The Geometry of the Cholesteric Phase

We propose a construction of a cholesteric pitch axis for an arbitrary nematic director field as an eigenvalue problem. Our definition leads to a Frenet-Serret description of an orthonormal triad determined by this axis, the director, and the mutually perpendicular direction. With this tool we are able to compare defect structures in cholesterics, biaxial nematics, and smectics. Though they all have similar ground state manifolds, the defect structures are different and cannot be, in general, translated from one phase to the other.Comment: 5 pages, the full catastroph

Geometry of the cholesteric phase

We propose a construction of a cholesteric pitch axis for an arbitrary nematic director field as an eigenvalue problem. Our definition leads to a Frenet-Serret description of an orthonormal triad determined by this axis, the director, and the mutually perpendicular direction. With this tool, we are able to compare defect structures in cholesterics, biaxial nematics, and smectics. Though they all have similar ground state manifolds, the defect structures are different and cannot, in general, be translated from one phase to the other

High pressure x-ray diffraction study of the volume collapse in Ba24Si100 clathrate

International audienceThe high pressure stability of the silicon type-III clathrate Ba24Si100 has been studied by x-ray diffraction (XRD) up to a maximum pressure of 37.4 GPa. The high pressure behavior of this Si type-III clathrate appears to be analogous to the structural type-I parent Ba8Si46. An isostructural volume collapse is observed at ~23 GPa, a value higher than for Ba8Si46 (13-15 GPa). The crystallinity of the structure is preserved up to the maximum attained pressure without amorphization, which appears to be in contradiction with the interpretation given in a Raman spectroscopy study [Shimizu et al., Phys. Rev. B 71, 094108 (2005)]. Nevertheless, the XRD analysis shows the appearance of a type-III disordered nanocaged-based crystalline structure after the volume collapse. Moreover, we find that the volume collapse transformation is (quasi)reversible after pressure release. Additionally, a low pressure transition first evidenced by Raman spectroscopy is also observed in our XRD study at 5 GPa: The variation of the isotropic thermal factors of Ba atoms shows a clear discontinuity at this pressure while the average positions of Ba atoms remain identical

Monte Carlo study of coaxially gated CNTFETs: capacitive effects and dynamic performance

Carbon Nanotube (CNT) appears as a promising candidate to shrink field-effect transistors (FET) to the nanometer scale. Extensive experimental works have been performed recently to develop the appropriate technology and to explore DC characteristics of carbon nanotube field effect transistor (CNTFET). In this work, we present results of Monte Carlo simulation of a coaxially gated CNTFET including electron-phonon scattering. Our purpose is to present the intrinsic transport properties of such material through the evaluation of electron mean-free-path. To highlight the potential of high performance level of CNTFET, we then perform a study of DC characteristics and of the impact of capacitive effects. Finally, we compare the performance of CNTFET with that of Si nanowire MOSFET.Comment: 15 pages, 14 figures, final version to be published in C. R. Acad. Sci. Pari

High-pressure phase transformations, pressure-induced amorphization, and polyamorphic transition of the clathrate Rb6.15Si46

International audienceThe type-I clathrate Rb6.15Si46 with partly empty cage sites has been studied up to 36 GPa using Raman spectroscopy, synchrotron x-ray diffraction in diamond-anvil cells, and ab initio total-energy and lattice-dynamics calculations. A first phase transition is observed at 13±1 GPa and a "volume collapse" transition within the clathrate structure is then observed at 24±1 GPa. Pressure-induced amorphization into a high-density amorphous (HDA) state occurs above P=33±1 GPa. The HDA form transforms into a low-density amorphous polymorph during decompression. During the compression study using angle dispersive synchrotron x-ray diffraction techniques we measured bulk modulus parameters for rocksalt-structured TaO, included adventitiously in the clathrate sample [K0=293(3) GPa and K′0=5.4(3)]

High pressure behavior of CsC8 graphite intercalation compound

International audienceThe high pressure phase diagram of CsC8 graphite intercalated compound has been investigated at ambient temperature up to 32 GPa. Combining X-ray and neutron diffraction, Raman and X- ray absorption spectroscopies, we report for the first time that CsC8, when pressurized, undergoes phase transitions around 2.0, 4.8 and 8 GPa. Possible candidate lattice structures and the transition mechanism involved are proposed. We show that the observed transitions involve the structural re- arrangement in the Cs sub-network while the distance between the graphitic layers is continuously reduced at least up to 8.9 GPa. Around 8 GPa, important modifications of signatures of the electronic structure measured by Raman and X-ray absorption spectroscopies evidence the onset of a new transition

The uptake, tissue distribution and metabolism of the mothproofing agent Eulan WA new in species of freshwater fish

The active ingredients of the mothproofing agent Eulan WA New are polychloro-2-(chloromethyl sulphonamido) diphenyl ether (PCSD) components, differing in their degree of aromatic ring chlorination. It has been shown that direct release of textile effluents has resulted in the contamination of the aquatic environment by Eulan WA New and the exposure of aquatic organisms to this complex xenobiotic. Dosing studies of this work showed that the accumulation of the major active ingredient of Eulan WA New, 6—PCSD (hexachloro-2- [chloromethyl sulphonamido] diphenyl ether) in freshwater fish tissue occurred mainly by gill and cutaneous routes. It accumulates to high concentrations, especially in the bile of pike E. lucius for example, after short periods of dosing. Analysis of pike and goldfish C. auratus tissue showed generally high ratios of 5-PAD:6-PCSD providing evidence for the in vivo cleavage of the sulphonamido bond of 6-PCSD with the formation of 5-PAD metabolite. The primary locations of the 5-PAD forming activity in these fish were identified as the liver and digestive tissue. In vitro studies showed the presence of an activity in goldfish, carp C. carpio and pike liver (homogenates and subcellular fractions) which catalysed the formation of 5-PAD from 6-PCSD. The maximum rate of 5-PAD formation was observed when liver homogenate was prepared in phosphate buffer (40 mM) of neutral to alkaline pH, containing dithiothreitol, NADPH and/or NADH, and (from a preliminary study) showing a requirement for oxygen. The activity is characteristic of a microsomal monooxygenase type (cyt.P-450 dependent and/or cyt.P-450 independent). Complementary data of contrasting differences in the ability of species of freshwater fish to metabolise 6-PCSD to 5-PAD was obtained from in vivo and in vitro studies. 5-PAD formation occurred in goldfish, carp and pike liver tissue with an apparent absence (or greatly reduced activity) in tissue of rainbow trout S. gairdneri, perch P. fluviatilis and eel A. anguilla. Such apparent qualitative differences in the metabolism of Eulan WA New by species of freshwater fish highlight the importance of a careful choice of fish species as model systems to assess environmental contamination/metabolism of this xenobiotic

Nitrous oxide emissions from European agriculture - An analysis of variability and drivers of emissions from field experiments

Nitrous oxide emissions from a network of agricultural experiments in Europe were used to explore the relative importance of site and management controls of emissions. At each site, a selection of management interventions were compared within replicated experimental designs in plot-based experiments. Arable experiments were conducted at Beano in Italy, El Encin in Spain, Foulum in Denmark, Logården in Sweden, Maulde in Belgium, Paulinenaue in Germany, and Tulloch in the UK. Grassland experiments were conducted at Crichton, Nafferton and Peaknaze in the UK, Gödöllö in Hungary, Rzecin in Poland, Zarnekow in Germany and Theix in France. Nitrous oxide emissions were measured at each site over a period of at least two years using static chambers. Emissions varied widely between sites and as a result of manipulation treatments. Average site emissions (throughout the study period) varied between 0.04 and 21.21 kg N₂O-N ha⁻¹ yr⁻¹, with the largest fluxes and variability associated with the grassland sites. Total nitrogen addition was found to be the single most important determinant of emissions, accounting for 15% of the variance (using linear regression) in the data from the arable sites (<i>p</i> < 0.0001), and 77% in the grassland sites. The annual emissions from arable sites were significantly greater than those that would be predicted by IPCC default emission factors. Variability of N₂O emissions within sites that occurred as a result of manipulation treatments was greater than that resulting from site-to-site and year-to-year variation, highlighting the importance of management interventions in contributing to greenhouse gas mitigation

Spin-polarized supercurrents for spintronics: a review of current progress

During the past 15 years a new field has emerged, which combines superconductivity and spintronics, with the goal to pave a way for new types of devices for applications combining the virtues of both by offering the possibility of long-range spin-polarized supercurrents. Such supercurrents constitute a fruitful basis for the study of fundamental physics as they combine macroscopic quantum coherence with microscopic exchange interactions, spin selectivity, and spin transport. This report follows recent developments in the controlled creation of long-range equal-spin triplet supercurrents in ferromagnets and its contribution to spintronics. The mutual proximity-induced modification of order in superconductor-ferromagnet hybrid structures introduces in a natural way such evasive phenomena as triplet superconductivity, odd-frequency pairing, Fulde-Ferrell-Larkin-Ovchinnikov pairing, long-range equal-spin supercurrents, $\pi$-Josephson junctions, as well as long-range magnetic proximity effects. All these effects were rather exotic before 2000, when improvements in nanofabrication and materials control allowed for a new quality of hybrid structures. Guided by pioneering theoretical studies, experimental progress evolved rapidly, and since 2010 triplet supercurrents are routinely produced and observed. We have entered a new stage of studying new phases of matter previously out of our reach, and of merging the hitherto disparate fields of superconductivity and spintronics to a new research direction: super-spintronics.Comment: 95 pages, 23 Figures; published version with minor typos corrected and few references adde