Imaging the essential role of spin-fluctuations in high-Tc superconductivity

We have used scanning tunneling spectroscopy to investigate short-length electronic correlations in three-layer Bi2Sr2Ca2Cu3O(10+d) (Bi-2223). We show that the superconducting gap and the energy Omega_dip, defined as the difference between the dip minimum and the gap, are both modulated in space following the lattice superstructure, and are locally anti-correlated. Based on fits of our data to a microscopic strong-coupling model we show that Omega_dip is an accurate measure of the collective mode energy in Bi-2223. We conclude that the collective mode responsible for the dip is a local excitation with a doping dependent energy, and is most likely the (pi,pi) spin resonance.Comment: 4 pages, 4 figure

Optical shield: measuring viscosity of turbid fluids using optical tweezers

The viscosity of a fluid can be measured by tracking the motion of a suspended micron-sized particle trapped by optical tweezers. However, when the particle density is high, additional particles entering the trap compromise the tracking procedure and degrade the accuracy of the measurement. In this work we introduce an additional Laguerre–Gaussian, i.e. annular, beam surrounding the trap, acting as an optical shield to exclude contaminating particles

First direct observation of the Van Hove singularity in the tunneling spectra of cuprates

In two-dimensional lattices the electronic levels are unevenly spaced, and the density of states (DOS) displays a logarithmic divergence known as the Van Hove singularity (VHS). This is the case in particular for the layered cuprate superconductors. The scanning tunneling microscope (STM) probes the DOS, and is therefore the ideal tool to observe the VHS. No STM study of cuprate superconductors has reported such an observation so far giving rise to a debate about the possibility of observing directly the normal state DOS in the tunneling spectra. In this study, we show for the first time that the VHS is unambiguously observed in STM measurements performed on the cuprate Bi-2201. Beside closing the debate, our analysis proves the presence of the pseudogap in the overdoped side of the phase diagram of Bi-2201 and discredits the scenario of the pseudogap phase crossing the superconducting dome.Comment: 4 pages, 4 figure

Effect of Disorder on Ultrafast Exciton Dynamics Probed by Single Molecule Spectroscopy

We present a single-molecule study unraveling the effect of static disorder on the vibrational-assisted ultrafast exciton dynamics in multichromophoric systems. For every single complex, we probe the initial exciton relaxation process by an ultrafast pump-probe approach and the coupling to vibrational modes by emission spectra, while fluorescence lifetime analysis measures the amount of static disorder. Exploiting the wide range of disorder found from complex to complex, we demonstrate that static disorder accelerates the dephasing and energy relaxation rate of the exciton

Responsive glyco-poly(2-oxazoline)s: synthesis, cloud point tuning, and lectin binding

A new sugar-substituted 2-oxazoline monomer was prepared using the copper-catalyzed alkyne-azide cycloaddition (CuAAC) reaction. Its copolymerization with 2-ethyl-2-oxazoline as well as 2-(dec-9-enyl)-2-oxazoline, yielding well-defined copolymers with the possibility to tune the properties by thiol-ene "click" reactions, is described. Extensive solubility studies on the corresponding glycocopolymers demonstrated that the lower critical solution temperature behavior and pH-responsiveness of these copolymers can be adjusted in water and phosphate-buffered saline (PBS) depending on the choice of the thiol. By conjugation of 2,3,4,6-tetra-O-acetyl-1-thio-beta-D-glucopyranose and subsequent deprotection of the sugar moieties, the hydrophilicity of the copolymer could be increased significantly, allowing a cloud-point tuning in the physiological range. Furthermore, the binding capability of the glycosylated copoly(2-oxazoline) to concanavalin A was investigated

Editorial

‘A new spring, and a new sound’, so begins a famous Dutch poem. Will the birds sing differently, as the poet wishes in the next line? BKI, now 178 years old—surely one of the longest-running journals of Southeast Asian studies in the world, and known around its original home, the KITLV (Royal Institute), as ‘the Old Dame’—starts 2022 with a remarkable new development. For this reason, the first issue of the year opens with an Editorial. After generations of sound and steady editing under the direction of two scholars, one in the role of Chief Editor and one as Managing Editor, from now on, BKI will be run by an expanded editorial team of seven scholars drawn both from the geographical region, Southeast Asia, and the disciplines in the humanities and social sciences that BKI is dedicated to examining..

The Density of States in High-Tc Superconductors Vortices

We calculated the electronic structure of a vortex in a pseudogapped superconductor within a model featuring strong correlations. With increasing strength of the correlations, the BCS core states are suppressed and the spectra in and outside the core become similar. If the correlations are short-range, we find new core states in agreement with the observations in YBaCuO and BiSrCaCuO. Our results point to a common phenomenology for these two systems and indicate that normal-state correlations survive below Tc without taking part in the overall phase coherence.Comment: REVTeX 4, 5 pages, 2 EPS figures. Some changes to the text; new figures; references update

Genetically improved dual-purpose cowpea. Assessment of adoption and impact in the dry savannah of West Africa

The research reported here has the potential for contributing to a real improvement in the livelihoods of mixed crop-livestock farming households in the dry savannah zone of West Africa through widespread uptake of improved dual-purpose cowpea (IDPC). This technology offers opportunities for the production of more, higher-quality food for poor people and fodder for animals, along with soil-fertility improvement and other social benefits. The study examines issues surrounding the adoption and impact of the new varieties and associated management strategies. A novel approach was taken, combining GIS, a crop model, and household, community and participatory research approaches in northern Nigeria in order to address the following questions: `What types of impact are expected and their magnitude, where is the impact most likely to be felt, and by whom?'. The results suggest that the research investment has been beneficial, and the expected returns are high. Furthermore, the steps taken in order to quantify the benefits versus the costs of this research have identified for researchers, policy makers and development practitioners important considerations and possibilities for speeding up and widening the impact of this technology. First, it is a flexible technology that is appreciated by, and will have the greatest impact on, farming households that are usually poor and living in remoter areas where improved crop and livestock production are especially critical to livelihood strategies. Although the wealthiest households are more likely to be adopters, poorer households have also taken up IDPC. As it is the poorer households that cultivate 75% of the arable land, the potential impact of extending the technology to these more rural, less market-oriented households is huge. Uptake to date has been more likely to occur near wholesale markets in the most densely populated areas. Thus, finding innovative ways to increase access to markets and provide improved seeds and information for farmers in low-population density areas may have potentially large payoffs. The benefit from investment in rural market infrastructure and roads will be reflected in increased uptake of natural-resource-enhancing technologies such as IDPC. Farmer-impact workshops were held and the results pointed towards environmental- and poverty-impact indicators that can be monitored as people experiment with, and adapt, the new varieties and associated management techniques. The study has highlighted opportunities relating to the identification of the benefits of IDPC for livestock which are likely to emerge when data from several years of ongoing integrated crop-livestock trials become available. Given the population, climatic and land-use changes that are likely to occur in West Africa in the coming decades, there is an onus on researchers to streamline the effectiveness of R&D activities so that they benefit the rapidly increasing numbers of poor people in the region. The lessons learnt from the impact assessment study reported here will have much broader applicability in the future than to cowpea research alone. It is hoped that this analysis provides a research and impact-assessment strategy that will be useful for other crops and technologies, and in particular that it provides guidelines for assessments of more integrated natural resource management strategies (including livestock) and technologies. Most importantly, the novel multidisciplinary, multicentre and participatory approaches taken by the cowpea research team are helping to close the researcher-farmer feedback loop. Ultimately this is what will lead to faster and more widespread adoption and impact of new technologies

Determination of the Coherence Length and the Cooper-Pair Size in Unconventional Superconductors by Tunnelling Spectroscopy

The main purpose of the paper is to discuss a possibility of the determination of the values of the coherence length and the Cooper-pair size in unconventional superconductors by using tunnelling spectroscopy. In the mixed state of type-II superconductors, an applied magnetic field penetrates the superconductor in the form of vortices which form a regular lattice. In unconventional superconductors, the inner structure of a vortex core has a complex structure which is determined by the order parameter of the superconducting state and by the pairing wavefunction of the Cooper pairs. In clean superconductors, the spatial variations of the order parameter and the pairing wavefunction occur over the distances of the order of the coherence length and the Cooper-pair size, respectively. Therefore, by performing tunnelling spectroscopy along a line passing through a vortex core, one is able, in principle, to estimate the values of the coherent length and the Cooper-pair size.Comment: 13 pages, including 17 figure

Spatial distribution of beef cattle on a New Zealand hill country farm: monitoring the use of streams and wet areas

Grazing livestock are an important source of contamination of freshwater, particularly when they have direct access to streams. Cattle in particular contribute to riparian habitat deterioration through stream bank destruction and direct defecation and urination in streams. Exclusion of stock or planting of riparian areas, are the most common catchment management methods used to protect waterways. Given the relatively low returns from beef and sheep farming, both of these strategies are very expensive and often logistically prohibitive in steep hill county landscapes. Despite this, policy trends indicate that fencing of streams in agricultural catchments may become mandatory in the future. It is important that we understand how much time cattle spend in and around hill country streams and wet areas (wetlands and hill side seeps), in order to quantify the likely environmental benefits from such policies. The current study examined cattle movement data obtained using Global Positioning System (GPS) collars from experiments undertaken at Massey University’s hill country research farm, Tuapaka, near Palmerston North, to investigate the amount of time cattle spent in and around streams and wet areas. Animal movement data were collected over seven grazing events, in three winter periods (2012, 2013 and 2015). Permanent streams and wet areas were identified using a digital elevation model derived from 1m LiDAR data, aerial RGB images and RTK measurements. Cattle spent 3.3 – 6% (48 – 86 min/day) of their day in streams and wet areas consistently across the 7 data collections. Cattle spent more time in streams and wet areas during the afternoon. There are differences in the median amount of time individual animals spend in non-risk areas. Further research is necessary to evaluate how we can influence the amount of time cattle spend in riparian areas on hill country and how stream bank behaviour varies at different times of the year