Molecular beam epitaxy of highly mismatched N-rich GaNSb and InNAs alloys

GaN materials alloyed with group V anions form the so-called highly mismatched alloys (HMAs). Recently, the authors succeeded in growing N-rich GaNAs and GaNBi alloys over a large composition range by plasma-assisted molecular beam epitaxy (PA-MBE). Here, they present first results on PA-MBE growth and properties of N-rich GaNSb and InNAs alloys and compare these with GaNAs and GaNBi alloys. The enhanced incorporation of As and Sb was achieved by growing the layers at extremely low growth temperatures. Although layers become amorphous for high As, Sb, and Bi content, optical absorption measurements show a progressive shift of the optical absorption edge to lower energy. The large band gap range and controllable conduction and valence band positions of these HMAs make them promising materials for efficient solar energy conversion devices

Finite-frequency Rayleigh wave tomography of the western Mediterranean: Mapping its lithospheric structure

We present a 3-D shear wave velocity model for the crust and upper mantle of the western Mediterranean from Rayleigh wave tomography. We analyzed the fundamental mode in the 20¿167 s period band (6.0¿50.0 mHz) from earthquakes recorded by a number of temporary and permanent seismograph arrays. Using the two-plane wave method, we obtained phase velocity dispersion curves that were inverted for an isotropic Vs model that extends from the southern Iberian Massif, across the Gibraltar Arc and the Atlas mountains to the Saharan Craton. The area of the western Mediterranean that we have studied has been the site of complex subduction, slab rollback, and simultaneous compression and extension during African-European convergence since the Oligocene. The shear velocity model shows high velocities beneath the Rif from 65 km depth and beneath the Granada Basin from ¿¿70 km depth that extend beneath the Alboran Domain to more than 250 km depth, which we interpret as a near-vertical slab dangling from beneath the western Alboran Sea. The slab appears to be attached to the crust beneath the Rif and possibly beneath the Granada Basin and Sierra Nevada where low shear velocities (3.8 km/s) are mapped to >55 km depth. The attached slab is pulling down the Gibraltar Arc crust, thickening it, and removing the continental margin lithospheric mantle beneath both Iberia and Morocco as it descends into the deeper mantle. Thin lithosphere is indicated by very low upper mantle velocities beneath the Alboran Sea, above and east of the dangling slab and beneath the Cenozoic volcanics.This research was funded by the U.S. National Science Foundation EAR-0808939. The deployment of the IberArray broadband seismic network is part of the CONSOLIDER CSD2006-00041 (Geosciences in Iberia: Integrated studies on Topography and 4-D Evolution) grant from the Spanish Ministry of Science and Innovation. Additional funding was provided by the Spanish ministry under grants CGL2010-17280 and by Generalitat de Catalunya under grant 2009 SGR 6.Peer Reviewe

FROM THE ATLAS TO THE RIF A CRUSTAL SEISMIC IMAGE ACROSS MOROCCO

The velocity structure of the crust and the geometry of the Moho across Morocco has been the main target of two recently acquired wide-angle seismic reflection transects. One is the SIMA experiment which provided seismic constraints beneath the Atlas Mountains and the second has been the RIFSEIS experiment which sampled the RIF orogen. Jointly these controlled source wide-angle seismic reflection data results in an almost 700 km, seismic profile going from the the Sahara craton across the High and Middle Atlas and Rif Mountain till the Gibraltar-Arc (Alboran). Current work on the interpretation of the seismic data-set is based on forward modeling, ray-tracing, as well as low fold wide-angle stacking. The data has resulted in a detailed crustal structure and velocity model for the Atlas Mountains and a 700 km transect revealing the irregular topography of the Moho beneath these two mountain orogens. Results indicate that the High Atlas features a moderate crustal thickness and that shortening is resolved at depth through a crustal root where the Saharan crust under-thrusts below the Moroccan crust, defining a lower crust imbrication which locally places the Moho boundary at, approximately, 40 km depth. The P-wave velocity model is characterized, in averaged, by relatively low velocities. These low deep crustal velocities together with other geophysical observables such as: conductivity estimates derived from Mt measurements; moderate Bouguer gravity anomaly; surface exposures of recent alkaline volcanics; lead the interpretation to propose that partial melts are currently emplaced in the deep crustal levels and in the upper mantle. The Moho discontinuity defines a crust which is in average relatively thin beneath the Atlas which is almost a 4000 m high orogenic belt. The resulting model supports existence of mantle upwelling as a possible mechanism that contributes, significantly, to maintain the High Atlas topographyPeer Reviewe

Toxicity of 1,2-dimethlyhydrazine in mice: effect of diet and development of tolerance

The effect of diet on the lethality of 1, 2-dimethylhydrazine (DMH) injections was investigated using Swiss mice. Mortality was highest when mice were fed a nutrient-dilutealfhigh-fat diet, was intermediate with a nutrientdilutealflow- fat diet and was lowest with laboratory chow. Wheat bran was not protective. Mice developed tolerance to DMH after receiving several injections of progressively increasing dose

Field propagation in de Sitter black holes

We present an exhaustive analysis of scalar, electromagnetic and gravitational perturbations in the background of Schwarzchild-de Sitter and Reissner-Nordstrom-de Sitter spacetimes. The field propagation is considered by means of a semi-analytical (WKB) approach and two numerical schemes: the characteristic and general initial value integrations. The results are compared near the extreme cosmological constant regime, where analytical results are presented. A unifying picture is established for the dynamics of different spin fields.Comment: 15 pages, 16 figures, published versio

Friend or foe? The current epidemiologic evidence on selenium and human cancer risk.

Scientific opinion on the relationship between selenium and the risk of cancer has undergone radical change over the years, with selenium first viewed as a possible carcinogen in the 1940s then as a possible cancer preventive agent in the 1960s-2000s. More recently, randomized controlled trials have found no effect on cancer risk but suggest possible low-dose dermatologic and endocrine toxicity, and animal studies indicate both carcinogenic and cancer-preventive effects. A growing body of evidence from human and laboratory studies indicates dramatically different biological effects of the various inorganic and organic chemical forms of selenium, which may explain apparent inconsistencies across studies. These chemical form-specific effects also have important implications for exposure and health risk assessment. Overall, available epidemiologic evidence suggests no cancer preventive effect of increased selenium intake in healthy individuals and possible increased risk of other diseases and disorders

Lunar Crater Volcanic Field (Reveille and Pancake Ranges, Basin and Range Province

The Lunar Crater volcanic field (LCVF) in central Nevada (USA) is domi­nated by monogenetic mafic volcanoes spanning the late Miocene to Pleisto­cene. There are as many as 161 volcanoes (there is some uncertainty due to erosion and burial of older centers); the volumes of individual eruptions were typically ~0.1 km 3 and smaller. The volcanic field is underlain by a seismically slow asthenospheric domain that likely reflects compositional variability rela­tive to surrounding material, such as relatively higher abundances of hydrous phases. Although we do not speculate about why the domain is in its cur­rent location, its presence likely explains the unusual location of the LCVF within the interior of the Basin and Range Province. Volcanism in the LCVF occurred in 4 magmatic episodes, based upon geochemistry and ages of 35 eruptive units: episode 1 between ca. 6 and 5 Ma, episode 2 from ca. 4.7 to 3 Ma, episode 3 between ca. 1.1 and 0.4 Ma, and episode 4, ca. 300 to 35 ka. Each successive episode shifted northward but partly overlapped the area of its predecessor. Compositions of the eruptive products include basalts, teph­rites, basanites, and trachybasalts, with very minor volumes of trachyandesite and trachyte (episode 2 only). Geochemical and petrologic data indicate that magmas originated in asthenospheric mantle throughout the lifetime of the volcanic field, but that the products of the episodes were derived from unique source types and therefore reflect upper mantle compositional variability on spatial scales of tens of kilometers. All analyzed products of the volcanic field have characteristics consistent with small degrees of partial melting of ocean island basalt sources, with additional variability related to subduction­-related enrichment processes in the mantle, including contributions from recycled ocean crust (HIMU source; high­-µ, where µ = 238 U/ 204 Pb) and from hydrous flu­ids derived from subducted oceanic crust (enriched mantle, EM source). Geo­chemical evidence indicates subtle source heterogeneity at scales of hundreds of meters to kilometers within each episode­ scale area of activity, and tempo­rary ponding of magmas near the crust­-mantle boundary. Episode 1 magmas may have assimilated Paleozoic carbonate rocks, but the other episodes had little if any chemical interaction with the crust. Thermodynamic modeling and the presence of amphibole support dissolved water contents to ~5–7 wt% in some of the erupted magmas. The LCVF exhibits clustering in the form of overlapping and colocated monogenetic volcanoes that were separated by variable amounts of time to as much as several hundred thousand years, but without sustained crustal reservoirs between the episodes. The persistence of clusters through different episodes and their association with fault zones are consistent with shear­ assisted mobilization of magmas ponded near the crust­-mantle boundary, as crustal faults and underlying ductile deformation persist for hundreds of thousands of years or more (longer than individual episodes). Volcanoes were fed at depth by dikes that occur in en echelon sets and that preserve evidence of multiple pulses of magma. The dikes locally flared in the upper ~10 m of the crust to form shallow conduits that fed erup­tions. The most common volcanic landforms are scoria cones, agglomerate ramparts, and ‘a‘ ā lava fields. Eruptive styles were dominantly Strombolian to Hawaiian; the latter produced tephra fallout blankets, along with effusive activity, although many lavas were likely clastogenic and associated with lava fountains. Eroded scoria cones reveal complex plumbing structures, includ­ing radial dikes that fed magma to bocas and lava flows on the cone flanks. Phreatomagmatic maar volcanoes compose a small percentage of the land­ form types. We are unable to identify any clear hydrologic or climatic drivers for the phreatomagmatic activity; this suggests that intrinsic factors such as magma flux played an important role. Eruptive styles and volumes appear to have been similar throughout the 6 m.y. history of the volcanic field and across all 4 magmatic episodes. The total volume and time­ volume behavior of the LCVF cannot be precisely determined by surface observations due to erosion and burial by basin­fill sediments and subsequent eruptive products. However, previous estimates of a total volume of 100 km3 are likely too high by a factor of ~5, suggesting an average long­term eruptive flux of ~3–5 km 3 /m.y

LNG fueled barge for cold ironing: feasibility study for the emission abatement in the Port of Genoa

The scientific analysis presented in this paper aims at studying some maritime technical solutions for the electric energy generation and delivery to ships moored in port by means of LNG fueled generators installed onboard a floating unit. Two different scenarios regarding the LNG supply chain are supposed and some options for producing cleaner electric energy are then investigated. The reference area considered in this study is the old port of Genoa where the traffic of both passenger and cargo ships takes place. The paper presents an analysis concerning the main technical features of the considered solutions for an actual port calls scenario. The results regard dimensions and weights of the proposed floating units and the most significant characteristics of the generation equipment, as far as average load factor, fuel consumption and cost are concerned