Gold Nucleation Inhibition by Halide Ions: a Basis for a Seed-Mediated Approach

In the present work, we examine the effect of halide ions on gold nucleation, a typical synthetic variable in the wet-chemical production of gold nanostructures. It was found that the homogeneous nucleation of gold by the chemical reduction of aqueous gold ions is kinetically quenched by an increase in the concentration of halide ions, and this effect grows stronger as the Au–halide complex stability increases. The nucleation quenching is not exclusively related to a specific reducing agent, but appears to be a more general behavior, and is affected by the pH of the media. While no nucleation is observed, Au(I) metastable species coexist together with the reducer, constituting metastable solutions. It is demonstrated that nucleation inhibition by halide ions can be employed as a basis for a seed-mediated approach to produce gold nanostructures. The metastable solutions are proved to function as growth baths, where Au(I) reduction is triggered on the surface of previously synthesized gold nanoparticles, driving their growth in the absence of secondary nucleation. It is also shown how, with this approach, the synthesis conditions can be rationally designed to obtain gold nanoparticles with the desired properties in a controlled and reproducible fashion.Fil: Moiraghi, Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Douglas Gallardo, Oscar Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Coronado, Eduardo A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Macagno, Vicente Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Perez, Manuel Alejo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentin

Synchronization in a ring of pulsating oscillators with bidirectional couplings

We study the dynamical behavior of an ensemble of oscillators interacting through short range bidirectional pulses. The geometry is 1D with periodic boundary conditions. Our interest is twofold. To explore the conditions required to reach fully synchronization and to invewstigate the time needed to get such state. We present both theoretical and numerical results.Comment: Revtex, 4 pages, 2 figures. To appear in Int. J. Bifurc. and Chao

Agilidad, flexibilidad de producción e innovación en la empresa manufacturera española

Este artículo analiza en una muestra de empresas manufactureras españolas la relación de la producción ágil con el esfuerzo interno y la cooperación externa en innovación tecnológica. Los resultados del estudio indican que las empresas con mayor capacidad de agilidad utilizan con más intensidad un amplio conjunto de tecnologías agiles de desarrollo, fabricación y suministro. Las empresas más ágiles también cooperan externamente más en innovación y dicha cooperación modera la flexibilidad de producción de las empresas, indicando con ello que, gracias a la cooperación externa en innovación las empresas con menor flexibilidad de producción pueden aun así conseguir mayor capacidad de agilidad

Aportaciones a la flora de Andalucía.

New data on the Andalusian flora. Palabras clave. Papaver, Erica, Convolvulus, Teucrium, flora, corología, Andalucía, España.Key words. Papaver, Erica, Convolvulus, Teucrium, flora, chorology, Andalusia, Spain

Criticalidade auto-organizada no cerrado? Invariância escalar dos padrões texturais e espectrais de fitosionomias do cerrado paulista.

Padrões presentes em uma paisagem podem estar associados importantes processos relativos à organização e dinâmica do sistema. Objetivo: O objetivo do presente trabalho foi avaliar, a partir de algumas métricas derivadas do paradigma da complexidade, a complexidade dos padrões texturais e espectrais de fisionomias do Cerrado paulista a fim de verificar quais propriedades relativas à sua organização e dinâmica tais padrões podem revelar. Metodologia: Para tanto, imagens do sensor Aster de três unidades de conservação do estado de São Paulo foram analisadas, utilizando-se dois tipos de medidas (dimensão fractal e medidas baseadas na entropia informacional) para avaliar a complexidade dos padrões texturais e espectrais das fisionomias. Resultados e discussão: Todas as fisionomias, nas três localidades estudadas e para todas as medidas usadas, apresentarem em diversas ocasiões a ocorrência de padrões texturais e espectrais que se repetem em diferentes escalas. A principal implicação desses resultados diz respeito às inferências sobre a dinâmica do Cerrado: a invariância escalar é uma característica marcante de sistemas que se desenvolvem longe do equilíbrio. Mais do que isso, é um grande indicativo de que o sistema pode apresentar criticalidade auto-organizada.Edição especia

Suplementación de raciones para cebo intensivo de terneros con aceites vegetales: rendimientos productivos, calidad de la canal, de la grasa y de la carne

Se han estudiado los efectos de la incorporación de aceites de origen vegetal sobre los rendimientos productivos, calidad de la canal y de la grasa en el ganado vacuno. Se utilizaron 240 terneros agrupados en 24 lotes de 10 terneros cada uno. Las raciones experimentales fueron: Tratamiento Control (4% de aceite de palma), Oliva (4,8% de jabón cálcico de aceite de oliva), Soja (4% de aceite de soja). De cada lote se seleccionó al azar un ternero (8 terneros por tratamiento) para diseccionar su 6ª costilla. No se han observado diferencias significativas entre tratamientos para ningún parámetro productivo ni de calidad de la canal. Los animales que consumieron aceite de oliva presentaron un mayor contenido (P=0,09) en C18:2 cis-9, trans-11 CLA en la grasa intramuscular que los que consumieron palma

Suplementación de raciones para cebo intensivo de terneros con aceites vegetales: calidad de carne

Se han estudiado los efectos de la incorporación de aceites de origen vegetal sobre la calidad de carne en el ganado vacuno. Se utilizaron 240 terneros agrupados en 24 lotes de 10 terneros cada uno. Las raciones experimentales fueron: Tratamiento Control (4% de aceite de palma), Oliva (4,8% de jabón cálcico de aceite de oliva), Soja (4% de aceite de soja). De cada lote se seleccionó al azar un ternero (8 terneros por tratamiento) para diseccionar su 6ª costilla. Se tomaron medidas de pH, color y textura del músculo Longissimus dorsi. Por último se realizó un análisis sensorial mediante un panel de catadores en el que se analizaron los parámetros de olor, textura y flavor de la carne. La carne de los animales alimentados con aceite de palma (Control) presentó el valor más alto (P0,05). En el análisis sensorial de la carne no se han observado diferencias significativas en los parámetros estudiados

A moment based approach to the dynamical solution of the Kuramoto model

We examine the dynamics of the Kuramoto model with a new analytical approach. By defining an appropriate set of moments the dynamical equations can be exactly closed. We discuss some applications of the formalism like the existence of an effective Hamiltonian for the dynamics. We also show how this approach can be used to numerically investigate the dynamical behavior of the model without finite size effects.Comment: 6 pages, 5 figures, Revtex file, to appear in J. Phys.

Assessment of complexity metrics applied to analysis of spectral patterns generated by aster sensor.

Landscape metrics are traditionally used in the analysis and search for spatial patterns in complex environmental systems through of establishing numeric relationships between different types of targets on Earth's surface. Under this perspective, remote sensing has had great importance as a tool for data generation, providing several levels of land use and occupancy information isonomically for large areas. For that purpose, remote sensing uses regular pixel matrices (Picture Element) with associated quantitative values (e.g. digital numbers, radiance, reflectance) which constitute a direct measurement of the variation of electromagnetic radiation (EMR) after interaction with the target. The variations in pixel values may be considered in terms of their textural patterns, regarding pixel neighborhood relationships, or spectral patterns, when EMR variations are considered along different wavelengths for a same pixel. Thus, the objective of this work was to assess the results of spectral measurements to different area extensions in images taken by the ASTER sensor, which operates with 9 bands within the visible to shortwave infrared region (0.556 to 2.400 µm) and has a spatial resolution of 15 m. For this purpose, cerrado phytophysiognomies in two hillsides at Jataí Ecological Station, in the city of Luiz Antônio, northeast portion of the state of São Paulo, Brazil, were considered reference targets, and encompassed to its greatest extent the cerradão domain and also "campo sujo" and "cerrado strictu sensu" physiognomies. The metrics used for spectral analyses are based on information entropy: measure (SDL), in which most complexity values are associated to more disorderly patterns; and measure, LMC, which is represent by a convex entropy of function that attributes greater complexity values to patterns located in an intermediate zone between order and disorder. These measures was applied to values extracted from spectral response curve generated by a wavelength X reflectance graphic which represented the target's behavior in different bands of the electromagnetic spectrum. In this work, was used two bands (8 and 9) that emphasize important components of cerrado phytophysiognomies, as lignin and water cell. For each hillside, was analysed three positions: base, medium and top, and each of these position, two spatial scales (150x150m and 75x75m). The results shows that, when taken alone, any measure presented a consistent behavior when compared of different spatial scales and bands used. However, both measures show identical behavior to attribute greater and lesser values of complexity to different positions and spatial scale at the same hillside. This results appoint that its can be used in combined as complementary measures, demonstrating in case LMC measure ? heterogeneity degrees of spectral patterns analysed and, from SDL measure, your respective location along of continuum that have in your extremes, one side, more ordered condition (therefore, more homogeneous) and, in the other extremity, more disordered conditions