Iridescence mimicking in fabrics: a ultraviolet/visible spectroscopy study

Poly(styrene-methyl methacrylate-acrylic acid) photonic crystals (PCs), with five different sizes (170, 190, 210, 230 and 250 nm), were applied onto three plain fabrics, namely polyamide, polyester and cotton. The PC-coated fabrics were analyzed using scanning electronic microscopy and two UV/Vis reflectance spectrophotometric techniques (integrating sphere and scatterometry) to evaluate the PCs’ self-assembly along with the obtained spectral and colors characteristics. Results showed that surface roughness of the fabrics had a major influence on the color produced by PCs. Polyamide-coated fabrics were the only samples having an iridescent effect, producing more vivid and brilliant colors than polyester and cotton samples. It was observed that as the angle of incident light increases, a hypsochromic shift in the reflection peak occurs along with the formation of new reflection peaks. Furthermore, color behavior simulations were performed with an illuminant A light source on polyamide samples. The illuminant A simulation showed greener and yellower structural colors than those illuminated with D50. The polyester and cotton samples were analyzed using scatterometry to check for iridescence, which was unseen upon ocular inspection and then proven to be present in these samples. This work allowed a better comprehension of how structural colors and their iridescence are affected by the textile substrate morphology and fiber type.This research was funded by Portuguese Foundation for Science and Technology (FCT), Portuguese Ministry of Science, Technology and Higher Education (MCTS), project UID/CTM/00264/2021 and PhD grant SFRH/BD/145269/2019

A review on characterization of pillared clays by specific techniques

[EN]The use of specific characterization techniques, namely Thermal Analysis, Near Infrared Spectroscopy, Ultraviolet–Visible Spectroscopy, Electron Paramagnetic Resonance, Mössbauer Spectroscopy and Neutron Scattering, in the characterization of pillared clays is reviewed. Special emphasis is placed in the information provided by each of these techniques in the characterization of pillared clays

Microencapsulation Yield Assessment Using TGA

In this study, microcapsules containing different contents of different kinds of fragrances and with a regular spherical shape, 2,0–8,0 µm diameter, were synthesized in various core:shell ratios. Mint and cuir fragrances were successfully encapsulated in poly(urea-formaldehyde) (PUF) shell via in-situ polymerization. This was confirmed by optical microscope, scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FTIR) studies. By observation from thermogravimetric analysis (TGA), it was found a relation between thermal gravimetric curves and the amount of fragrance encapsulated, which was later contrasted by ultraviolet-visible spectroscopy. In this way, comparatively, the yield percentage values can be quantitatively defined with a sufficient degree of accuracy by TGA methodPostprint (author's final draft

Using Simple Microwave Approach for Synthesize of CuInS2 Nanostructures and Investigation of their Performance in Solar Cells

This study focuses on the preparation and characterization of single phase CuInS2 nanoparticles with a copper complex as precursor via microwave technique. The effect of sulfur sources on product size and morphology was investigated. The products were characterized by X-ray diffraction, scanning electron microscopy, ultraviolet–visible spectroscopy, and photoluminescence spectroscopy. Thin films CuInS2 were prepared by doctor’s blade method and then studied via I-V characterization

Using Simple Microwave Approach for Synthesize of CuInS2 Nanostructures and Investigation of their Performance in Solar Cells

This study focuses on the preparation and characterization of single phase CuInS2 nanoparticles with a copper complex as precursor via microwave technique. The effect of sulfur sources on product size and morphology was investigated. The products were characterized by X-ray diffraction, scanning electron microscopy, ultraviolet–visible spectroscopy, and photoluminescence spectroscopy. Thin films CuInS2 were prepared by doctor’s blade method and then studied via I-V characterization

An Alternative Procedure to Quantify Soot in Engine Oil by Ultraviolet-Visible Spectroscopy

"This is an Accepted Manuscript of an article published by Taylor & Francis in Tribology Transactions on 02-11-2019, available online: https://www.tandfonline.com/doi/full/10.1080/10402004.2019.1645255."[EN] Due to new pollutant emissions standards, internal combustion engines need several emission control strategies (and related procedures) such as exhaust gas recirculation, diesel/gasoline particulate filters, and selective catalyst reduction that allow them to comply with complete requirements defined on those standards. These strategies result in faster degradation of engine oil, one of the most relevant consequences of which is an increase in soot contamination level. All of these strategies facilitate soot generation. Consequently, soot is one of the most important contaminants present in engine oil. The main technique to measure the content of soot in oil is thermogravimetric analysis (TGA), but this technique has certain limitations. TGA requires a long and specific procedure and has limitations in measuring small concentrations of soot in oil. Therefore, the design of an alternative technique to quantify soot in oil is relevant. One alternative is Fourier transform infrared (FTIR) spectroscopy, but it also has limitations related to low concentrations of soot in oil. This work presents an alternative technique based on ultraviolet-visible (UV-Vis) spectroscopy that allows quantification of small soot contents in used engine oil samples and avoids potential interference from other typical contaminants or those related to measurement processes, such as sample cuvette material.Antonio Garcia-Barbera was supported through the Programa Nacional de Formacion de Recursos Humanos de Investigacion of Spanish Ministerio de Ciencia e Innovacion (Grant Number BES-2016-078073).Macian Martinez, V.; Tormos, B.; Ruiz-Rosales, S.; García-Barberá, A. (2019). An Alternative Procedure to Quantify Soot in Engine Oil by Ultraviolet-Visible Spectroscopy. Tribology Transactions. 62(6):1063-1071. https://doi.org/10.1080/10402004.2019.1645255S10631071626Squaiella, L. L. F., Martins, C. A., & Lacava, P. T. (2013). Strategies for emission control in diesel engine to meet Euro VI. Fuel, 104, 183-193. doi:10.1016/j.fuel.2012.07.027Piock, W., Hoffmann, G., Berndorfer, A., Salemi, P., & Fusshoeller, B. (2011). Strategies Towards Meeting Future Particulate Matter Emission Requirements in Homogeneous Gasoline Direct Injection Engines. SAE International Journal of Engines, 4(1), 1455-1468. doi:10.4271/2011-01-1212Johnson, B. T. (2008). Diesel Engine Emissions and Their Control. Platinum Metals Review, 52(1), 23-37. doi:10.1595/147106708x248750Johnson, T. V. (2008). Diesel Emission Control in Review. SAE International Journal of Fuels and Lubricants, 1(1), 68-81. doi:10.4271/2008-01-0069Mohan, B., Yang, W., & Chou, S. kiang. (2013). Fuel injection strategies for performance improvement and emissions reduction in compression ignition engines—A review. Renewable and Sustainable Energy Reviews, 28, 664-676. doi:10.1016/j.rser.2013.08.051ALKEMADE, U., & SCHUMANN, B. (2006). Engines and exhaust after treatment systems for future automotive applications. Solid State Ionics, 177(26-32), 2291-2296. doi:10.1016/j.ssi.2006.05.051Bensaid, S., Caroca, C. J., Russo, N., & Fino, D. (2011). Detailed investigation of non-catalytic DPF regeneration. The Canadian Journal of Chemical Engineering, 89(2), 401-407. doi:10.1002/cjce.20408E, J., Xie, L., Zuo, Q., & Zhang, G. (2016). Effect analysis on regeneration speed of continuous regeneration-diesel particulate filter based on NO 2 -assisted regeneration. Atmospheric Pollution Research, 7(1), 9-17. doi:10.1016/j.apr.2015.06.012Tripathi, A., & Vinu, R. (2015). Characterization of Thermal Stability of Synthetic and Semi-Synthetic Engine Oils. Lubricants, 3(1), 54-79. doi:10.3390/lubricants3010054Karacan, Ö., Kök, M. V., & Karaaslan, U. (1999). Journal of Thermal Analysis and Calorimetry, 55(1), 109-114. doi:10.1023/a:1010136222719Heredia-Cancino, J. A., Ramezani, M., & Álvarez-Ramos, M. E. (2018). Effect of degradation on tribological performance of engine lubricants at elevated temperatures. Tribology International, 124, 230-237. doi:10.1016/j.triboint.2018.04.015Wattrus, M. (2013). Fuel Property Effects on Oil Dilution in Diesel Engines. SAE International Journal of Fuels and Lubricants, 6(3), 794-806. doi:10.4271/2013-01-2680Sharma, V., Uy, D., Gangopadhyay, A., O’Neill, A., Paxton, W. A., Sammut, A., … Aswath, P. B. (2016). Structure and chemistry of crankcase and exhaust soot extracted from diesel engines. Carbon, 103, 327-338. doi:10.1016/j.carbon.2016.03.024Pfau, S. A., La Rocca, A., Haffner-Staton, E., Rance, G. A., Fay, M. W., Brough, R. J., & Malizia, S. (2018). Comparative nanostructure analysis of gasoline turbocharged direct injection and diesel soot-in-oil with carbon black. Carbon, 139, 342-352. doi:10.1016/j.carbon.2018.06.050George, S., Balla, S., Gautam, V., & Gautam, M. (2007). Effect of diesel soot on lubricant oil viscosity. Tribology International, 40(5), 809-818. doi:10.1016/j.triboint.2006.08.002Antusch, S., Dienwiebel, M., Nold, E., Albers, P., Spicher, U., & Scherge, M. (2010). On the tribochemical action of engine soot. Wear, 269(1-2), 1-12. doi:10.1016/j.wear.2010.02.028Green, D. A., & Lewis, R. (2008). The effects of soot-contaminated engine oil on wear and friction: A review. Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering, 222(9), 1669-1689. doi:10.1243/09544070jauto468Bredin, A., Larcher, A. V., & Mullins, B. J. (2011). Thermogravimetric analysis of carbon black and engine soot—Towards a more robust oil analysis method. Tribology International, 44(12), 1642-1650. doi:10.1016/j.triboint.2011.06.002VAN DE VOORT, F. R., SEDMAN, J., COCCIARDI, R. A., & PINCHUK, D. (2006). FTIR Condition Monitoring of In-Service Lubricants: Ongoing Developments and Future Perspectives. Tribology Transactions, 49(3), 410-418. doi:10.1080/10402000600781432Van de Voort, F. R., Ghetler, A., García-González, D. L., & Li, Y. D. (2008). Perspectives on Quantitative Mid-FTIR Spectroscopy in Relation to Edible Oil and Lubricant Analysis: Evolution and Integration of Analytical Methodologies. Food Analytical Methods, 1(3), 153-163. doi:10.1007/s12161-008-9031-6Ess, M. N., Ferry, D., Kireeva, E. D., Niessner, R., Ouf, F.-X., & Ivleva, N. P. (2016). In situ Raman microspectroscopic analysis of soot samples with different organic carbon content: Structural changes during heating. Carbon, 105, 572-585. doi:10.1016/j.carbon.2016.04.056Russo, C., Apicella, B., Lighty, J. S., Ciajolo, A., & Tregrossi, A. (2017). Optical properties of organic carbon and soot produced in an inverse diffusion flame. Carbon, 124, 372-379. doi:10.1016/j.carbon.2017.08.07

Investigating the cyclic breaking of butyl-, methyland ethyl-biodiesel from waste vegetable oil using ultraviolet-visible spectrophotometry

The main advantage of biodiesel to fossil-diesel is attributed to the ester functional group in its structure. Many researchers have affirmed that the functional group assists the diesel engine to function at its peak. However, the efficiency of the biodiesel to keep the mechanical piston-strokes in the diesel engine is experimentally presumed low especially if the engine works for a long time. In this research, it was proposed that the cyclic break down of the ester functional group of biodiesel is a major disadvantage. Butanol, ethanol and methanol biodiesel were produced in the laboratory using waste vegetable oil from restaurant. The Ultraviolet-visible spectroscopy or spectrophotometer (UV–Vis) was used to investigate the cyclic break down in the Butyl-, Methyl- and Ethyl- biodiesel. The Ultraviolet-visible spectroscopy or spectrophotometer (UV–Vis) was used to probe the various biodiesel samples with a start and stop wavelength of 500 and 900 nm respectively. The wavelength interval was 1 nm at a high scanning speed. Between 500–550 and 800–850 nm, the Ethyl- and Butyl- biodiesel had an absorbance of 2.7 and 1.6 respectively with 3 peaks each. Methyl-biodiesel had the highest absorbance of 1.7 at 600–650 nm with 1 peak. The computational extrapolation of all outcomes affirms that cyclic breaking is highest in Butylbiodiesel. The most resilient biodiesel type was the Ethyl-biodiesel. However, it was recommended that cyclic breaking may be preserved by ratio-mixing of biodiesel with fossil-diesel

Influence of NaBH4 reduction on the hydrogen storage properties of aniline/Pd composite materials

The characterization and chemical synthesis of composites containing aniline and N-Phenylenediamine (NPPD), synthesized with palladium, will be analyzed according to recent studies [1] to confer hydrogen storage capabilities. The palladium metal will be introduced as either PdCl4 2- or PdCl2 2-. The experiments will be carried out under both acidic and non-acidic conditions forming a total of 8 different compounds. Each compound will be reduced with NaBH4 and analyzed using gas chromatography to measure hydrogen storage. Infrared spectroscopy and ultraviolet visible spectroscopy will also be used to gather data concerning each compound

Microwave Synthesis of Carbon Dot Nanoparticles

This study aimed to improve the known microwave method to produce carbon dot nanoparticles from ethylenediamine and citric acid. Carbon dots have recently gained much attention as they have diverse applications, such as bioimaging and drug delivery reagents as cancer theranostics. Research was focused on establishing the ideal time for the synthetic reaction to produce carbon dot nanoparticles with the microwave method. After several trials, the 16-minute trial provided the best results based on Fourier transform infrared spectroscopy, ultraviolet-visible spectroscopy, fluorescence spectroscopy, and ultraviolet exposure