1,217 research outputs found
Localization properties of one-dimensional Frenkel excitons: Gaussian versus Lorentzian diagonal disorder
We compare localization properties of one-dimensional Frenkel excitons with
Gaussian and Lorentzian uncorrelated diagonal disorder. We focus on the states
of the Lifshits tail, which dominate the optical response and low-temperature
energy transport in molecular J-aggregates. The absence of exchange narrowing
in chains with Lorentzian disorder is shown to manifest itself in the disorder
scaling of the localization length distribution. Also, we show that the local
exciton level structure of the Lifshits tail differs substantially for these
two types of disorder: In addition to the singlets and doublets of localized
states near the bare band edge, strongly resembling those found for Gaussian
disorder, for Lorentzian disorder two other types of states are found in this
energy region as well, namely multiplets of three or four states localized on
the same chain segment and isolated states localized on short segments.
Finally, below the Lifshits tail, Lorentzian disorder induces strongly
localized exciton states, centered around low energy sites, with localization
properties that strongly depend on energy. For Gaussian disorder with a
magnitude that does not exceed the exciton bandwidth, the likelihood to find
such very deep states is exponentially small.Comment: 9 two-column pages, 4 figures, to appear in Phys. Rev.
Excitons in Molecular Aggregates with L\'evy Disorder: Anomalous Localization and Exchange Broadening of Optical Spectra
We predict the existence of exchange broadening of optical lineshapes in
disordered molecular aggregates and a nonuniversal disorder scaling of the
localization characteristics of the collective electronic excitations
(excitons). These phenomena occur for heavy-tailed L\'evy disorder
distributions with divergent second moments - distributions that play a role in
many branches of physics. Our results sharply contrast with aggregate models
commonly analyzed, where the second moment is finite. They bear a relevance for
other types of collective excitations as well
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