Nanofabrication techniques in large-area molecular electronic devices

The societal impact of the electronics industry is enormous-not to mention how this industry impinges on the global economy. The foreseen limits of the current technology-technical, economic, and sustainability issues-open the door to the search for successor technologies. In this context, molecular electronics has emerged as a promising candidate that, at least in the short-term, will not likely replace our silicon-based electronics, but improve its performance through a nascent hybrid technology. Such technology will take advantage of both the small dimensions of the molecules and new functionalities resulting from the quantum effects that govern the properties at the molecular scale. An optimization of interface engineering and integration of molecules to form densely integrated individually addressable arrays of molecules are two crucial aspects in the molecular electronics field. These challenges should be met to establish the bridge between organic functional materials and hard electronics required for the incorporation of such hybrid technology in the market. In this review, the most advanced methods for fabricating large-area molecular electronic devices are presented, highlighting their advantages and limitations. Special emphasis is focused on bottom-up methodologies for the fabrication of well-ordered and tightly-packed monolayers onto the bottom electrode, followed by a description of the top-contact deposition methods so far used

Rigidez debida a adsorbatos, potencia termoeléctrica cuántica y fotorrespuesta en materiales dos-dimensionales

Tesis doctoral inédita leída en la Universidad Autónoma de Madrid, Facultad de Ciencias, Departamento de Física de la Materia Condensada . Fecha de lectura: 27-10-2017This work has been supported by the European Commission through EC FP7 ITN “MOLESCO” Project No. 60672

Encoding information onto the charge and spin state of a paramagnetic atom using MgO tunnelling spintronics

An electrical current that flows across individual atoms or molecules can generate exotic quantum-based behavior, from memristive effects to Coulomb blockade and the promotion of quantum excited states. These fundamental effects typically appear one at a time in model junctions built using atomic tip or lateral techniques. So far, however, a viable industrial pathway for such discrete state devices has been lacking. Here, we demonstrate that a commercialized device platform can serve as this industrial pathway for quantum technologies. We have studied magnetic tunnel junctions with a MgO barrier containing C atoms. The paramagnetic localized electrons due to individual C atoms generate parallel nanotransport paths across the micronic device as deduced from magnetotransport experiments. Coulomb blockade effects linked to tunnelling magnetoresistance peaks can be electrically controlled, leading to a persistent memory effect. Our results position MgO tunneling spintronics as a promising platform to industrially implement quantum technologies

Comparison of energy storage technologies for applications of unmanned electrical aerial vehicles

Tese de Mestrado Integrado. Engenharia Mecânica. Faculdade de Engenharia. Universidade do Porto. 201

Molecular Electronics

This is a Special Issue on Molecular Electronics which provides an overview of the field and will be useful for both theoreticians and experimentalists. Topics include protein-based electronics, field-induced trans-to-cis isomerisation, phonon thermal conductance, spin-dependent transport, attenuation factors, HOMO-LUMO gap corrections and nanofabrication techniques

A cooling system for s.m.a. (shape memory alloy)based on the use of peltier cells

The aim of this thesis has been the study and the implementation of an innovative cooling system for S.M.A. (Shape Memory Alloy) material by using a Peltier cell. This system has demonstrated a consistent cooling time reduction during the application and so that the solution adopted has confirmed that it can be used for a better operability of the S.M.A. material during the cooling phase. After an accurate selection of possible cooling system to be adopted on these materials the better choice in terms of efficiency and energy consumption reduction has converged on Peltier cell design development. In this context for our research three investigation have been conducted. The first one has concerned an analytic investigation in order to understand the phenomenology and the terms involved during the heat exchange. After this study a numerical investigation through a Finite Element approach by commercial software has been carried out. Also an experimental investigation has been conducted, at the CIRA Smart Structure Laboratory, in order to verify the results obtained by the numerical prediction. The set-up with the Peltier cell used as heater and cooler of the S.M.A. has confirmed the soundness of the solution adopted. Finally, a correlation between numerical and experimental results have been presented demonstrating the validity of the obtained results through the developed investigations. This system, composed of Peltier cell has confirmed also an energy consumption reduction because the cell has been used for heating and cooling phase without additional system as resistive system (Joule effect). This project shall be also industrial involvement in a new cost cut down point of vie

Recent Progress in Multiphase Thermoelectric Materials

Thermoelectric materials, which directly convert thermal energy to electricity and vice versa, are considered a viable source of renewable energy. However, the enhancement of conversion efficiency in these materials is very challenging. Recently, multiphase thermoelectric materials have presented themselves as the most promising materials to achieve higher thermoelectric efficiencies than single-phase compounds. These materials provide higher degrees of freedom to design new compounds and adopt new approaches to enhance the electronic transport properties of thermoelectric materials. Here, we have summarised the current developments in multiphase thermoelectric materials, exploiting the beneficial effects of secondary phases, and reviewed the principal mechanisms explaining the enhanced conversion efficiency in these materials. This includes energy filtering, modulation doping, phonon scattering, and magnetic effects. This work assists researchers to design new high-performance thermoelectric materials by providing common concepts