1,214 research outputs found
Phase diagram of a two-dimensional lattice gas model of a ramp system
Using Monte Carlo Simulation and fundamental measure theory we study the
phase diagram of a two-dimensional lattice gas model with a nearest neighbor
hard core exclusion and a next-to-nearest neighbors finite repulsive
interaction. The model presents two competing ranges of interaction and, in
common with many experimental systems, exhibits a low density solid phase,
which melts back to the fluid phase upon compression. The theoretical approach
is found to provide a qualitatively correct picture of the phase diagram of our
model system.Comment: 14 pages, 8 figures, uses RevTex
Pro-environmental behaviours at work: The interactive role of norms and attitudinal ambivalence
The environmental costs arising from unsustainable production patterns have increased to the point that organisations are now expected to adopt more responsible practices. Pro-environmental behaviours (PEBs) in the workplace can significantly contribute to bettering companies’ environmental performance and sustainability transition. This research investigated the interactive role of norms and attitudes in predicting voluntary energy conservation behaviours, based on a correlational study of 189 Portuguese workers. The study examined whether perceived norm conflicts involving co‐workers, closer colleagues and leaders’ behaviours promote or hinder workers’ own PEBs and whether attitudinal ambivalence towards their organisation’s pro-environmental initiatives is a moderator of this relationship. Controlling for the effect of the pro-environmental organisational climate, the ages of employees and organisation size, the results confirm that felt ambivalence moderates the relationship between norm conflict and reported energy conservation behaviours. The findings indicate that ambivalent workers are less likely to engage in PEBs if they perceive norm conflict, that is, if other staff members are not equally motivated to adopt those behaviours. Conversely, norm conflict had an energising effect on non-ambivalent workers. The results thus indicate that organisations could benefit from promoting their environmental policies more explicitly, encouraging their employees to discuss these initiatives and making voluntary PEBs more visible in the workplace.info:eu-repo/semantics/publishedVersio
Phase behavior of the Confined Lebwohl-Lasher Model
The phase behavior of confined nematogens is studied using the Lebwohl-Lasher
model. For three dimensional systems the model is known to exhibit a
discontinuous nematic-isotropic phase transition, whereas the corresponding two
dimensional systems apparently show a continuous
Berezinskii-Kosterlitz-Thouless like transition. In this paper we study the
phase transitions of the Lebwohl-Lasher model when confined between planar
slits of different widths in order to establish the behavior of intermediate
situations between the pure planar model and the three-dimensional system, and
compare with previous estimates for the critical thickness, i.e. the slit width
at which the transition switches from continuous to discontinuous.Comment: Submitted to Physical Review
Effective Magnetic Hamiltonian and Ginzburg Criterion for Fluids
We develop further the approach of Hubbard and Schofield (Phys.Lett., A40
(1972) 245), which maps the fluid Hamiltonian onto a magnetic one. We show that
all coefficients of the resulting effective Landau-Ginzburg-Wilson (LGW)
Hamiltonian may be expressed in terms of the compressibility of a reference
fluid containing only repulsive interactions, and its density derivatives; we
calculate the first few coefficients in the case of the hard-core reference
fluid. From this LGW-Hamiltonian we deduce approximate mean-field relations
between critical parameters and test them on data for Lennard-Jones,
square-well and hard-core-Yukawa fluids. We estimate the Ginzburg criterion for
these fluids.Comment: 4 pages, LaTeX, To appear in Phys.Rev.
Temperature of maximum density and excess properties of short-chain alcohol aqueous solutions : a simplified model simulation study
We perform an extensive computational study of binary mixtures of water and short-chain alcohols resorting to two-scale potential models to account for the singularities of hydrogen bonded liquids. Water molecules are represented by a well studied core softened potential which is known to qualitatively account for a large number of water’s characteristic anomalies. Along the same lines, alcohol molecules are idealized by dimers in which the hydroxyl groups interact with each other and withwater with a core softened potential as well. Interactions involving non-polar groups are all deemed purely repulsive. We find that the qualitative behavior of excess properties (excess volume, enthalpy, and constant pressure heat capacity) agrees with that found experimentally for alcohols such as t-butanol in water. Moreover, we observe that our simple solute under certain conditions acts as a “structuremaker,” in the sense that the temperature of maximum density of the bulk water model increases as the solute is added, i.e., the anomalous behavior of the solvent is enhanced by the solute
The effect of extraction methodology on the recovery and distribution of naphthenic acids of oilfield produced water
Comprehensive chemical characterization of naphthenic acids (NAs) in oilfield produced water is a challenging task due to sample complexity. The recovery of NAs from produced water, and the corresponding distribution of detectable NAs are strongly influenced by sample extraction methodologies. In this study, we evaluated the effect of the extraction method on chemical space (i.e. the total number of chemicals present in a sample), relative recovery, and the distribution of NAs in a produced water sample. Three generic and pre-established extraction methods (i.e. liquid-liquid extraction (Lq), and solid phase extraction using HLB cartridges (HLB), and the combination of ENV+ and C8 (ENV) cartridges) were employed for our evaluation. The ENV method produced the largest number of detected NAs (134 out of 181) whereas the HLB and Lq methods produced 108 and 91 positive detections, respectively, in the tested produced water sample. For the relative recoveries, the ENV performed better than the other two methods. The uni-variate and multi-variate statistical analysis of our results indicated that the ENV and Lq methods explained most of the variance observed in our data. When looking at the distribution of NAs in our sample the ENV method appeared to provide a more complete picture of the chemical diversity of NAs in that sample. Finally, the results are further discussed
PENYELENGGARAAN BANTUAN HUKUM BAGI MASYARAKAT TIDAK MAMPU DI KABUPATEN SOPPENG
Legal aid is a constitutional right of every citizen to guaranteed legal protection and guaranteed equality before the law. This study aims to find out how the application of local regulations regarding the provision of legal aid to the poor in Soppeng Regency. This research is a qualitative field research, with a normative juridical approach. The results of the research show that the provision of legal aid for the poor through Regional Regulation No. 1 of 2017 is a manifestation of the commitment of the local government of Soppeng Regency to providing protection, guarantees of human rights, and access to justice for underprivileged people in the justice system. In addition, legal aid for People Cannot Afford It the answer to equality before the law which needs to be regulated in laws and derivative regulations. With the existence of legal aid regulations, equality before the law and access to justice for the community can be realized.Bantuan hukum merupakan hak konstitusional setiap warga negara atas jaminan perlindungan hukum dan jaminan persamaan di depan hukum. Penelitian ini bertujuan untuk mengetahui bagaimana penerapan peraturan daerah tentang pemberian bantuan hukum kepada masyarakat tidak mampu di Kabupaten Soppeng. Penelitian ini merupakan penelitian kualitatif lapangan (field research), dengan pendekatan yuridis normatif. Hasil Penelitian menunjukkan bahwa pemberian bantuan hukum bagi masyarakat tidak mampu melalui Peraturan Daerah No. 1 Tahun 2017 merupakan wujud komitmen Pemerintah Daerah Kabupaten Soppeng dalam memberikan perlindungan, jaminan hak asasi manusia dan akses keadilan bagi masyarakat kurang mampu dalam sistem peradilan. Disamping itu, bantuan hukum bagi warga tidak mampu adalah jawaban atas persamaan dihadapan hukum yang perlu diatur dalam undang-undang maupun peraturan dibawahnya, dengan adanya regulasi bantuan hukum, maka persamaan dihadapan hukum dan akses keadilan bagi masyarakat dapat terwujud
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