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    ํ•€ํŽซ ์†Œ์ž์—์„œ์˜ ํ•ซ์บ๋ฆฌ์–ด ์‹ ๋ขฐ์„ฑ ๋ถ„์„

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    ํ•™์œ„๋…ผ๋ฌธ (๋ฐ•์‚ฌ) -- ์„œ์šธ๋Œ€ํ•™๊ต ๋Œ€ํ•™์› : ๊ณต๊ณผ๋Œ€ํ•™ ์ „๊ธฐยท์ •๋ณด๊ณตํ•™๋ถ€, 2021. 2. ์‹ ํ˜•์ฒ .CMOS ๋กœ์ง ์†Œ์ž๋Š” ํผํฌ๋จผ์Šค๋ฅผ ํ–ฅ์ƒ์‹œํ‚ค๊ธฐ ์œ„ํ•ด ์ง€์†์ ์œผ๋กœ ์ถ•์†Œํ™” ๋˜๊ณ  ์žˆ๋‹ค. ํ•˜์ง€๋งŒ ๊ตฌ์กฐ ํŒŒ๋ผ๋ฏธํ„ฐ๋“ค์˜ ์ถ•์†Œํ™”์— ๋น„ํ•ด ๋™์ž‘ ์ „์••์€ ์ถฉ๋ถ„ํžˆ ๊ฐ์†Œํ•˜์ง€ ์•Š๋Š”๋‹ค. ๋”ฐ๋ผ์„œ ์†Œ์ž ๋‚ด ์ˆ˜์ง ์ „๊ณ„๋‚˜ ์˜จ๋„๊ฐ€ ์ฆ๊ฐ€ํ•˜๋Š” ์ถ”์„ธ์ด๊ธฐ ๋•Œ๋ฌธ์— ์‹ ๋ขฐ์„ฑ์€ ๊ณ„์†ํ•ด์„œ ๋ฌธ์ œ๊ฐ€ ๋˜๊ณ  ์žˆ๋‹ค. ์ตœ๊ทผ 3D ์†Œ์ž์˜ ์‹ ๋ขฐ์„ฑ์— ๋Œ€ํ•œ ์—ฐ๊ตฌ๋Š” ๋งŽ์ด ์ง„ํ–‰๋˜๊ณ  ์žˆ์ง€๋งŒ empirical ๋ชจ๋ธ๋ง๊ณผ ๊ด€๋ จ๋œ ์—ฐ๊ตฌ๊ฐ€ ๋Œ€๋ถ€๋ถ„์ด๋‹ค. ๋”ฐ๋ผ์„œ ๋ณธ ์—ฐ๊ตฌ์—์„œ๋Š” ์‹ค์ œ ์ธก์ •์„ ๊ธฐ๋ฐ˜์œผ๋กœ ์‹œ๋ฎฌ๋ ˆ์ด์…˜์„ ์ด์šฉํ•˜์—ฌ ๋ฌผ๋ฆฌ์  ์ด๋ก  ์ค‘์‹ฌ์œผ๋กœ ๋กœ์ง ์†Œ์ž์˜ ํ•ซ์บ๋ฆฌ์–ด ์‹ ๋ขฐ์„ฑ์„ ๋ถ„์„ํ•˜์˜€๋‹ค. ๋จผ์ € ํ•ซ์บ๋ฆฌ์–ด ๋ชจ๋ธ์˜ ์ •ํ™•์„ฑ์„ ํ–ฅ์ƒ์‹œํ‚ค๊ธฐ ์œ„ํ•ด์„œ TCAD ์‹œ๋ฎฌ๋ ˆ์ด์…˜์— electron-electron scattering์„ ์ ์šฉํ•˜์˜€๋‹ค. ์ถ”๊ฐ€์ ์œผ๋กœ 3D FinFET์˜ ์ธก์ • ๋ฐ์ดํ„ฐ์™€ calibration์„ ์ง„ํ–‰ํ•˜์—ฌ ๋ชจ๋ธ์˜ ์ •ํ•ฉ์„ฑ์„ ํ™•์ธํ•˜์˜€๋‹ค. calibration ๊ณผ์ •์—์„œ๋Š” ๋ชจ๋“  scattering ๋ฉ”์ปค๋‹ˆ์ฆ˜์„ ๊ณ ๋ คํ•˜๊ธฐ ์œ„ํ•ด ๋‹ค์–‘ํ•œ ์ „์••๊ณผ ์˜จ๋„ ์กฐ๊ฑด์ด ํ•„์š”ํ•˜๋‹ค. ๋”ฐ๋ผ์„œ ๋‹ค์–‘ํ•œ ์ „์•• ์กฐ๊ฑด์— ๋”ฐ๋ฅธ HCD๋ฅผ ๋ถ„์„ํ•˜๊ณ , calibration์„ ์ง„ํ–‰ํ•˜์—ฌ HCD ๋ชจ๋ธ์˜ ํŒŒ๋ผ๋ฏธํ„ฐ๋ฅผ ์ถ”์ถœํ•˜์˜€๋‹ค. ๋‹ค์Œ์œผ๋กœ ์ „์•• ์กฐ๊ฑด์— ๋”ฐ๋ฅธ HCD์˜ ์˜จ๋„ ๊ฒฝํ–ฅ์„ฑ์„ ๋ถ„์„ํ•˜์˜€๋‹ค. oxide trap๊ณผ ๋‹ฌ๋ฆฌ interface trap์€ ์ „์•• ์กฐ๊ฑด์— ๋”ฐ๋ผ ๋‹ค๋ฅธ ์˜จ๋„ ๊ฒฝํ–ฅ์„ฑ์„ ๋ณด์ธ๋‹ค. ๋”ฐ๋ผ์„œ interface trap์„ 3๊ฐ€์ง€ ์„ฑ๋ถ„์œผ๋กœ ๋ถ„๋ฆฌํ•˜์—ฌ ๊ฐ ์„ฑ๋ถ„์˜ ์˜จ๋„ ๊ฒฝํ–ฅ์„ฑ์„ ๋ถ„์„ํ•˜์˜€๋‹ค. Multiple particle process(MP)๊ณผ field enhanced thermal degradation process(FP)๋Š” ์ „์•• ์กฐ๊ฑด๊ณผ ์ƒ๊ด€์—†์ด ์ผ์ •ํ•œ ์˜จ๋„ ๊ฒฝํ–ฅ์„ฑ์„ ๊ฐ€์ง„๋‹ค. ๋ฐ˜๋ฉด Single particle process(SP)๋Š” scattering์˜ ์˜ํ–ฅ์„ ๋ฐ›๊ธฐ ๋•Œ๋ฌธ์— ์˜จ๋„ ๊ฒฝํ–ฅ์„ฑ์€ ์ „์•• ์กฐ๊ฑด์— ๋”ฐ๋ผ ๋‹ฌ๋ผ์ง„๋‹ค. ์˜จ๋„ ๊ฒฝํ–ฅ์„ฑ ๋ถ„์„ ๊ณผ์ •์—์„œ๋„ calibration์„ ์ง„ํ–‰ํ•˜๋ฉฐ ์—ฌ๋Ÿฌ ๋ฒˆ์˜ iteration์„ ํ†ตํ•ด ๋‹ค์–‘ํ•œ ์ „์•• ๋ฐ ์˜จ๋„๊ฐ€ ๊ณ ๋ ค๋œ ํŒŒ๋ผ๋ฏธํ„ฐ๋ฅผ ์ถ”์ถœํ•œ๋‹ค. ์ถ”์ถœ๋œ ํŒŒ๋ผ๋ฏธํ„ฐ๋ฅผ ์ ์šฉํ•œ ์‹œ๋ฎฌ๋ ˆ์ด์…˜ ๋ชจ๋ธ์€ ๊ธฐ์กด์˜ ๋ชจ๋ธ๋ณด๋‹ค ๋” ์ •ํ™•ํ•˜๊ฒŒ HCD ์ธก์ • ๊ฒฐ๊ณผ๋ฅผ ์˜ˆ์ธกํ•˜์˜€๋‹ค. ๊ฒฐ๊ณผ์ ์œผ๋กœ ๋ฌผ๋ฆฌ์  ์ด๋ก ์— ๊ทผ๊ฑฐํ•˜์—ฌ ์‹œ๋ฎฌ๋ ˆ์ด์…˜ ๋ชจ๋ธ ๊ตฌ์ถ•ํ•จ์œผ๋กœ์จ HCD ๋ถ„์„์˜ ์ •ํ™•์„ฑ์„ ํ–ฅ์ƒ์‹œ์ผฐ๋‹ค. ํ•˜์ง€๋งŒ ๊ฐ€์† ์กฐ๊ฑด๊ณผ ๋™์ž‘ ์กฐ๊ฑด์˜ self-heating ํšจ๊ณผ๊ฐ€ ๋‹ค๋ฅด๊ธฐ ๋•Œ๋ฌธ์— ์†Œ์ž๊ฐ€ ์‹ค์ œ CMOS ํšŒ๋กœ์˜ ๋™์ž‘ ์กฐ๊ฑด์—์„œ interface trap์„ ๋ฐœ์ƒ์‹œํ‚ค๋Š” ๋ฉ”์ปค๋‹ˆ์ฆ˜์€ ๋‹ค๋ฅผ ์ˆ˜ ์žˆ๋‹ค. ๋”ฐ๋ผ์„œ ์šฐ๋ฆฌ๋Š” ๋™์ž‘ ์˜์—ญ์—์„œ์˜ ๊ฐ ์„ฑ๋ถ„์˜ ๋น„์œจ๊นŒ์ง€ ์˜ˆ์ธกํ•˜์˜€๋‹ค. ๋งˆ์ง€๋ง‰์œผ๋กœ ์šฐ๋ฆฌ๋Š” 10 nm node ์†Œ์ž์—์„œ nFinFET์— ๋น„ํ•ด pFinFET์—์„œ ๋†’์€ ์—ดํ™”๊ฐ€ ๋ฐœ์ƒํ•˜๋Š” ์›์ธ์— ๋Œ€ํ•ด ๋ถ„์„ํ•˜์˜€๋‹ค. pFinFET์€ ์†Œ์Šค/๋“œ๋ ˆ์ธ ๋ฌผ์งˆ๋กœ SiGe๋ฅผ ์‚ฌ์šฉํ•˜๊ธฐ ๋•Œ๋ฌธ์— nFinFET์— ๋น„ํ•ด self-heating ํšจ๊ณผ๊ฐ€ ์‹ฌํ•˜์—ฌ ์†Œ์ž ์˜จ๋„๊ฐ€ ๋„ ๋†’๋‹ค. ์ด๋ก ์ ์œผ๋กœ MP ๋ฉ”์ปค๋‹ˆ์ฆ˜์˜ lifetime์€ ์˜จ๋„๊ฐ€ ์ฆ๊ฐ€ํ• ์ˆ˜๋ก ๊ฐ์†Œํ•˜๊ธฐ ๋•Œ๋ฌธ์— MP์— ์˜ํ•œ ์—ดํ™” ๋˜ํ•œ ๊ฐ์†Œํ•œ๋‹ค. ๋”ฐ๋ผ์„œ ์†Œ์ž ์˜จ๋„๊ฐ€ ๋” ๋†’์€ pFinFET์—์„œ nFinFET์— ๋น„ํ•ด ๋” ๋งŽ์€ MP๊ฐ€ ๋ฐœ์ƒํ•˜๊ธฐ ์–ด๋ ต๋‹ค. ํ•˜์ง€๋งŒ nFinFET ๊ณผ ๋‹ฌ๋ฆฌ pFinFET์—์„œ๋Š” Si-H bond์˜ electron๊ณผ hole์ด ๋ฐ˜์‘ํ•˜์—ฌ interface trap์„ ์ƒ์„ฑ์‹œํ‚ค๋Š” RD ๊ฐ€ ๋ฐœ์ƒํ•  ์ˆ˜ ์žˆ๋‹ค. ๋˜ํ•œ RD๋Š” ์˜จ๋„๊ฐ€ ๋†’์„์ˆ˜๋ก ๋” ๋งŽ์€ ์—ดํ™”๊ฐ€ ๋ฐœ์ƒํ•˜๊ธฐ ๋•Œ๋ฌธ์—, pFinFET์—์„œ nFinFET๋ณด๋‹ค ๋” ๋งŽ์€ ์—ดํ™”๊ฐ€ ๋ฐœ์ƒํ•˜๋Š” ํ˜„์ƒ์„ ์„ค๋ช…ํ•  ์ˆ˜ ์žˆ๋‹ค. ๋”ฐ๋ผ์„œ ์šฐ๋ฆฌ๋Š” HCD ์กฐ๊ฑด์ด์ง€๋งŒ ์†Œ์ž ์˜จ๋„๊ฐ€ ๋†’์€ pFinFET์—์„œ ์ถ”๊ฐ€์ ์ธ RD ๋ฉ”์ปค๋‹ˆ์ฆ˜์ด ๋ฐœ์ƒํ•  ์ˆ˜ ์žˆ๋‹ค๊ณ  ์ œ์•ˆํ•œ๋‹ค. ๋‹ค์–‘ํ•œ ์ „์•• ์กฐ๊ฑด์—์„œ์˜ ์ „๋ฅ˜ ์—ดํ™”์œจ์„ ํ†ตํ•ด ์ฃผ์š” ์—ดํ™” ๋ฉ”์ปค๋‹ˆ์ฆ˜์„ ๋ถ„์„ํ•˜์˜€์œผ๋ฉฐ pFinFET์—์„œ๋Š” RD๊ฐ€ ์ฃผ์š”ํ•จ์„ ํ™•์ธํ•˜์˜€๋‹ค. ๋˜ํ•œ TCAD ์‹œ๋ฎฌ๋ ˆ์ด์…˜์„ ์ด์šฉํ•˜์—ฌ HCD ์กฐ๊ฑด์—์„œ ๋ฐœ์ƒํ•  ์ˆ˜ ์žˆ๋Š” RD๋ฅผ ์˜ˆ์ธกํ•˜์˜€๋‹ค. ๊ทธ ๊ฒฐ๊ณผ RD๋ฅผ ์ œ์™ธํ•œ ์ˆœ์ˆ˜ hot carrier ์„ฑ๋ถ„์€ pFinFET๋ณด๋‹ค nFinFET์—์„œ ๋” ๋งŽ์ด ๋ฐœ์ƒํ•œ๋‹ค.CMOS logic devices have been scaled down to improve performance. However, the operating voltage is not sufficiently reduced compared to the scale down in physical dimensions. Therefore, since the electric field and temperature of the device gradually increase, reliability is still a critical issue in logic devices. Recently, many studies on the reliability of 3D devices are being conducted, but most of the studies are related to empirical modeling. Therefore, in this study, based on the actual measurement results, the hot carrier degradation(HCD) reliability of the logic device was analyzed focusing on the physical theory using Technology computer-aided design (TCAD) simulation. First, electron-electron scattering(EES) was applied to the TCAD simulation to improve the accuracy of the hot carrier model. Additionally, calibration between the measurement data of 14 nm node FinFET and the model was performed to confirm the consistency. The calibration process required various voltage and temperature conditions to account for all scattering mechanisms. Therefore, HCD was analyzed according to various voltage conditions, and the parameters of the HCD model were extracted by calibration process. Next, temperature dependence under various HCD conditions was analyzed. Unlike oxide traps, interface traps show different temperature dependence depending on HCD voltage conditions. Therefore, the interface traps were separated into three components and the temperature dependence was analyzed for each component. Multiple particle process (MP) and Field enhanced thermal degradation process (FP) have a constant temperature dependence regardless of voltage conditions. On the other hand, the temperature dependence of Single particle process (SP) varies depending on the voltage condition because SP is affected by scattering. In the process of temperature dependence analysis, calibration is also performed and parameters considering various voltages and temperatures were extracted through several iterations. The improved model to which the extracted parameters were applied showed more precise prediction of degradation compared to that of the previous model. As a results, accuracy of the HCD analysis was improved by establishing the HCD simulation framework based on physical theories. However, since the self-heating effect of the acceleration condition and the operation condition are different, the HCD mechanism that occurs in the actual CMOS circuit may also be different. Therefore, we predicted the ratio of each component under operating condition. Finally, in 10 nm node devices, we analyzed the cause of higher HCD in pFinFETs than in nFinFETs. Self-heating effect is severe in pFinFETs because SiGe is used as the source/drain material which makes the device temperature higher than nFinFETs. Theoretically, because the lifetime of multiple particle(MP) mechanism decreases as temperature increases, degradation due to MP decreases. Therefore, it is difficult for the HCD mechanisms to occur more in pFinFETs which has higher temperature than nFinFETs. However, in pFinFETs unlike nFinFETs, reaction-diffusion (RD) mechanism can occur in which holes react with the electrons of Si-H bonds to generate interface traps. Also, since RD deteriorates more as the temperature increases, the phenomenon that more degradation occurs in pFinFET than nFinFET can be explained by the RD mechanism. Therefore, we propose an additional RD mechanism that is caused by high device temperature in pFinFETs even in HCD condition. Main components were investigated through measurements of current degradation rate in various voltage conditions, and it was found that RD is dominant in pFinFETs. Also, RD that can occur in HCD condition was predicted through TCAD simulation. As a results, degradation due to pure hot carriers without RD occurs more in nFinFETs than in pFinFETs.Abstract i Chapter 1. Introduction 1 Chapter 2. Hot Carrier Degradation Model 4 2.1. Physical theory 4 2.2. TCAD simulation 8 2.3. Calibration process 14 2.4. Summary 22 Chapter 3. Analysis on Temperature Dependence of HCD 25 3.1. Introduction 25 3.2. Temperature dependence according to acceleration conditions 26 3.3. Calibration process 30 3.4. Mechanism separation 33 3.5. HCD prediction in the nominal voltage 35 3.6. Summary 36 Chapter 4. Comparative Analysis of HCD in nMOS/pMOS FinFET 39 4.1. Introduction 39 4.2. Comparison of HCD in the long/short channel FinFET 40 4.3. Self-heating effect in n/pFinFET 44 4.4. Bias Temperature Instability(BTI) in n/pFinFET 47 4.5. Summary 59 Chapter 5. Conclusion 64 Abstract in Korean 66 List of Publications 69Docto

    Miniaturized Transistors, Volume II

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    In this book, we aim to address the ever-advancing progress in microelectronic device scaling. Complementary Metal-Oxide-Semiconductor (CMOS) devices continue to endure miniaturization, irrespective of the seeming physical limitations, helped by advancing fabrication techniques. We observe that miniaturization does not always refer to the latest technology node for digital transistors. Rather, by applying novel materials and device geometries, a significant reduction in the size of microelectronic devices for a broad set of applications can be achieved. The achievements made in the scaling of devices for applications beyond digital logic (e.g., high power, optoelectronics, and sensors) are taking the forefront in microelectronic miniaturization. Furthermore, all these achievements are assisted by improvements in the simulation and modeling of the involved materials and device structures. In particular, process and device technology computer-aided design (TCAD) has become indispensable in the design cycle of novel devices and technologies. It is our sincere hope that the results provided in this Special Issue prove useful to scientists and engineers who find themselves at the forefront of this rapidly evolving and broadening field. Now, more than ever, it is essential to look for solutions to find the next disrupting technologies which will allow for transistor miniaturization well beyond siliconโ€™s physical limits and the current state-of-the-art. This requires a broad attack, including studies of novel and innovative designs as well as emerging materials which are becoming more application-specific than ever before

    Modeling the Interdependences between Voltage Fluctuation and BTI Aging

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    With technology scaling, the susceptibility of circuits to different reliability degradations is steadily increasing. Aging in transistors due to bias temperature instability (BTI) and voltage fluctuation in the power delivery network of circuits due to IR-drops are the most prominent. In this paper, we are reporting for the first time that there are interdependences between voltage fluctuation and BTI aging that are nonnegligible. Modeling and investigating the joint impact of voltage fluctuation and BTI aging on the delay of circuits, while remaining compatible with the existing standard design flow, is indispensable in order to answer the vital question, โ€œwhat is an efficient (i.e., small, yet sufficient) timing guardband to sustain the reliability of circuit for the projected lifetime?โ€ This is, concisely, the key goal of this paper. Achieving that would not be possible without employing a physics-based BTI model that precisely describes the underlying generation and recovery mechanisms of defects under arbitrary stress waveforms. For this purpose, our model is validated against varied semiconductor measurements covering a wide range of voltage, temperature, frequency, and duty cycle conditions. To bring reliability awareness to existing EDA tool flows, we create standard cell libraries that contain the delay information of cells under the joint impact of aging and IR-drop. Our libraries can be directly deployed within the standard design flow because they are compatible with existing commercial tools (e.g., Synopsys and Cadence). Hence, designers can leverage the mature algorithms of these tools to accurately estimate the required timing guardbands for any circuit despite its complexity. Our investigation demonstrates that considering aging and IR-drop effects independently, as done in the state of the art, leads to employing insufficient and thus unreliable guardbands because of the nonnegligible (on average 15% and up to 25%) underestimations. Importantly, considering interdependences between aging and IR-drop does not only allow correct guardband estimations, but it also results in employing more efficient guardbands

    ์ ์ธต ๋‚˜๋…ธ์‹œํŠธ ๊ตฌ์กฐ์˜ ์Œ์˜ ์ •์ „์šฉ๋Ÿ‰ ์ „๊ณ„ ํšจ๊ณผ ํŠธ๋žœ์ง€์Šคํ„ฐ

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    ํ•™์œ„๋…ผ๋ฌธ(๋ฐ•์‚ฌ) -- ์„œ์šธ๋Œ€ํ•™๊ต๋Œ€ํ•™์› : ๊ณต๊ณผ๋Œ€ํ•™ ์ „๊ธฐยท์ •๋ณด๊ณตํ•™๋ถ€, 2022. 8. ์ตœ์šฐ์˜.The development of integrated circuit (IC) technology has continued to improve speed and capacity through miniaturization of devices. However, power density is increasing rapidly due to the increasing leakage current as miniaturization advances. Although the remarkable advancement of process technology has allowed complementary-metal-oxide-semiconductor (CMOS) technology to consistently overcome its constraints, the physical limitations of the metal-oxide-semiconductor field-effect transistor (MOSFET) are unmanageable. Accordingly, research on logic device is being divided into a CMOS-extension and a beyond-CMOS. CMOS-extension focuses on the gate-all-around field-effect transistors (GAAFETs) which is a promising architecture for future CMOS thanks to the excellent electrostatic gate controllability. Particularly, nanosheet (NS) architecture with high current drivability required in ICs, is the most promising. However, NS GAAFET has a trade-off relation between the controllability and the drivability, which requires the necessity of a higher-level effective oxide thickness (EOT) scaling for further scaling of NS GAAFET. On the other hand, beyond-CMOS mainly focuses on developing devices with novel mechanisms to overcome the MOSFETs' physical limits. Among several candidates, negative capacitance field-effect transistors (NCFETs) with exceptional CMOS compatibility and current drivability are highlighted as future logic devices for low-power, high-performance operation. Although the NCFET utilizing the negative capacitance (NC) effect of a ferroelectric has been demonstrated theoretically by the Landau model, it is challenging to be implemented due to the fact that stabilized NC and sub-thermionic subthreshold swing (SS) are incompatible. In this dissertation, a GAA NCFET that maintains a stable capacitance boosting by NC effect and exhibits high performance is demonstrated. A ferroelectric-antiferroelectric mixed-phase hafnium-zirconium-oxide (HZO) thin film was introduced, whose effect was confirmed by capacitors and FET experiments. Furthermore, the mixed-phase HZO was demonstrated on a stacked nanosheet gate-all-around (stacked NS GAA) structure, the advanced CMOS technology, which exhibits a superior gate controllability as well as a satisfactory drivability for ICs. The hysteresis-free stable NC operation with the superior performance was confirmed in NS GAA NCFET. The improved SS and on-current (Ion) compared to MOSFETs fabricated in the same manner were validated, and its feasibility as a low-power, high-performance logic device was proven based on a variety of figure of merits.์ง‘์ ํšŒ๋กœ ๊ธฐ์ˆ ์˜ ๋ฐœ์ „์€ ์†Œ์ž์˜ ์†Œํ˜•ํ™”๋ฅผ ํ†ตํ•œ ์†๋„ ๋ฐ ์šฉ๋Ÿ‰์˜ ํ–ฅ์ƒ์„ ์œ„ํ•ด ๋ฐœ์ „์„ ๊ฑฐ๋“ญํ•ด์™”๋‹ค. ๊ทธ๋Ÿฌ๋‚˜ ์†Œํ˜•ํ™”๋ฅผ ๊ฑฐ๋“ญํ• ์ˆ˜๋ก ์ฆ๊ฐ€ํ•˜๋Š” ๋ˆ„์„ค์ „๋ฅ˜์˜ ๋ฌธ์ œ๋กœ ์ „๋ ฅ ๋ฐ€๋„๊ฐ€ ๊ธ‰๊ฒฉํ•˜๊ฒŒ ์ฆ๊ฐ€ํ•˜๊ณ  ์žˆ๋‹ค. ์ƒ๋ณดํ˜• ๊ธˆ์†-์‚ฐํ™”๋ง‰-๋ฐ˜๋„์ฒด(CMOS) ๊ธฐ์ˆ ์€ ๋ˆˆ๋ถ€์‹  ๊ณต์ •๊ธฐ์ˆ ์˜ ์„ฑ์žฅ์— ํž˜์ž…์–ด ํ•œ๊ณ„๋ฅผ ๋Š์ž„์—†์ด ๊ทน๋ณตํ•ด์™”์œผ๋‚˜, ๊ธฐ์กด์˜ ๊ธˆ์†-์‚ฐํ™”๋ง‰-๋ฐ˜๋„์ฒด ์ „๊ณ„-ํšจ๊ณผ-ํŠธ๋žœ์ง€์Šคํ„ฐ(MOSFET)์˜ ๋ฌผ๋ฆฌ์  ํ•œ๊ณ„๋Š” ๊ทน๋ณตํ•  ์ˆ˜ ์—†๋Š” ๋ฌธ์ œ์ด๋‹ค. ์ด์— ๋”ฐ๋ผ ๋…ผ๋ฆฌ ๋ฐ˜๋„์ฒด์— ๊ด€ํ•œ ์—ฐ๊ตฌ๋Š” CMOS๋ฅผ ์—ฐ์žฅํ•˜๋Š” ๋ฐฉํ–ฅ๊ณผ CMOS๋ฅผ ๋›ฐ์–ด๋„˜๋Š” ๋ฐฉํ–ฅ์œผ๋กœ ๋‚˜๋‰˜์–ด ์ง„ํ–‰๋˜๊ณ  ์žˆ๋‹ค. CMOS๋ฅผ ์—ฐ์žฅํ•˜๋Š” ๋ฐฉํ–ฅ์€ ๋›ฐ์–ด๋‚œ ์ •์ „๊ธฐ์  ๊ฒŒ์ดํŠธ ์žฅ์•…๋ ฅ์„ ๊ฐ–๋Š” ์ฐจ์„ธ๋Œ€ CMOS ๊ตฌ์กฐ๋กœ ์œ ๋งํ•œ ๊ฒŒ์ดํŠธ-์˜ฌ-์–ด๋ผ์šด๋“œ ์ „๊ณ„-ํšจ๊ณผ-ํŠธ๋žœ์ง€์Šคํ„ฐ(GAAFET)์— ๊ด€ํ•œ ์—ฐ๊ตฌ๊ฐ€ ์ฃผ๋ฅผ ์ด๋ฃฌ๋‹ค. ํŠนํžˆ ๋†’์€ ์ „๋ฅ˜ ๊ตฌ๋™๋ ฅ์„ ๊ฐ€์งˆ ์ˆ˜ ์žˆ๋Š” ๋‚˜๋…ธ์‹œํŠธ(NS) ๊ตฌ์กฐ๊ฐ€ ๊ฐ€์žฅ ์œ ๋งํ•œ๋ฐ, ๊ฒŒ์ดํŠธ ์žฅ์•…๋ ฅ์ด ์ „๋ฅ˜ ๊ตฌ๋™๋ ฅ๊ณผ ์ƒ์ถฉ๋œ๋‹ค๋Š” ๋‹จ์ ์ด ์žˆ๋‹ค. ์ด์— ๋”ฐ๋ผ NS GAAFET ๊ธฐ์ˆ ์„ ์œ„ํ•ด์„œ๋Š” ๋” ๋†’์€ ์ˆ˜์ค€์˜ ์œ ํšจ์‚ฐํ™”๋ง‰๋‘๊ป˜ (EOT) ์Šค์ผ€์ผ๋ง์ด ํ•„์ˆ˜์ ์ด๋‹ค. ํ•œํŽธ, CMOS๋ฅผ ๋›ฐ์–ด๋„˜๋Š” ๋ฐฉํ–ฅ์˜ ์—ฐ๊ตฌ๋Š” MOSFET์˜ ๋ฌผ๋ฆฌ์  ํ•œ๊ณ„๋ฅผ ๊ทน๋ณตํ•˜๊ธฐ ์œ„ํ•ด ์ƒˆ๋กœ์šด ๋ฉ”์ปค๋‹ˆ์ฆ˜์„ ๊ฐ–๋Š” ์†Œ์ž๋ฅผ ๊ฐœ๋ฐœํ•˜๋Š” ๋ฐฉํ–ฅ์œผ๋กœ ์ด๋ฃจ์–ด์ง„๋‹ค. ๋‹ค์–‘ํ•œ ํ›„๋ณด๊ตฐ ์ค‘ CMOS ํ˜ธํ™˜์„ฑ๊ณผ ์ „๋ฅ˜ ๊ตฌ๋™๋Šฅ๋ ฅ์ด ๋›ฐ์–ด๋‚œ ์Œ์˜ ์ •์ „์šฉ๋Ÿ‰ ์ „๊ณ„-ํšจ๊ณผ-ํŠธ๋žœ์ง€์Šคํ„ฐ(NCFET)์ด ์ €์ „๋ ฅ, ๊ณ ์„ฑ๋Šฅ ๋™์ž‘์„ ์œ„ํ•œ ๋ฏธ๋ž˜ CMOS ์†Œ์ž๋กœ ๊ฐ๊ด‘๋ฐ›๊ณ  ์žˆ๋‹ค. ๊ฐ•์œ ์ „์ฒด์˜ ์Œ์˜ ์ •์ „์šฉ๋Ÿ‰ (NC) ํšจ๊ณผ๋ฅผ ์ด์šฉํ•œ NCFET์€ Landau ๋ชจ๋ธ์— ์˜ํ•ด ์ด๋ก ์ ์œผ๋กœ ์ฆ๋ช…๋˜์—ˆ์œผ๋‚˜, ์—ด์—ญํ•™์ ์œผ๋กœ ์•ˆ์ •ํ•œ ์ƒํƒœ์™€ 60 mV/dec ์ดํ•˜์˜ ๋ฌธํ„ฑ์ „์••-์ดํ•˜-๊ธฐ์šธ๊ธฐ(SS)๋ฅผ ๋™์‹œ์— ๊ตฌํ˜„ํ•˜๊ธฐ ๋ถˆ๊ฐ€๋Šฅํ•˜๋‹ค๋Š” ๋ฌธ์ œ๊ฐ€ ์žˆ๋‹ค. ๋ณธ ํ•™์œ„๋…ผ๋ฌธ์—์„œ๋Š” ์•ˆ์ •ํ•œ ์ •์ „์šฉ๋Ÿ‰ ํ–ฅ์ƒ ํŠน์„ฑ์„ ๊ฐ€์ง€๋ฉฐ ๋†’์€ ์„ฑ๋Šฅ์„ ๊ฐ–๋Š” NS GAA NCFET์„ ๊ตฌํ˜„ํ•˜์˜€๋‹ค. ๊ฐ•์œ ์ „์ฒด(ferroelectric)-๋ฐ˜๊ฐ•์œ ์ „์ฒด(antiferroelectric) ํ˜ผํ•ฉ์ƒ(mixed-phase) ํ•˜ํ”„๋Š„-์ง€๋ฅด์ฝ”๋Š„-์˜ฅ์‚ฌ์ด๋“œ(HZO) ๋ฐ•๋ง‰์˜ ์ •์ „์šฉ๋Ÿ‰ ํ–ฅ์ƒ ํšจ๊ณผ๋ฅผ ์ปคํŒจ์‹œํ„ฐ ๋ฐ FET ์ œ์ž‘์„ ํ†ตํ•ด ํšจ๊ณผ๋ฅผ ๊ฒ€์ฆํ•˜์˜€๋‹ค. ๋˜ํ•œ ๋†’์€ ๊ฒŒ์ดํŠธ ์žฅ์•…๋ ฅ์„ ๊ฐ€์ง€๋ฉฐ ์ง‘์ ํšŒ๋กœ์—์„œ ์š”๊ตฌํ•˜๋Š” ์ „๋ฅ˜ ๊ตฌ๋™๋ ฅ์„ ๋งŒ์กฑ์‹œํ‚ฌ ์ˆ˜ ์žˆ๋Š” ์ ์ธตํ˜• ๋‚˜๋…ธ์‹œํŠธ ๊ฒŒ์ดํŠธ-์˜ฌ-์–ด๋ผ์šด๋“œ(stacked NS GAA) ๊ตฌ์กฐ์— ํ˜ผํ•ฉ์ƒ NC ๋ฐ•๋ง‰์„ ์ ์šฉํ•œ FET์„ ์‹œ์—ฐํ•˜๊ณ  ์„ฑ๋Šฅ์˜ ์šฐ์ˆ˜์„ฑ์„ ํ™•์ธํ•˜์˜€๋‹ค. ๋™์ผํ•˜๊ฒŒ ์ œ์ž‘๋œ MOSFET ๋Œ€๋น„ ํ–ฅ์ƒ๋œ SS์™€ ๊ตฌ๋™ ์ „๋ฅ˜(Ion)๋ฅผ ํ™•์ธํ•˜์˜€๊ณ , ๋‹ค์–‘ํ•œ ์„ฑ๋Šฅ ์ง€์ˆ˜๋ฅผ ํ† ๋Œ€๋กœ ์ €์ „๋ ฅ, ๊ณ ์„ฑ๋Šฅ ๋กœ์ง ์†Œ์ž๋กœ์„œ์˜ ํƒ€๋‹น์„ฑ์„ ๊ฒ€์ฆํ•˜์˜€๋‹ค.Abstract i Contents iv List of Table vii List of Figures viii Chapter 1 Introduction 1 1.1 Power and Area Scaling Challenges 1 1.2 Nanosheet Gate-All-Around FETs 5 1.2.1 Gate-All-Around FETs 5 1.2.2 Nanosheet GAAFETs 6 1.3 Negative Capacitance FETs 11 1.3.1 Negative Capacitance in Ferroelectric Materials 11 1.3.2 Negative Capacitance for Steep Switching Devices 14 1.3.3 Stable NC vs. Sub-thermionic SS 17 1.4 Scope and Organization of Dissertation 21 Chapter 2 Stacked NS GAA NCFET with Ferroelectric-Antiferroelectric-Mixed-Phase HZO 22 2.1 Mixed-Phase HZO for Capacitance Boosting 22 2.2 NS GAA NCFET using Mixed-Phase HZO 25 Chapter 3 HZO ALD Stack Optimization 28 3.1 Metal-Ferroelectric-Interlayer-Silicon (MFIS) / MFM Capacitors 29 3.1.1 Fabrication of MFIS Capacitors 29 3.1.2 Electrical Characteristics of MFIS / MFM Capacitors 33 3.2 SOI Planar NCFETs 38 3.2.1 DC Measurements 38 3.2.2 Direct Capacitance Measurements 47 3.2.3 Speed Measurements 49 Chapter 4 Device Fabrication of Stacked NS GAA NCFET 51 4.1 Initial Process Flow of NS GAA NCFET 52 4.2 Process Issues and Solution 56 4.2.1 External Resistance 56 4.2.2 TiN Gate Sidewall Spacer 60 4.2.3 Unintentionally Etched Sacrificial Layer 65 4.2.4 Discussions 68 4.3 Channel Release Process 69 4.3.1 Consideration in Channel Release Process 69 4.3.2 Methods for SiGe Selective Etching 72 4.3.3 SiGe Selective Etching using Carboxylic Acid Solution 75 4.4 Revised Process of NS GAA NCFET 78 Chapter 5 Electrical Characteristics of Fabricated NS GAA NCFET 84 5.1 DC Characteristics 85 5.1.1 NS GAA NCFET vs. Planar SOI NCFET 85 5.1.2 Performance Enhancement of NS GAA NCFET 88 5.1.3 Performance Evaluation 96 5.2 Operating Temperature Properties 99 Chapter 6 Conclusion 102 Bibliography 105 ์ดˆ ๋ก 115๋ฐ•

    Electrical Characterisation of III-V Nanowire MOSFETs

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    The ever increasing demand for faster and more energy-efficient electricalcomputation and communication presents severe challenges for the semiconductor industry and particularly for the metal-oxidesemiconductorfield-effect transistor (MOSFET), which is the workhorse of modern electronics. III-V materials exhibit higher carrier mobilities than the most commonly used MOSFET material Si so that the realisation of III-V MOSFETs can enable higher operation speeds and lower drive voltages than that which is possible in Si electronics. A lowering of the transistor drive voltage can be further facilitated by employing gate-all-around nanowire geometries or novel operation principles. However, III-V materials bring about their own challenges related to material quality and to the quality of the gate oxide on top of a III-V MOSFET channel.This thesis presents detailed electrical characterisations of two types of (vertical) III-V nanowire transistors: MOSFETs based on conventional thermionic emission; and Tunnel FETs, which utilise quantum-mechanical tunnelling instead to control the device current and reach inverse subthreshold slopes below the thermal limit of 60 mV/decade. Transistor characterisations span over fourteen orders of magnitude in frequency/time constants and temperatures from 11 K to 370 K.The first part of the thesis focusses on the characterisation of electrically active material defects (โ€˜trapsโ€™) related to the gate stack. Low-frequency noise measurements yielded border trap densities of 10^18 to 10^20 cm^-3 eV^-1 and hysteresis measurements yielded effective trap densities โ€“ projected to theoxide/semiconductor interface โ€“ of 2x10^12 to 3x10^13 cm^-2 eV^-1. Random telegraph noise measurements revealed that individual oxide traps can locally shift the channel energy bands by a few millielectronvolts and that such defects can be located at energies from inside the semiconductor band gap all the way into the conduction band.Small-signal radio frequency (RF) measurements revealed that parts of the wide oxide trap distribution can still interact with carriers in the MOSFET channel at gigahertz frequencies. This causes frequency hystereses in the small-signal transconductance and capacitances and can decrease the RF gains by a few decibels. A comprehensive small-signal model was developed, which takes into account these dispersions, and the model was applied to guide improvements of the physical structure of vertical RF MOSFETs. This resulted in values for the cutoff frequency fT and the maximum oscillation frequency fmax of about 150 GHz in vertical III-V nanowire MOSFETs.Bias temperature instability measurements and the integration of (lateral) III-V nanowire MOSFETs in a back end of line process were carried out as complements to the main focus of this thesis. The results of this thesis provide a broad perspective of the properties of gate oxide traps and of the RF performance of III-V nanowire transistors and can act as guidelines for further improvement and finally the integration of III-V nanowire MOSFETs in circuits

    Study of High-k Dielectrics and their Interfaces on Semiconductors for Device Applications

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    This thesis has focused on two emerging applications of high-k dielectrics in Metal-Oxide-Semiconductor Field Effect Transistors (MOSFETs) and in Metal-InsulatorSemiconductor High Electron Mobility Transistors (MIS-HEMTs). The key aim has been to propose the best routes for passivation of semiconductor/high-k oxide interfaces by investigating the band alignments and interface properties of several oxides, such as Tm2O3, Ta2O5, ZrO2, Al2O3 and MgO, deposited on different semiconductors: Si, Ge, GaN, InGaAs and InGaSb. The electrical characterisation of fabricated MIS capacitor and (MIS)-HEMT devices have also been performed. Thulium silicate (TmSiO) has been identified as a promising candidate for integration as interfacial layer (IL) in HfO2/TiN MOSFETs. The physical properties of Tm2O3/IL/Si interface have been elucidated, where IL (TmSiO) has been formed using different post-deposition annealing (PDA) temperatures, from 550 to 750 ยฐC. It has been found that the best-scaled stack (sub-nm IL) is formed at 550 ยฐC PDA with a graded interface layer and a strong SiOx (Si 3+) component. A large valence band offset (VBO) of 2.8 eV and a large conduction band offset (CBO) of 1.9 eV have been derived for Tm2O3/Si by X-ray photoelectron spectroscopy (XPS) and variable angle spectroscopic ellipsometry. Further increase of device performance can be achieved by replacing Si with GaN for high frequency, high power and high-temperature operation. In this thesis, several GaN cleaning procedures have been considered: 30% NH4OH, 20% (NH4)2S, and 37% HCl. It has been found that the HCl treatment shows the lowest oxygen contamination and Garich surface, and hence has been used prior sputtering of Ta2O5, Al2O3, ZrO2 and MgO on GaN. The large VBOs of 1.1 eV and 1.2 eV have been derived for Al2O3 and MgO on GaN respectively, using XPS and Krautโ€™s method; the corresponding CBOs are 2.0 eV and 2.8 eV respectively, taking into account the band gaps of Al2O3 (6.5 eV) and MgO (7.4 eV) determined from XPS O 1s electron energy spectra. The lowest leakage currents were obtained for devices with Al2O3 and MgO, i.e. 5.3 ร—10-6 A/cm2 and 3.2 ร—10-6 A/cm2 at 1 V, respectively in agreement with high band offsets (> 1 eV). Furthermore, the effect of different surface treatments (HCl, O2 plasma and 1-Octadecanethiol (ODT)) prior to atomic layer deposition of Al2O3 on the GaN/AlGaN/GaN heterostructure has been investigated. The MIS-HEMTs fabricated using the low-cost ODT GaN surface treatment have been found to exhibit superior performance for power switching applications such as a low threshold voltage, VT of -12.3 V, hysteresis of 0.12 V, a small subthreshold voltage slope (SS) of 73 mV/dec, and a low density of interface states, Dit of 3.0 x10^12 cm-2eV-1. A comprehensive novel study of HfO2/InGaAs and Al2O3/InGaSb interfaces have also been conducted for use in III-V based MOSFETs. The addition of the plasma H2/TMA/H2 pre-cleaning has been found to be very effective in recovering etch damage on InGaAs, especially for (110) orientation, and led to the improvement of electrical characteristics. Furthermore, the combination of H2 plasma exposure and forming gas anneal yielded significantly improved metrics for Al2O3/InGaSb over the control HCltreated sample, with the 150 W plasma treatment giving both the highest capacitance and the lowest stretch out

    Nanoscale Field Emission Devices for High-Temperature and High-Frequency Operation

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    Field emissionโ€”the quantum-mechanical tunneling of electrons from the surface of a material into vacuum by means of a strong electric fieldโ€”has been studied for over a century. However, the usage of devices based on this mechanism has been limited to a handful of niche applications such as high-power RF systems and field emission displays. The preference for solid-state devices relies on their low cost, long lifetimes, reduced power consumption, ease of integrability, and simple and scalable fabrication. Nonetheless, with the advent of modern fabrication techniques, it has been possible to build field emission devices with nanoscale dimensions that offer several advantages over traditional semiconductor devices. The use of vacuum allows ballistic transport with no lattice scattering. As device capacitance can be engineered by tuning the geometry, these devices are appealing for high-frequency operation. Vacuum is also inherently immune to harsh operating conditions such as high temperature and radiation, which is desirable for aerospace, nuclear, and military applications. In addition, even though field emission requires substantial electric fields, by exploiting the nanoscale gaps that can be easily fabricated with state-of-the-art lithographic capabilities, we can expect operating voltages comparable to CMOS. Thus, vacuum emission devices have the potential to greatly improve upon the limitations of current technologies. In this work, we experimentally demonstrate various design paradigms to develop nanoscale field emission devices for high-temperature environments and high-frequency operation. First, we propose suspended lateral two- and four-terminal devices. By removing the underlying solid substrate, we aim to increase the resistance of the leakage current pathways that emerge at elevated temperatures. Tungsten is the chosen electrode material due to its low work function and ability to withstand high temperatures. Our next architecture consists of a multi-tip two-terminal array, which exclusively relies on the inherent fast response of field emission. Due to the strong non-linearity in the emission characteristic, frequency mixing is measured. Lastly, we combine field emission with plasmonics to conceive devices that can be modulated both electrically and optically at telecommunication wavelength. By taking advantage of the strong confinement and significant optical field enhancement of surface plasmon polaritons, we seek to minimize the applied voltages required for field emission as well as the necessary laser powers for photoemission towards the development of high-speed, low-power, nanoscale optoelectronic systems.</p
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