Spectral Efficiency of Spectrum Pooling Systems

In this contribution, we investigate the idea of using cognitive radio to reuse locally unused spectrum to increase the total system capacity. We consider a multiband/wideband system in which the primary and cognitive users wish to communicate to different receivers, subject to mutual interference and assume that each user knows only his channel and the unused spectrum through adequate sensing. The basic idea under the proposed scheme is based on the notion of spectrum pooling. The idea is quite simple: a cognitive radio will listen to the channel and, if sensed idle, will transmit during the voids. It turns out that, although its simplicity, the proposed scheme showed very interesting features with respect to the spectral efficiency and the maximum number of possible pairwise cognitive communications. We impose the constraint that users successively transmit over available bands through selfish water filling. For the first time, our study has quantified the asymptotic (with respect to the band) achievable gain of using spectrum pooling in terms of spectral efficiency compared to classical radio systems. We then derive the total spectral efficiency as well as the maximum number of possible pairwise communications of such a spectrum pooling system

Asynchronous CDMA Systems with Random Spreading-Part I: Fundamental Limits

Spectral efficiency for asynchronous code division multiple access (CDMA) with random spreading is calculated in the large system limit allowing for arbitrary chip waveforms and frequency-flat fading. Signal to interference and noise ratios (SINRs) for suboptimal receivers, such as the linear minimum mean square error (MMSE) detectors, are derived. The approach is general and optionally allows even for statistics obtained by under-sampling the received signal. All performance measures are given as a function of the chip waveform and the delay distribution of the users in the large system limit. It turns out that synchronizing users on a chip level impairs performance for all chip waveforms with bandwidth greater than the Nyquist bandwidth, e.g., positive roll-off factors. For example, with the pulse shaping demanded in the UMTS standard, user synchronization reduces spectral efficiency up to 12% at 10 dB normalized signal-to-noise ratio. The benefits of asynchronism stem from the finding that the excess bandwidth of chip waveforms actually spans additional dimensions in signal space, if the users are de-synchronized on the chip-level. The analysis of linear MMSE detectors shows that the limiting interference effects can be decoupled both in the user domain and in the frequency domain such that the concept of the effective interference spectral density arises. This generalizes and refines Tse and Hanly's concept of effective interference. In Part II, the analysis is extended to any linear detector that admits a representation as multistage detector and guidelines for the design of low complexity multistage detectors with universal weights are provided

Mechanisms of light energy harvesting in dendrimers and hyperbranched polymers

Since their earliest synthesis, much interest has arisen in the use of dendritic and structurally allied forms of polymer for light energy harvesting, especially as organic adjuncts for solar energy devices. With the facility to accommodate a proliferation of antenna chromophores, such materials can capture and channel light energy with a high degree of efficiency, each polymer unit potentially delivering the energy of one photon-or more, when optical nonlinearity is involved. To ensure the highest efficiency of operation, it is essential to understand the processes responsible for photon capture and channelling of the resulting electronic excitation. Highlighting the latest theoretical advances, this paper reviews the principal mechanisms, which prove to involve a complex interplay of structural, spectroscopic and electrodynamic properties. Designing materials with the capacity to capture and control light energy facilitates applications that now extend from solar energy to medical photonics. © 2011 by the authors; licensee MDPI, Basel, Switzerland

Energy-harvesting materials

It is shown how key features of natural photosynthesis can be emulated in novel materials based on photoactive multichromophore arrays and crystals. A major consideration in the design of such systems is the means of channeling electronic excitation from sites of light absorption to centers where it is stored or released. Storage is often achieved by driving charge separation or, for the longer term, a more complex chemical reaction whilst rapid release is commonly associated with frequency up-converted emission. In each case channeling to the conversion site generally entails a multi-step energy transfer mechanism whose efficiency is determined by the arrangement and electronic properties of the array chromophores or ions, guided in the more complex systems by a spectroscopic gradient that promotes overall directionality. The functional cascade molecules known as photoactive dendrimers are exemplars of this approach. The latest developments involve new mechanisms for concerted excitation transfer in multichromophore systems, leading towards the tailoring and exploitation of optical nonlinearities for high intensity energy pooling applications