conditions and intra-crustal collision

The extrasolar planet Gliese 581 d: a potentially habitable planet? (Corrigendum to arXiv:1009.5814)

We report here that the equation for H2O Rayleigh scattering was incorrectly stated in the original paper [arXiv:1009.5814]. Instead of a quadratic dependence on refractivity r, we accidentally quoted an r^4 dependence. Since the correct form of the equation was implemented into the model, scientific results are not affected.Comment: accepted to Astronomy&Astrophysic

The Quality Reference Framework for MOOC Design

This paper introduces "The Quality Reference Framework (QRF) for the Quality of MOOCs". It was developed by the European Alliance for the Quality of Massive Open Online Courses (MOOCs), called MOOQ that could involve in the QRF finalization more than 10,000 MOOC learners, designers, facilitators and providers. The QRF consists of three dimensions: Phases, Perspectives and Roles. It includes two quality instruments: the QRF Key Quality Criteria for MOOC experts and QRF Quality Checklist for MOOC beginners

Bestimmung der ernährungsphysiologischen Qualität von Öko-Produkten anhand des antioxidativen Potentials der Lebensmittel

Problemstellung: Die Diskussionen über sichere Lebensmittel (u.a. Rückstände von Pestiziden) im letzten Jahrzehnt hat das Verbraucherverhalten verändert. Viele Verbraucher bevorzugen ökologisch erzeugte Lebensmittel. Allerdings gibt es bis heute noch nicht ausreichende wissenschaftliche Daten dazu, ob ökologisch erzeugte Lebensmittel tatsächlich ernährungsphysiologisch hochwertiger sind als konventionell produzierte. Sekundären Pflanzenstoffen aus Obst und Gemüse (Carotinoiden, Polyphenole) kommt im Allgemeinen eine hohe gesundheitliche Bedeutung zu. Die in der Literatur beschriebenen protektiven Effekte auf entzündliche, atherosklerotische und tumorigene Prozesse werden u.a. auf ihr antioxidatives Potenzial zurückgeführt. Ziel der Studie war es daher zu untersuchen, ob sich der Gehalt an Carotinoiden und Polyphenolen und die antioxidative Kapazität in Lebensmitteln aus konventionellem und ökologischem Anbau unterscheidet. Darüber hinaus wurden drei humane Interventionsstudien durchgeführt, die klären sollten, ob die unterschiedlichen Anbauvarianten (ökologisch/konventionell) Einfluss auf die Bioverfügbarkeit der sekundären Pflanzenstoffe und den antioxidativen Status in vivo haben. Methodik: Im Rahmen des Projektes wurden Äpfel, Karotten und Weizenvollkorn der Erntejahre 2004, 2005 und 2006 aus kontrollierten Anbauversuchen untersucht. Die Gehalte an sekundären Pflanzenstoffen in vitro und in vivo wurden mittels HPLC/DAD/MS quantifiziert. Die antioxidativen Kapazitäten in vivo und in vitro wurden mit drei unterschiedlichen Testsystemen analysiert. Ergebnisse: Die Ergebnisse zeigen, dass die Anbauweise (ökologisch/konventionell) die Bildung von sekundären Pflanzenstoffen und das antioxidatives Potenzial in den untersuchten Lebensmitteln beeinflussen kann. Für die Öko-Produkte kann ein leicht höherer Gehalt und antioxidatives Potenzial bestimmt werden. In den durchgeführten Humanstudien, konnten keine Unterschiede in der Bioverfügbarkeit von Carotinoiden und Polyphenolen zwischen ökologisch und konventionell angebauten Äpfeln bzw. Karotten gezeigt werden. Schlussfolgerung: Die beobachteten Unterschiede im Gehalt an sekundären Pflanzenstoffen sowie im antioxidativen Potenzial zwischen den Anbauweisen sind klein und besitzen geringe ernährungsphysiologische Relevanz

Ancient refractory asthenosphere revealed by mantle re-melting at the Arctic Mid Atlantic Ridge

The upper mantle is a heterogeneous mixture of refractory and recycled crustal domains. The recycled portions, more fertile and thus preferentially melted, dominate the composition of the basalts erupted on the surface, whereas the imprint of melting of the refractory counterparts is more difficult to discern from the basalt chemistry. Contrasting radiogenic isotopic signatures of mid-ocean ridge basalts and oceanic mantle, however, show that Hf isotope ratios may provide hints for melting of refractory source materials despite ubiquitous magma mixing during ascent and stalling in the crust. This property may allow identifying contributions from depleted mantle materials unseen in other isotope systematics in basalts. Here, we show that basalts from Mohns and Knipovich ridges, two >500-km long oblique super-segments in the Arctic Atlantic, have distinctly high Hf isotope ratios, not mirrored by comparatively high Nd and low Sr and Pb isotope ratios. These compositions can be explained if a highly depleted asthenospheric mantle melts beneath this section of the Arctic Mid Atlantic Ridge. We argue that this depleted source consists of high proportions of ancient (>1 Ga), ultra-depleted mantle, previously drained of enriched components before being re-melted in its current location following a recent ridge-jump, allowing the identification of ultra-depleted mantle components in the arctic subridge mantle

Sind Bio-Äpfel gesünder?

Viele Verbraucher, die sich beim Kauf von Lebensmitteln für Bioprodukte entscheiden, erhoffen sich davon gesundheitsfördernde Effekte. Allerdings liegen bis heute noch nicht genügend wissenschaftliche Daten vor, um ökologisch und konventionell erzeugte Lebensmittel vergleichend ernährungsphysiologisch bewerten zu können. Am Institut für Ernährungsphysiologie der Bundesforschungsanstalt für Ernährung und Lebensmittel (BfEL) wird zurzeit untersucht, ob sich verschiedene pflanzliche Lebensmittel aus ökologischer und konventioneller Anbauweise hinsichtlich ihres Gehaltes an sekundären Pflanzenstoffen und deren ernährungsphysiologischer Wirkung am Menschen unterscheiden