Determination of biogeochemical properties of marine particles using above water measurements of the degree of polarization at the Brewster angle

Retrieval of biogeochemical parameters from remotely sensed data in optically complex waters such as those found in coastal zones is a challenging task due to the effects of various water constituents (biogenic, nonalgal and inorganic particles, dissolved matter) on the radiation exiting the ocean. Since scattering by molecules, aerosols, hydrosols and reflection at the sea surface introduce and modify the polarization state of light, the polarized upward radiation contains embedded information about the intrinsic nature of aerosols and suspended matter in the ocean. In this study, shipborne above water angularly resolved visible/near infrared multiband measurements of the degree of polarization are analysed against their corresponding in-situ biogeochemically characterized water samples for the first time. Water samples and radiometric data were collected in the English Channel along an inshore-offshore transect. Angular variations in the degree of polarization P are found to be consistent with theory. Maximum values of P are observed near the Brewster viewing angle in the specular direction. Variations in the degree of polarization at the Brewster angle (PB) with water content revealed that the suspended particulate matter, which is mainly composed of inorganic particles during the experiment, contributes to depolarise the skylight reflection, thus reducing PB. An empirical polarization-based approach is proposed to determine biogeochemical properties of the particles. The concentration of inorganic particles can be estimated using PB to within ±13% based on the dataset used. Larger sets of polarized measurements are recommended to corroborate the tendency observed in this study

Materials thermal and thermoradiative properties/characterization technology

Reliable properties data on well characterized materials are necessary for design of experiments and interpretation of experimental results. The activities of CINDAS to provide data bases and predict properties are discussed. An understanding of emissivity behavior is important in order to select appropriate methods for non-contact temperature determination. Related technical issues are identified and recommendations are offered

Analysis of systems hardware flown on LDEF. Results of the systems special investigation group

The Long Duration Exposure Facility (LDEF) was retrieved after spending 69 months in low Earth orbit (LEO). LDEF carried a remarkable variety of mechanical, electrical, thermal, and optical systems, subsystems, and components. The Systems Special Investigation Group (Systems SIG) was formed to investigate the effects of the long duration exposure to LEO on systems related hardware and to coordinate and collate all systems analysis of LDEF hardware. Discussed here is the status of the LDEF Systems SIG investigation through the end of 1991

Intercomparison in the field between the new WISP-3 and other radiometers (TriOS Ramses, ASD FieldSpec, and TACCS)

Optical close-range instruments can be applied to derive water quality parameters for monitoring purposes and for validation of optical satellite data. In situ radiometers are often difficult to deploy, especially from a small boat or a remote location. The water insight spectrometer (WISP-3) is a new hand-held radiometer for monitoring water quality, which automatically performs measurements with three radiometers (L-sky, L-u, E-d) and does not need to be connected with cables and electrical power during measurements. The instrument is described and its performance is assessed by an intercomparison to well-known radiometers, under real fieldwork conditions using a small boat and with sometimes windy and cloudy weather. Root mean squared percentage errors relative to those of the TriOS system were generally between 20% and 30% for remote sensing reflection, which was comparable to those of the other instruments included in this study. From this assessment, it can be stated that for the tested conditions, the WISP-3 can be used to obtain reflection spectra with accuracies in the same range as well-known instruments. When tuned with suitable regional algorithms, it can be used for quick scans for water quality monitoring of Chl, SPM, and aCDOM. (C) 2012 Society of Photo-Optical Instrumentation Engineers (SPIE). [DOI: 10.1117/1.JRS.6.063615

Development of bio-optical algorithms to estimate chlorophyll in the Great Salt Lake and New England lakes using in situ hyperspectral measurements

Chlorophyll is widely used to evaluate lake water quality, effectively integrating the chemical, physical and biological state of a lake. Assessment of chlorophyll conditions in lakes can be greatly enhanced by the use of remote sensing, allowing information to be gathered at spatial and temporal scales not possible with traditional limnological sampling methods. In order for remote sensing methods to provide accurate estimates of chlorophyll concentration, algorithms need to be developed with high-quality spectral data paired with water quality measurements and optimized for regional lake differences. In this study, in situ hyperspectral optical measurements were used to develop algorithms to estimate chlorophyll for the Great Salt Lake and New England lakes. The spectral data were used to mimic bands utilized by the MODIS, MERIS, and SeaWiFS sensors, as well as for a theoretical hyperspectral sensor with 3-nm wide bands, providing the capability to evaluate algorithm performance in all of these sensors. In addition to the traditional bands used in these algorithms, alternate band combinations were examined for both ocean color chlorophyll (OC) and maximum chlorophyll index (MCI) algorithms. A simulated 709 nm band was created for MODIS using the 754 nm band, providing a method for testing MODIS with algorithms relying on the key 705 nm to 715 nm wavelength range. In New England lakes, the most effective algorithm for hyperspectral bands (RMS = 0.206, in log decades) and MERIS (RMS = 0.218) was a version of MCI. For MODIS and SeaWiFS, the most effective algorithm used an OC approach with 489 nm as the blue band, yielding an RMS of 0.242 and 0.231, respectively. In the Great Salt Lake, the most effective algorithms for hyperspectral bands and MERIS were based on a single ratio of 709 nm / 675 nm, providing an RMS of 0.236 and 0.249, respectively. For MODIS and SeaWiFS, the most effective algorithm was the OC method using 489 nm as the blue band, which resulted in an RMS of 0.246 and 0.255, respectively

Quantitative Mapping of Cyanobacterial Blooms Using Oceansat-1 OCM Satellite Data

Cyanobacteria represent a major harmful algal group in fresh to brackish water environments. Lac des Allemands, a freshwater lake of 49 km2 southwest of New Orleans, Louisiana, provides a natural laboratory for remote characterization of cyanobacteria blooms because of their seasonal occurrence. This dissertation makes a contribution to research methodology pertaining to atmospheric correction of satellite data and development of remote sensing algorithms to quantify cyanobacterial pigments. The Ocean Color Monitor (OCM) sensor provides radiance measurements similar to Sea-viewing Wide Field-of-View Sensor (SeaWiFS) but with higher spatial resolution. However, OCM does not have a standard atmospheric correction procedure and the comprehensive suite of atmospheric correction procedures for ocean (or lake) is not available in the literature in one place. Atmospheric correction of satellite data over inland lakes, estuaries and coastal waters is also challenging due to difficulties in the estimation of aerosol scattering accurately over these optically complex water bodies. Thus an atmospheric correction procedure was developed to obtain more accurate spectral remote sensing reflectance (Rrs) over Lac des Allemands from OCM data based on NASA’s extensive work for SeaWiFS. Since OCM was not well calibrated, a new vicarious calibration procedure was also developed to adjust OCM radiance values to SeaWiFS radiance as SeaWiFS is well calibrated over its entire life. Empirical inversion algorithms were developed to convert the OCM Rrs at bands centered at 510.6 and 556.4 nm to concentrations of phycocyanin (PC), the primary cyanobacterial pigment. For the algorithms to be uniformly valid over all areas (or all bio-optical regimes) of the lake, a holistic approach was developed to minimize the influence of other optically active constituents on the PC algorithms. Similarly, empirical algorithms to estimate chlorophyll a (Chl a) concentrations were developed using OCM bands centered at 556.4 and 669 nm. The best PC algorithm (R2=0.7450, p\u3c0.0001, n=72) yielded a root mean square error (RMSE) of 36.92 µg/L with a relative RMSE of 10.27%, and a mean absolute error (MAE) of 21.79 µg/L with a relative MAE of 6.06% (PC from 2.75 to 363.50 µg/L, n=48). The best algorithm for Chl a (R2=0.7510, p\u3c0.0001) produced an RMSE of 31.19 µg/L, with relative RMSE = 15.70% and a MAE of 16.56 µg/L, with relative MAE = 8.33% (Chl a from 9.46 to 212.76 µg/L, n=48). The results demonstrate the preliminary success of using the 360 x 236 m resolution OCM data to map cyanobacterial blooms in a small lake. While more field data are required to further validate the long-term performance of the algorithms, at present the algorithms may be implemented to process OCM data in an automated setup to provide timely information on the lake’s bloom conditions. Similarly, retrospective processing may provide a long-term time series of bloom characteristics to document potential trends. The applicability of the algorithms can be extended to other lakes after necessary testing

SeaWiFS calibration and validation plan, volume 3

The Sea-viewing Wide Field-of-view Sensor (SeaWiFS) will be the first ocean-color satellite since the Nimbus-7 Coastal Zone Color Scanner (CZCS), which ceased operation in 1986. Unlike the CZCS, which was designed as a proof-of-concept experiment, SeaWiFS will provide routine global coverage every 2 days and is designed to provide estimates of photosynthetic concentrations of sufficient accuracy for use in quantitative studies of the ocean's primary productivity and biogeochemistry. A review of the CZCS mission is included that describes that data set's limitations and provides justification for a comprehensive SeaWiFS calibration and validation program. To accomplish the SeaWiFS scientific objectives, the sensor's calibration must be constantly monitored, and robust atmospheric corrections and bio-optical algorithms must be developed. The plan incorporates a multi-faceted approach to sensor calibration using a combination of vicarious (based on in situ observations) and onboard calibration techniques. Because of budget constraints and the limited availability of ship resources, the development of the operational algorithms (atmospheric and bio-optical) will rely heavily on collaborations with the Earth Observing System (EOS), the Moderate Resolution Imaging Spectrometer (MODIS) oceans team, and projects sponsored by other agencies, e.g., the U.S. Navy and the National Science Foundation (NSF). Other elements of the plan include the routine quality control of input ancillary data (e.g., surface wind, surface pressure, ozone concentration, etc.) used in the processing and verification of the level-0 (raw) data to level-1 (calibrated radiances), level-2 (derived products), and level-3 (gridded and averaged derived data) products

Spaceborne sensors (1983-2000 AD): A forecast of technology

A technical review and forecast of space technology as it applies to spaceborne sensors for future NASA missions is presented. A format for categorization of sensor systems covering the entire electromagnetic spectrum, including particles and fields is developed. Major generic sensor systems are related to their subsystems, components, and to basic research and development. General supporting technologies such as cryogenics, optical design, and data processing electronics are addressed where appropriate. The dependence of many classes of instruments on common components, basic R&D and support technologies is also illustrated. A forecast of important system designs and instrument and component performance parameters is provided for the 1983-2000 AD time frame. Some insight into the scientific and applications capabilities and goals of the sensor systems is also given

Optical properties monitor: Experiment definition phase

The stability of materials used in the space environment will continue to be a limiting technology for space missions. The Optical Properties Monitor (OPM) Experiment provides a comprehensive space research program to study the effects of the space environment-both natural and induced-on optical, thermal and space power materials. The OPM Experiment was selected for definition under the NASA/OAST In-Space Technology Experiment Program. The results of the OPM Definition Phase are presented. The OPM Experiment will expose selected materials to the space environment and measure the effects with in-space optical measurements. In-space measurements include total hemispherical reflectance total integrated scatter and VUV reflectance/transmittance. The in-space measurements will be augmented with extensive pre- and post-flight sample measurements to determine other optical, mechanical, electrical, chemical or surface effects of space exposure. Environmental monitors will provide the amount and time history of the sample exposure to solar irradiation, atomic oxygen and molecular contamination

Dedicated JPSS VIIRS Ocean Color Calibration/Validation Cruise

The NOAA/STAR ocean color team is focused on “end-to-end” production of high quality satellite ocean color products. In situ validation of satellite data is essential to produce the high quality, “fit for purpose” remotely sensed ocean color products that are required and expected by all NOAA line offices, as well as by external (both applied and research) users. In addition to serving the needs of its diverse users within the U.S., NOAA has an ever increasing role in supporting the international ocean color community and is actively engaged in the International Ocean-Colour Coordinating Group (IOCCG). The IOCCG, along with the Committee on Earth Observation Satellites (CEOS) Ocean Colour Radiometry Virtual Constellation (OCR-VC), is developing the International Network for Sensor Inter-comparison and Uncertainty assessment for Ocean Color Radiometry (INSITU-OCR). The INSITU-OCR has identified, amongst other issues, the crucial need for sustained in situ observations for product validation, with longterm measurement programs established and maintained beyond any individual mission. Recently, the NOAA/STAR Ocean Color Team has been making in situ validation measurements continually since the launch in fall 2011 of the Visible Infrared Imaging Radiometer Suite (VIIRS) aboard the Suomi National Polar-orbiting Partnership (SNPP) platform, part of the U.S. Joint Polar Satellite System (JPSS) program. NOAA ship time for the purpose of ocean color validation, however, had never been allocated until the cruise described herein. As the institutional lead for this cruise, NOAA/STAR invited external collaborators based on scientific objectives and existing institutional collaborations. The invited collaborators are all acknowledged professionals in the ocean color remote sensing community. Most of the cruise principal investigators (PIs) are also PIs of the VIIRS Ocean Color Calibration and Validation (Cal/Val) team, including groups from Stennis Space Center/Naval Research Laboratory (SSC/NRL) and the University of Southern Mississippi (USM); City College of New York (CCNY); University of Massachusetts Boston (UMB); University of South Florida (USF); University of Miami (U. Miami); and, the National Institute of Standards and Technology (NIST). These Cal/Val PIs participated directly, sent qualified researchers from their labs/groups, or else contributed specific instruments or equipment. Some of the cruise PIs are not part of the NOAA VIIRS Ocean Color Cal/Val team but were chosen to complement and augment the strengths of the Cal/Val team participants. Outside investigator groups included NASA Goddard Space Flight Center (NASA/GSFC), Lamont-Doherty Earth Observatory at Columbia University (LDEO), and the Joint Research Centre of the European Commission (JRC). This report documents the November 2014 cruise off the U.S. East Coast aboard the NOAA Ship Nancy Foster. This cruise was the first dedicated ocean color validation cruise to be supported by the NOAA Office of Marine and Air Operations (OMAO). A second OMAO-supported cruise aboard the Nancy Foster is being planned for late 2015. We at NOAA/STAR are looking forward to continuing dedicated ocean color validation cruises, supported by OMAO on NOAA vessels, on an annual basis in support of JPSS VIIRS on SNPP, J-1, J-2 and other forthcoming satellite ocean color missions from the U.S as well as other countries. We also look forward to working with the U.S. and the international ocean community for improving our understanding of global ocean optical, biological, and biogeochemical properties.JRC.H.1-Water Resource